Estimation of the hydrophobicity of tris-beta-diketonato complexes from reversed-phase thin-layer chromatographic data
Апстракт
Experimental R(M) values for two series of beta-diketonato complexes, M(acac)(3-n)(phacphac)(n) and M(acae)(3-n)(phSacphSac)(n), where M represents cobalt(III) or chromium(III), have been determined by reversed-phase thin-layer chromatography on RP-18 silica with binary tetrahydrofuran-water, acetonitrile-water, and acetone-water mobile phases. R(M)(0) values were determined for the different mobile phase mixtures by linear extrapolation to 0% (v/v) organic modifier. Lipophilicity C(0) was calculated as the ratio of the intercept and slope values. Chromatographically obtained lipophilicity was correlated with calculated Clog P values.
Кључне речи:
beta-diketonato complexes / reversed-phase thin-layer chromatography / RP-18 silica / lipophilicityИзвор:
Journal of Planar Chromatography: Modern TLC / Thin Layer Chromatography, 2005, 18, 105, 344-348Издавач:
- Research Inst Medicinal Plants, Budakalasz
DOI: 10.1556/JPC.18.2005.5.2
ISSN: 0933-4173
WoS: 000233095000002
Scopus: 2-s2.0-27944471426
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Natić, Maja AU - Baošić, Rada AU - Milojković-Opsenica, Dušanka AU - Tešić, Živoslav Lj. PY - 2005 UR - https://cherry.chem.bg.ac.rs/handle/123456789/736 AB - Experimental R(M) values for two series of beta-diketonato complexes, M(acac)(3-n)(phacphac)(n) and M(acae)(3-n)(phSacphSac)(n), where M represents cobalt(III) or chromium(III), have been determined by reversed-phase thin-layer chromatography on RP-18 silica with binary tetrahydrofuran-water, acetonitrile-water, and acetone-water mobile phases. R(M)(0) values were determined for the different mobile phase mixtures by linear extrapolation to 0% (v/v) organic modifier. Lipophilicity C(0) was calculated as the ratio of the intercept and slope values. Chromatographically obtained lipophilicity was correlated with calculated Clog P values. PB - Research Inst Medicinal Plants, Budakalasz T2 - Journal of Planar Chromatography: Modern TLC / Thin Layer Chromatography T1 - Estimation of the hydrophobicity of tris-beta-diketonato complexes from reversed-phase thin-layer chromatographic data VL - 18 IS - 105 SP - 344 EP - 348 DO - 10.1556/JPC.18.2005.5.2 ER -
@article{ author = "Natić, Maja and Baošić, Rada and Milojković-Opsenica, Dušanka and Tešić, Živoslav Lj.", year = "2005", abstract = "Experimental R(M) values for two series of beta-diketonato complexes, M(acac)(3-n)(phacphac)(n) and M(acae)(3-n)(phSacphSac)(n), where M represents cobalt(III) or chromium(III), have been determined by reversed-phase thin-layer chromatography on RP-18 silica with binary tetrahydrofuran-water, acetonitrile-water, and acetone-water mobile phases. R(M)(0) values were determined for the different mobile phase mixtures by linear extrapolation to 0% (v/v) organic modifier. Lipophilicity C(0) was calculated as the ratio of the intercept and slope values. Chromatographically obtained lipophilicity was correlated with calculated Clog P values.", publisher = "Research Inst Medicinal Plants, Budakalasz", journal = "Journal of Planar Chromatography: Modern TLC / Thin Layer Chromatography", title = "Estimation of the hydrophobicity of tris-beta-diketonato complexes from reversed-phase thin-layer chromatographic data", volume = "18", number = "105", pages = "344-348", doi = "10.1556/JPC.18.2005.5.2" }
Natić, M., Baošić, R., Milojković-Opsenica, D.,& Tešić, Ž. Lj.. (2005). Estimation of the hydrophobicity of tris-beta-diketonato complexes from reversed-phase thin-layer chromatographic data. in Journal of Planar Chromatography: Modern TLC / Thin Layer Chromatography Research Inst Medicinal Plants, Budakalasz., 18(105), 344-348. https://doi.org/10.1556/JPC.18.2005.5.2
Natić M, Baošić R, Milojković-Opsenica D, Tešić ŽL. Estimation of the hydrophobicity of tris-beta-diketonato complexes from reversed-phase thin-layer chromatographic data. in Journal of Planar Chromatography: Modern TLC / Thin Layer Chromatography. 2005;18(105):344-348. doi:10.1556/JPC.18.2005.5.2 .
Natić, Maja, Baošić, Rada, Milojković-Opsenica, Dušanka, Tešić, Živoslav Lj., "Estimation of the hydrophobicity of tris-beta-diketonato complexes from reversed-phase thin-layer chromatographic data" in Journal of Planar Chromatography: Modern TLC / Thin Layer Chromatography, 18, no. 105 (2005):344-348, https://doi.org/10.1556/JPC.18.2005.5.2 . .