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Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine - X-ray crystal structure of the polymeric Cd(II) complex
For the first time, complexes of Zn(II), Cd(II) and Co(II) (1-3) with N-benzyloxycarbonylglycine have been synthesized and characterized. The complexes adopt tetrahedral, pentagonal-bipyramidal and octahedral geometry, respectively. The structure of the polymeric cadmium complex was resolved by single crystal X-ray analysis. The cadmium ion has a distorted pentagonal-bipyramidal coordination formed by two water molecules and two N-benzyloxycarbonylglycinato ligands (N-Boc) coordinated in different fashions, one as bidentate and the second connecting three cadmium atoms. In a rather complicated 2D supramolecular structure, the phenyl rings interact mutually exclusively by the CH center dot center dot center dot pi interactions. Investigation of the antimicrobial activity of the obtained complexes and N-benzyloxycarbonylglycine revealed that the ligand does not inhibit the growth of Candida albicans, whereas the newly synthesized complexes suppress the growth of this human fungal pathoge...n. (c) 2007 Elsevier B.V. All rights reserved.
TY - JOUR
AU - Miodragović Đenana U.
AU - Mitić, Dragana
AU - Miodragović, Zoran
AU - Bogdanović, Goran A.
AU - Vitnik, Zeljko J.
AU - Vitorovic, Maja D.
AU - Radulovic, Milanka D.
AU - Nastasijevic, Branislav J.
AU - Juranić, Ivan O.
AU - Anđelković, Katarina K.
PY - 2008
UR - http://cherry.chem.bg.ac.rs/handle/123456789/914
AB - For the first time, complexes of Zn(II), Cd(II) and Co(II) (1-3) with N-benzyloxycarbonylglycine have been synthesized and characterized. The complexes adopt tetrahedral, pentagonal-bipyramidal and octahedral geometry, respectively. The structure of the polymeric cadmium complex was resolved by single crystal X-ray analysis. The cadmium ion has a distorted pentagonal-bipyramidal coordination formed by two water molecules and two N-benzyloxycarbonylglycinato ligands (N-Boc) coordinated in different fashions, one as bidentate and the second connecting three cadmium atoms. In a rather complicated 2D supramolecular structure, the phenyl rings interact mutually exclusively by the CH center dot center dot center dot pi interactions. Investigation of the antimicrobial activity of the obtained complexes and N-benzyloxycarbonylglycine revealed that the ligand does not inhibit the growth of Candida albicans, whereas the newly synthesized complexes suppress the growth of this human fungal pathogen. (c) 2007 Elsevier B.V. All rights reserved.
PB - Elsevier Science Sa, Lausanne
T2 - Inorganica Chimica Acta
T1 - Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine - X-ray crystal structure of the polymeric Cd(II) complex
VL - 361
IS - 1
SP - 86
EP - 94
DO - 10.1016/j.ica.2007.06.041
ER -
@article{
author = "Miodragović Đenana U. and Mitić, Dragana and Miodragović, Zoran and Bogdanović, Goran A. and Vitnik, Zeljko J. and Vitorovic, Maja D. and Radulovic, Milanka D. and Nastasijevic, Branislav J. and Juranić, Ivan O. and Anđelković, Katarina K.",
year = "2008",
url = "http://cherry.chem.bg.ac.rs/handle/123456789/914",
abstract = "For the first time, complexes of Zn(II), Cd(II) and Co(II) (1-3) with N-benzyloxycarbonylglycine have been synthesized and characterized. The complexes adopt tetrahedral, pentagonal-bipyramidal and octahedral geometry, respectively. The structure of the polymeric cadmium complex was resolved by single crystal X-ray analysis. The cadmium ion has a distorted pentagonal-bipyramidal coordination formed by two water molecules and two N-benzyloxycarbonylglycinato ligands (N-Boc) coordinated in different fashions, one as bidentate and the second connecting three cadmium atoms. In a rather complicated 2D supramolecular structure, the phenyl rings interact mutually exclusively by the CH center dot center dot center dot pi interactions. Investigation of the antimicrobial activity of the obtained complexes and N-benzyloxycarbonylglycine revealed that the ligand does not inhibit the growth of Candida albicans, whereas the newly synthesized complexes suppress the growth of this human fungal pathogen. (c) 2007 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Inorganica Chimica Acta",
title = "Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine - X-ray crystal structure of the polymeric Cd(II) complex",
volume = "361",
number = "1",
pages = "86-94",
doi = "10.1016/j.ica.2007.06.041"
}
Miodragović Đenana U., Mitić D, Miodragović Z, Bogdanović GA, Vitnik ZJ, Vitorovic MD, Radulovic MD, Nastasijevic BJ, Juranić IO, Anđelković KK. Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine - X-ray crystal structure of the polymeric Cd(II) complex. Inorganica Chimica Acta. 2008;361(1):86-94
Miodragović Đenana U., Mitić, D., Miodragović, Z., Bogdanović, G. A., Vitnik, Z. J., Vitorovic, M. D., Radulovic, M. D., Nastasijevic, B. J., Juranić, I. O.,& Anđelković, K. K. (2008). Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine - X-ray crystal structure of the polymeric Cd(II) complex.
Inorganica Chimica ActaElsevier Science Sa, Lausanne., 361(1), 86-94.
https://doi.org/10.1016/j.ica.2007.06.041
Miodragović Đenana U., Mitić Dragana, Miodragović Zoran, Bogdanović Goran A., Vitnik Zeljko J., Vitorovic Maja D., Radulovic Milanka D., Nastasijevic Branislav J., Juranić Ivan O., Anđelković Katarina K., "Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine - X-ray crystal structure of the polymeric Cd(II) complex" 361, no. 1 (2008):86-94,
https://doi.org/10.1016/j.ica.2007.06.041 .
