Multi-pi,pi stacked interaction between planar chelate rings in the crystal structure of dichloro(2-hydroxy-1-naphtaldehyde-3-methylisothlosemicarbazonato)iron(III) hemiethanol solvate
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Dichloro(2-hydroxy-1-naphtaldehyde-3-methylisothio semicarbazonato) iron(III) contains structural fragments capable for formation of hydrogen bonds and it stacking interactions. The analysis of intermolecular interactions in the crystal structure indicates the significance of a unique multistacked pi, pi interaction between five and six membered chelate rings of adjacent molecules in chains extended along the b axis. (C) 2006 Elsevier B.V. All rights reserved.
Keywords:metalloaromaticity / chelate/chelate pi,pi stacking interaction / thiosemicarbazonato iron(III) complex
Source:Inorganic Chemistry Communications, 2006, 9, 8, 833-835
- Elsevier Science Bv, Amsterdam