Electrochemical bromination of peracetylated glycals
Authorized Users Only
2008
Authors
Colovic, MarijaVukicevic, Mirjana
Šegan, Dejan M.
Manojlović, Dragan D.
Šojić, Nešo
Somsak, Laszlo
Vukicevic, Rastko D.
Article (Published version)
Metadata
Show full item recordAbstract
Bromination of glycals with tribromides formed in situ from bromine and different bromide salts in dichloromethane (DCM) or acetonitrile (AN) was found to give predominantly the products of anti addition of bromine from the C-6 side in high yields. The same selectivity, which was much higher compared to bromination with bromine alone, was achieved in bromination of these substrates by anodic generation of bromine from the same salts.
Keywords:
bromination / constant current electrolysis / glycals / tribromidesSource:
Advanced Synthesis and Catalysis, 2008, 350, 1, 29-34Publisher:
- Wiley-V C H Verlag Gmbh, Weinheim
DOI: 10.1002/adsc.200700310
ISSN: 1615-4150
WoS: 000252472100005
Scopus: 2-s2.0-38349142527
Collections
Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Colovic, Marija AU - Vukicevic, Mirjana AU - Šegan, Dejan M. AU - Manojlović, Dragan D. AU - Šojić, Nešo AU - Somsak, Laszlo AU - Vukicevic, Rastko D. PY - 2008 UR - https://cherry.chem.bg.ac.rs/handle/123456789/909 AB - Bromination of glycals with tribromides formed in situ from bromine and different bromide salts in dichloromethane (DCM) or acetonitrile (AN) was found to give predominantly the products of anti addition of bromine from the C-6 side in high yields. The same selectivity, which was much higher compared to bromination with bromine alone, was achieved in bromination of these substrates by anodic generation of bromine from the same salts. PB - Wiley-V C H Verlag Gmbh, Weinheim T2 - Advanced Synthesis and Catalysis T1 - Electrochemical bromination of peracetylated glycals VL - 350 IS - 1 SP - 29 EP - 34 DO - 10.1002/adsc.200700310 ER -
@article{ author = "Colovic, Marija and Vukicevic, Mirjana and Šegan, Dejan M. and Manojlović, Dragan D. and Šojić, Nešo and Somsak, Laszlo and Vukicevic, Rastko D.", year = "2008", abstract = "Bromination of glycals with tribromides formed in situ from bromine and different bromide salts in dichloromethane (DCM) or acetonitrile (AN) was found to give predominantly the products of anti addition of bromine from the C-6 side in high yields. The same selectivity, which was much higher compared to bromination with bromine alone, was achieved in bromination of these substrates by anodic generation of bromine from the same salts.", publisher = "Wiley-V C H Verlag Gmbh, Weinheim", journal = "Advanced Synthesis and Catalysis", title = "Electrochemical bromination of peracetylated glycals", volume = "350", number = "1", pages = "29-34", doi = "10.1002/adsc.200700310" }
Colovic, M., Vukicevic, M., Šegan, D. M., Manojlović, D. D., Šojić, N., Somsak, L.,& Vukicevic, R. D.. (2008). Electrochemical bromination of peracetylated glycals. in Advanced Synthesis and Catalysis Wiley-V C H Verlag Gmbh, Weinheim., 350(1), 29-34. https://doi.org/10.1002/adsc.200700310
Colovic M, Vukicevic M, Šegan DM, Manojlović DD, Šojić N, Somsak L, Vukicevic RD. Electrochemical bromination of peracetylated glycals. in Advanced Synthesis and Catalysis. 2008;350(1):29-34. doi:10.1002/adsc.200700310 .
Colovic, Marija, Vukicevic, Mirjana, Šegan, Dejan M., Manojlović, Dragan D., Šojić, Nešo, Somsak, Laszlo, Vukicevic, Rastko D., "Electrochemical bromination of peracetylated glycals" in Advanced Synthesis and Catalysis, 350, no. 1 (2008):29-34, https://doi.org/10.1002/adsc.200700310 . .