Experimental R(M) values for two series of beta-diketonato complexes, M(acac)(3-n)(phacphac)(n) and M(acae)(3-n)(phSacphSac)(n), where M represents cobalt(III) or chromium(III), have been determined by reversed-phase thin-layer chromatography on RP-18 silica with binary tetrahydrofuran-water, acetonitrile-water, and acetone-water mobile phases. R(M)(0) values were determined for the different mobile phase mixtures by linear extrapolation to 0% (v/v) organic modifier. Lipophilicity C(0) was calculated as the ratio of the intercept and slope values. Chromatographically obtained lipophilicity was correlated with calculated Clog P values.
TY - JOUR
AU - Natić, Maja
AU - Baošić, Rada
AU - Milojković-Opsenica, Dušanka
AU - Tešić, Živoslav Lj.
PY - 2005
UR - https://cherry.chem.bg.ac.rs/handle/123456789/736
AB - Experimental R(M) values for two series of beta-diketonato complexes, M(acac)(3-n)(phacphac)(n) and M(acae)(3-n)(phSacphSac)(n), where M represents cobalt(III) or chromium(III), have been determined by reversed-phase thin-layer chromatography on RP-18 silica with binary tetrahydrofuran-water, acetonitrile-water, and acetone-water mobile phases. R(M)(0) values were determined for the different mobile phase mixtures by linear extrapolation to 0% (v/v) organic modifier. Lipophilicity C(0) was calculated as the ratio of the intercept and slope values. Chromatographically obtained lipophilicity was correlated with calculated Clog P values.
PB - Research Inst Medicinal Plants, Budakalasz
T2 - Journal of Planar Chromatography: Modern TLC / Thin Layer Chromatography
T1 - Estimation of the hydrophobicity of tris-beta-diketonato complexes from reversed-phase thin-layer chromatographic data
VL - 18
IS - 105
SP - 344
EP - 348
DO - 10.1556/JPC.18.2005.5.2
UR - Kon_1689
ER -
@article{
author = "Natić, Maja and Baošić, Rada and Milojković-Opsenica, Dušanka and Tešić, Živoslav Lj.",
year = "2005",
abstract = "Experimental R(M) values for two series of beta-diketonato complexes, M(acac)(3-n)(phacphac)(n) and M(acae)(3-n)(phSacphSac)(n), where M represents cobalt(III) or chromium(III), have been determined by reversed-phase thin-layer chromatography on RP-18 silica with binary tetrahydrofuran-water, acetonitrile-water, and acetone-water mobile phases. R(M)(0) values were determined for the different mobile phase mixtures by linear extrapolation to 0% (v/v) organic modifier. Lipophilicity C(0) was calculated as the ratio of the intercept and slope values. Chromatographically obtained lipophilicity was correlated with calculated Clog P values.",
publisher = "Research Inst Medicinal Plants, Budakalasz",
journal = "Journal of Planar Chromatography: Modern TLC / Thin Layer Chromatography",
title = "Estimation of the hydrophobicity of tris-beta-diketonato complexes from reversed-phase thin-layer chromatographic data",
volume = "18",
number = "105",
pages = "344-348",
doi = "10.1556/JPC.18.2005.5.2",
url = "Kon_1689"
}
Natić, M., Baošić, R., Milojković-Opsenica, D.,& Tešić, Ž. Lj.. (2005). Estimation of the hydrophobicity of tris-beta-diketonato complexes from reversed-phase thin-layer chromatographic data. in Journal of Planar Chromatography: Modern TLC / Thin Layer Chromatography
Research Inst Medicinal Plants, Budakalasz., 18(105), 344-348.
https://doi.org/10.1556/JPC.18.2005.5.2
Kon_1689
Natić M, Baošić R, Milojković-Opsenica D, Tešić ŽL. Estimation of the hydrophobicity of tris-beta-diketonato complexes from reversed-phase thin-layer chromatographic data. in Journal of Planar Chromatography: Modern TLC / Thin Layer Chromatography. 2005;18(105):344-348.
doi:10.1556/JPC.18.2005.5.2
Kon_1689 .
Natić, Maja, Baošić, Rada, Milojković-Opsenica, Dušanka, Tešić, Živoslav Lj., "Estimation of the hydrophobicity of tris-beta-diketonato complexes from reversed-phase thin-layer chromatographic data" in Journal of Planar Chromatography: Modern TLC / Thin Layer Chromatography, 18, no. 105 (2005):344-348,
https://doi.org/10.1556/JPC.18.2005.5.2 .,
Kon_1689 .
