The 1,3-dipolar cycloaddition reaction was used to assemble fullerene, ferrocene and a second-generation liquid-crystalline cyanobiphenyl-based dendrimer. The targeted compound displayed an enantiotropic smectic A phase from 40 to 135degreesC. The d-layer spacing was determined by X-ray diffraction, and was found to be independent of temperature with a value of 95 Angstrom. Molecular modeling and structural considerations suggested partial bilayer organization of the mesogenic molecular units within the smectic layers. Oxidation or reduction processes of the basic components (ferrocene, fullerene, dendrimer) were investigated by electrochemical techniques, and were in agreement with the structure. Photoinduced electron transfer from ferrocene to fullerene was identified, most likely with a "through space" mechanism.
Source:
Journal of Materials Chemistry, 2004, 14, 8, 1266-1272
TY - JOUR
AU - Campidelli, S
AU - Vazquez, E
AU - Milić, Dragana
AU - Prato, M
AU - Barbera, J
AU - Guldi, DM
AU - Marcaccio, M
AU - Paolucci, D
AU - Paolucci, F
AU - Deschenaux, R
PY - 2004
UR - http://cherry.chem.bg.ac.rs/handle/123456789/634
AB - The 1,3-dipolar cycloaddition reaction was used to assemble fullerene, ferrocene and a second-generation liquid-crystalline cyanobiphenyl-based dendrimer. The targeted compound displayed an enantiotropic smectic A phase from 40 to 135degreesC. The d-layer spacing was determined by X-ray diffraction, and was found to be independent of temperature with a value of 95 Angstrom. Molecular modeling and structural considerations suggested partial bilayer organization of the mesogenic molecular units within the smectic layers. Oxidation or reduction processes of the basic components (ferrocene, fullerene, dendrimer) were investigated by electrochemical techniques, and were in agreement with the structure. Photoinduced electron transfer from ferrocene to fullerene was identified, most likely with a "through space" mechanism.
PB - Royal Soc Chemistry, Cambridge
T2 - Journal of Materials Chemistry
T1 - Liquid-crystalline fullerene-ferrocene dyads
VL - 14
IS - 8
SP - 1266
EP - 1272
DO - 10.1039/b316085h
ER -
@article{
author = "Campidelli, S and Vazquez, E and Milić, Dragana and Prato, M and Barbera, J and Guldi, DM and Marcaccio, M and Paolucci, D and Paolucci, F and Deschenaux, R",
year = "2004",
url = "http://cherry.chem.bg.ac.rs/handle/123456789/634",
abstract = "The 1,3-dipolar cycloaddition reaction was used to assemble fullerene, ferrocene and a second-generation liquid-crystalline cyanobiphenyl-based dendrimer. The targeted compound displayed an enantiotropic smectic A phase from 40 to 135degreesC. The d-layer spacing was determined by X-ray diffraction, and was found to be independent of temperature with a value of 95 Angstrom. Molecular modeling and structural considerations suggested partial bilayer organization of the mesogenic molecular units within the smectic layers. Oxidation or reduction processes of the basic components (ferrocene, fullerene, dendrimer) were investigated by electrochemical techniques, and were in agreement with the structure. Photoinduced electron transfer from ferrocene to fullerene was identified, most likely with a "through space" mechanism.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "Journal of Materials Chemistry",
title = "Liquid-crystalline fullerene-ferrocene dyads",
volume = "14",
number = "8",
pages = "1266-1272",
doi = "10.1039/b316085h"
}
Campidelli S, Vazquez E, Milić D, Prato M, Barbera J, Guldi D, Marcaccio M, Paolucci D, Paolucci F, Deschenaux R. Liquid-crystalline fullerene-ferrocene dyads. Journal of Materials Chemistry. 2004;14(8):1266-1272
Campidelli, S., Vazquez, E., Milić, D., Prato, M., Barbera, J., Guldi, D., Marcaccio, M., Paolucci, D., Paolucci, F.,& Deschenaux, R. (2004). Liquid-crystalline fullerene-ferrocene dyads.
Journal of Materials ChemistryRoyal Soc Chemistry, Cambridge., 14(8), 1266-1272.
https://doi.org/10.1039/b316085h
Campidelli S, Vazquez E, Milić Dragana, Prato M, Barbera J, Guldi DM, Marcaccio M, Paolucci D, Paolucci F, Deschenaux R, "Liquid-crystalline fullerene-ferrocene dyads" 14, no. 8 (2004):1266-1272,
https://doi.org/10.1039/b316085h .
