Up-conversion properties of SrGd2O4 nanoparticles co-doped with different Yb3+ and constant Er3+ ions were successfully prepared via sol- gel assisted combustion. Rietveld refinement and scanning/transmission electron microscopy with corresponding energydispersive X-ray spectroscopy revealed that obtained powders are composed of agglomerated nanoparticles with orthorhombic (Pnma) structure that have a uniform distribution of all constituting elements. Photoluminescence measurements implied intensification of the upconversion (UC) emission in the visible part of spectrum with the increase of Yb3+ content, which is followed by a significant change in the green to red ratio. Two-photon UC processes are established as a result of Er3+ f-f electronic transitions: green emission at 523 and 551 nm (2H11/2, 4S3/2 → 4I15/2) as well as a red emission at 661 nm (4F9/2 → 4I15/2). The highest value of absolute quantum efficiency (0.055%) is determined for SrGd2O4 nanoparticles doped with 0.5 at% of... Er3+ and co-doped with 5 at% of Yb3+ (λexc=976 nm, power density 200W/cm2).
Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022., 2022, 59-59
TY - CONF
AU - Dinić, Ivana
AU - Stamenković, Tijana
AU - Radmilović, Nadežda
AU - Vuković, Marina
AU - Rabasović, Mihailo
AU - Lojpur, Vesna
AU - Mančić, Lidija
PY - 2022
UR - http://cherry.chem.bg.ac.rs/handle/123456789/5837
AB - Up-conversion properties of SrGd2O4 nanoparticles co-doped with different Yb3+ and constant Er3+ ions were successfully prepared via sol- gel assisted combustion. Rietveld refinement and scanning/transmission electron microscopy with corresponding energydispersive X-ray spectroscopy revealed that obtained powders are composed of agglomerated nanoparticles with orthorhombic (Pnma) structure that have a uniform distribution of all constituting elements. Photoluminescence measurements implied intensification of the upconversion (UC) emission in the visible part of spectrum with the increase of Yb3+ content, which is followed by a significant change in the green to red ratio. Two-photon UC processes are established as a result of Er3+ f-f electronic transitions: green emission at 523 and 551 nm (2H11/2, 4S3/2 → 4I15/2) as well as a red emission at 661 nm (4F9/2 → 4I15/2). The highest value of absolute quantum efficiency (0.055%) is determined for SrGd2O4 nanoparticles doped with 0.5 at% of Er3+ and co-doped with 5 at% of Yb3+ (λexc=976 nm, power density 200W/cm2).
PB - Belgrade : Serbian Ceramic Society
C3 - Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.
T1 - Quantum efficiency of up-converting SrGd2O4:Yb,Er nanoparticles
SP - 59
EP - 59
UR - https://hdl.handle.net/21.15107/rcub_dais_13621
ER -
@conference{
author = "Dinić, Ivana and Stamenković, Tijana and Radmilović, Nadežda and Vuković, Marina and Rabasović, Mihailo and Lojpur, Vesna and Mančić, Lidija",
year = "2022",
abstract = "Up-conversion properties of SrGd2O4 nanoparticles co-doped with different Yb3+ and constant Er3+ ions were successfully prepared via sol- gel assisted combustion. Rietveld refinement and scanning/transmission electron microscopy with corresponding energydispersive X-ray spectroscopy revealed that obtained powders are composed of agglomerated nanoparticles with orthorhombic (Pnma) structure that have a uniform distribution of all constituting elements. Photoluminescence measurements implied intensification of the upconversion (UC) emission in the visible part of spectrum with the increase of Yb3+ content, which is followed by a significant change in the green to red ratio. Two-photon UC processes are established as a result of Er3+ f-f electronic transitions: green emission at 523 and 551 nm (2H11/2, 4S3/2 → 4I15/2) as well as a red emission at 661 nm (4F9/2 → 4I15/2). The highest value of absolute quantum efficiency (0.055%) is determined for SrGd2O4 nanoparticles doped with 0.5 at% of Er3+ and co-doped with 5 at% of Yb3+ (λexc=976 nm, power density 200W/cm2).",
publisher = "Belgrade : Serbian Ceramic Society",
journal = "Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.",
title = "Quantum efficiency of up-converting SrGd2O4:Yb,Er nanoparticles",
pages = "59-59",
url = "https://hdl.handle.net/21.15107/rcub_dais_13621"
}
Dinić, I., Stamenković, T., Radmilović, N., Vuković, M., Rabasović, M., Lojpur, V.,& Mančić, L.. (2022). Quantum efficiency of up-converting SrGd2O4:Yb,Er nanoparticles. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.
Belgrade : Serbian Ceramic Society., 59-59.
https://hdl.handle.net/21.15107/rcub_dais_13621
Dinić I, Stamenković T, Radmilović N, Vuković M, Rabasović M, Lojpur V, Mančić L. Quantum efficiency of up-converting SrGd2O4:Yb,Er nanoparticles. in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022.. 2022;:59-59.
https://hdl.handle.net/21.15107/rcub_dais_13621 .
Dinić, Ivana, Stamenković, Tijana, Radmilović, Nadežda, Vuković, Marina, Rabasović, Mihailo, Lojpur, Vesna, Mančić, Lidija, "Quantum efficiency of up-converting SrGd2O4:Yb,Er nanoparticles" in Program and the Book of abstracts / Serbian Ceramic Society Conference Advanced Ceramics and Application X New Frontiers in Multifunctional Material Science and Processing, Serbia, Belgrade, 26-27. September 2022. (2022):59-59,
https://hdl.handle.net/21.15107/rcub_dais_13621 .
