Synthesis and physico-chemical characterization of new dithiocarabamato ligand and its complexes with copper(II), nickel(II) and palladium(II)
Само за регистроване кориснике
2006
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Triammonium-N-dithiocarboxyiminodiacetate, (NH4)(3)L, a new dithiocarbamato derivative of iminodiacetate, has been synthesized. The coordination properties of the ligand were tested in reactions with copper(II), nickel(II) and palladium(II) salts in acidic solutions. Complexes with a general formula M(H2L)(2) were obtained, with the coordination taking place through the sulfur atoms of the dithiocarbamate moiety. The new compounds were characterized by elemental analysis, UV/VIS and IR spectroscopy, thermal analysis and magnetic measurements. In addition, the ligand was characterized by H-1- and C-13-NMR spectroscopy and molar conductivity measurements. The copper(II) complex is paramagnetic, while the nickel(II) and palladium(II) compounds are diamagnetic. The thermal decomposition of all compounds is continuous and the thermal stability of the complexes is higher than that of the ligand, as expected.
Кључне речи:
copper(II) complexes / IR / nickel(II) complexes / palladium(II) complexes / thermal analysis / triammonium-N-dithiocarboxyiminodiacetate / UV/VIS-spectrometryИзвор:
Journal of Thermal Analysis and Calorimetry, 2006, 83, 3, 687-691Издавач:
- Springer, Dordrecht
DOI: 10.1007/s10973-005-6938-7
ISSN: 1388-6150
WoS: 000236616400029
Scopus: 2-s2.0-33645668324
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Leka, ZB AU - Leovac, Vukadin M. AU - Lukic, S AU - Sabo, Tibor AU - Trifunović, Srećko R. AU - Szecsenyi, KM PY - 2006 UR - https://cherry.chem.bg.ac.rs/handle/123456789/773 AB - Triammonium-N-dithiocarboxyiminodiacetate, (NH4)(3)L, a new dithiocarbamato derivative of iminodiacetate, has been synthesized. The coordination properties of the ligand were tested in reactions with copper(II), nickel(II) and palladium(II) salts in acidic solutions. Complexes with a general formula M(H2L)(2) were obtained, with the coordination taking place through the sulfur atoms of the dithiocarbamate moiety. The new compounds were characterized by elemental analysis, UV/VIS and IR spectroscopy, thermal analysis and magnetic measurements. In addition, the ligand was characterized by H-1- and C-13-NMR spectroscopy and molar conductivity measurements. The copper(II) complex is paramagnetic, while the nickel(II) and palladium(II) compounds are diamagnetic. The thermal decomposition of all compounds is continuous and the thermal stability of the complexes is higher than that of the ligand, as expected. PB - Springer, Dordrecht T2 - Journal of Thermal Analysis and Calorimetry T1 - Synthesis and physico-chemical characterization of new dithiocarabamato ligand and its complexes with copper(II), nickel(II) and palladium(II) VL - 83 IS - 3 SP - 687 EP - 691 DO - 10.1007/s10973-005-6938-7 ER -
@article{ author = "Leka, ZB and Leovac, Vukadin M. and Lukic, S and Sabo, Tibor and Trifunović, Srećko R. and Szecsenyi, KM", year = "2006", abstract = "Triammonium-N-dithiocarboxyiminodiacetate, (NH4)(3)L, a new dithiocarbamato derivative of iminodiacetate, has been synthesized. The coordination properties of the ligand were tested in reactions with copper(II), nickel(II) and palladium(II) salts in acidic solutions. Complexes with a general formula M(H2L)(2) were obtained, with the coordination taking place through the sulfur atoms of the dithiocarbamate moiety. The new compounds were characterized by elemental analysis, UV/VIS and IR spectroscopy, thermal analysis and magnetic measurements. In addition, the ligand was characterized by H-1- and C-13-NMR spectroscopy and molar conductivity measurements. The copper(II) complex is paramagnetic, while the nickel(II) and palladium(II) compounds are diamagnetic. The thermal decomposition of all compounds is continuous and the thermal stability of the complexes is higher than that of the ligand, as expected.", publisher = "Springer, Dordrecht", journal = "Journal of Thermal Analysis and Calorimetry", title = "Synthesis and physico-chemical characterization of new dithiocarabamato ligand and its complexes with copper(II), nickel(II) and palladium(II)", volume = "83", number = "3", pages = "687-691", doi = "10.1007/s10973-005-6938-7" }
Leka, Z., Leovac, V. M., Lukic, S., Sabo, T., Trifunović, S. R.,& Szecsenyi, K.. (2006). Synthesis and physico-chemical characterization of new dithiocarabamato ligand and its complexes with copper(II), nickel(II) and palladium(II). in Journal of Thermal Analysis and Calorimetry Springer, Dordrecht., 83(3), 687-691. https://doi.org/10.1007/s10973-005-6938-7
Leka Z, Leovac VM, Lukic S, Sabo T, Trifunović SR, Szecsenyi K. Synthesis and physico-chemical characterization of new dithiocarabamato ligand and its complexes with copper(II), nickel(II) and palladium(II). in Journal of Thermal Analysis and Calorimetry. 2006;83(3):687-691. doi:10.1007/s10973-005-6938-7 .
Leka, ZB, Leovac, Vukadin M., Lukic, S, Sabo, Tibor, Trifunović, Srećko R., Szecsenyi, KM, "Synthesis and physico-chemical characterization of new dithiocarabamato ligand and its complexes with copper(II), nickel(II) and palladium(II)" in Journal of Thermal Analysis and Calorimetry, 83, no. 3 (2006):687-691, https://doi.org/10.1007/s10973-005-6938-7 . .