A simple and efficient one-step, regioselective, enzymatic glucosylation of arbutin by alpha-glucosidase
Само за регистроване кориснике
2007
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
4-Hydroxyphenyl-beta-isomaltoside has been synthesized by alpha-glucosidase assisted transglycosylation between arbutin as acceptor and sucrose as donor molecules, respectively. Optimum conditions for the transglucosylation reaction were 40 degrees C for 20 h with 10 mM arbutin and 1.5 M sucrose in a 100 mM sodium citrate/phosphate buffer at pH 5.0. The new glucoside was obtained in a 50% molar yield with respect to arbutin. (C) 2007 Elsevier Ltd. All rights reserved.
Кључне речи:
alpha-anomer-selective glucosylation / transglucosylation / 4-hydroxyphenyl-beta-isomaltoside / maltase / enzyme reactionsИзвор:
Tetrahedron Letters, 2007, 48, 40, 7222-7224Издавач:
- Pergamon-Elsevier Science Ltd, Oxford
Финансирање / пројекти:
- Испитивање структуре и функције биолошки важних макромолекула у физиолошким и патолошким стањима (RS-MESTD-MPN2006-2010-142020)
DOI: 10.1016/j.tetlet.2007.07.152
ISSN: 0040-4039
WoS: 000249771600039
Scopus: 2-s2.0-34548409004
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Milosavić, Nenad AU - Prodanović, Radivoje AU - Jankov, Ratko M. PY - 2007 UR - https://cherry.chem.bg.ac.rs/handle/123456789/878 AB - 4-Hydroxyphenyl-beta-isomaltoside has been synthesized by alpha-glucosidase assisted transglycosylation between arbutin as acceptor and sucrose as donor molecules, respectively. Optimum conditions for the transglucosylation reaction were 40 degrees C for 20 h with 10 mM arbutin and 1.5 M sucrose in a 100 mM sodium citrate/phosphate buffer at pH 5.0. The new glucoside was obtained in a 50% molar yield with respect to arbutin. (C) 2007 Elsevier Ltd. All rights reserved. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Tetrahedron Letters T1 - A simple and efficient one-step, regioselective, enzymatic glucosylation of arbutin by alpha-glucosidase VL - 48 IS - 40 SP - 7222 EP - 7224 DO - 10.1016/j.tetlet.2007.07.152 ER -
@article{ author = "Milosavić, Nenad and Prodanović, Radivoje and Jankov, Ratko M.", year = "2007", abstract = "4-Hydroxyphenyl-beta-isomaltoside has been synthesized by alpha-glucosidase assisted transglycosylation between arbutin as acceptor and sucrose as donor molecules, respectively. Optimum conditions for the transglucosylation reaction were 40 degrees C for 20 h with 10 mM arbutin and 1.5 M sucrose in a 100 mM sodium citrate/phosphate buffer at pH 5.0. The new glucoside was obtained in a 50% molar yield with respect to arbutin. (C) 2007 Elsevier Ltd. All rights reserved.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Tetrahedron Letters", title = "A simple and efficient one-step, regioselective, enzymatic glucosylation of arbutin by alpha-glucosidase", volume = "48", number = "40", pages = "7222-7224", doi = "10.1016/j.tetlet.2007.07.152" }
Milosavić, N., Prodanović, R.,& Jankov, R. M.. (2007). A simple and efficient one-step, regioselective, enzymatic glucosylation of arbutin by alpha-glucosidase. in Tetrahedron Letters Pergamon-Elsevier Science Ltd, Oxford., 48(40), 7222-7224. https://doi.org/10.1016/j.tetlet.2007.07.152
Milosavić N, Prodanović R, Jankov RM. A simple and efficient one-step, regioselective, enzymatic glucosylation of arbutin by alpha-glucosidase. in Tetrahedron Letters. 2007;48(40):7222-7224. doi:10.1016/j.tetlet.2007.07.152 .
Milosavić, Nenad, Prodanović, Radivoje, Jankov, Ratko M., "A simple and efficient one-step, regioselective, enzymatic glucosylation of arbutin by alpha-glucosidase" in Tetrahedron Letters, 48, no. 40 (2007):7222-7224, https://doi.org/10.1016/j.tetlet.2007.07.152 . .