Two fullerene-peralkylated ferrocene derivatives were synthesized: (1) a liquid-crystalline dyad (compound 1) was obtained by introduction of nonamethyl ferrocene into a liquid-crystalline fullerene derivative and (2) a reference compound (compound 2) was synthesized by attachment of nonamethyl ferrocene to a fulleropyrrolidine. The liquid-crystalline dyad displayed an enantiotropic smectic A phase from 57 to 155 degrees C. Oxidation and reduction processes were investigated by cyclic voltammetry, and were in agreement with the electrochemical characteristics of the redox-active units (peralkylated ferrocene, fullerene, dendrimer). Photoinduced electron transfer from ferrocene derivative to fullerene was identified.
Source:
Journal of Materials Chemistry, 2008, 18, 13, 1504-1509
TY - JOUR
AU - Campidelli, Stephane
AU - Severac, Marjorie
AU - Scanu, David
AU - Deschenaux, Robert
AU - Vazquez, Ester
AU - Milić, Dragana
AU - Prato, Maurizio
AU - Carano, Maurizio
AU - Marcaccio, Massimo
AU - Paolucci, Francesco
AU - Rahman, G. M. Aminur
AU - Guldi, Dirk M.
PY - 2008
UR - http://cherry.chem.bg.ac.rs/handle/123456789/925
AB - Two fullerene-peralkylated ferrocene derivatives were synthesized: (1) a liquid-crystalline dyad (compound 1) was obtained by introduction of nonamethyl ferrocene into a liquid-crystalline fullerene derivative and (2) a reference compound (compound 2) was synthesized by attachment of nonamethyl ferrocene to a fulleropyrrolidine. The liquid-crystalline dyad displayed an enantiotropic smectic A phase from 57 to 155 degrees C. Oxidation and reduction processes were investigated by cyclic voltammetry, and were in agreement with the electrochemical characteristics of the redox-active units (peralkylated ferrocene, fullerene, dendrimer). Photoinduced electron transfer from ferrocene derivative to fullerene was identified.
PB - Royal Soc Chemistry, Cambridge
T2 - Journal of Materials Chemistry
T1 - Photophysical, electrochemical, and mesomorphic properties of a liquid-crystalline [60]fullerene-peralkylated ferrocene dyad
VL - 18
IS - 13
SP - 1504
EP - 1509
DO - 10.1039/b716806c
ER -
@article{
author = "Campidelli, Stephane and Severac, Marjorie and Scanu, David and Deschenaux, Robert and Vazquez, Ester and Milić, Dragana and Prato, Maurizio and Carano, Maurizio and Marcaccio, Massimo and Paolucci, Francesco and Rahman, G. M. Aminur and Guldi, Dirk M.",
year = "2008",
url = "http://cherry.chem.bg.ac.rs/handle/123456789/925",
abstract = "Two fullerene-peralkylated ferrocene derivatives were synthesized: (1) a liquid-crystalline dyad (compound 1) was obtained by introduction of nonamethyl ferrocene into a liquid-crystalline fullerene derivative and (2) a reference compound (compound 2) was synthesized by attachment of nonamethyl ferrocene to a fulleropyrrolidine. The liquid-crystalline dyad displayed an enantiotropic smectic A phase from 57 to 155 degrees C. Oxidation and reduction processes were investigated by cyclic voltammetry, and were in agreement with the electrochemical characteristics of the redox-active units (peralkylated ferrocene, fullerene, dendrimer). Photoinduced electron transfer from ferrocene derivative to fullerene was identified.",
publisher = "Royal Soc Chemistry, Cambridge",
journal = "Journal of Materials Chemistry",
title = "Photophysical, electrochemical, and mesomorphic properties of a liquid-crystalline [60]fullerene-peralkylated ferrocene dyad",
volume = "18",
number = "13",
pages = "1504-1509",
doi = "10.1039/b716806c"
}
Campidelli S, Severac M, Scanu D, Deschenaux R, Vazquez E, Milić D, Prato M, Carano M, Marcaccio M, Paolucci F, Rahman GMA, Guldi DM. Photophysical, electrochemical, and mesomorphic properties of a liquid-crystalline [60]fullerene-peralkylated ferrocene dyad. Journal of Materials Chemistry. 2008;18(13):1504-1509
Campidelli, S., Severac, M., Scanu, D., Deschenaux, R., Vazquez, E., Milić, D., Prato, M., Carano, M., Marcaccio, M., Paolucci, F., Rahman, G. M. A.,& Guldi, D. M. (2008). Photophysical, electrochemical, and mesomorphic properties of a liquid-crystalline [60]fullerene-peralkylated ferrocene dyad.
Journal of Materials ChemistryRoyal Soc Chemistry, Cambridge., 18(13), 1504-1509.
https://doi.org/10.1039/b716806c
Campidelli Stephane, Severac Marjorie, Scanu David, Deschenaux Robert, Vazquez Ester, Milić Dragana, Prato Maurizio, Carano Maurizio, Marcaccio Massimo, Paolucci Francesco, Rahman G. M. Aminur, Guldi Dirk M., "Photophysical, electrochemical, and mesomorphic properties of a liquid-crystalline [60]fullerene-peralkylated ferrocene dyad" 18, no. 13 (2008):1504-1509,
https://doi.org/10.1039/b716806c .
