Generation and intermolecular additions of pyridylmethyl radicals
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2-, 3-, or 4-Pyridylmethyl radicals can be made to add to nonactivated alkenes to give a variety of otherwise inaccessible pyridine derivatives. Bicyclic structures can be obtained by combining the radical addition with ionic ring-closure steps.
Keywords:radical additions / heterocycles / pyridines / alkenes / cyclization
Source:Synthesis, Stuttgart, 2008, 18, 2996-3008
- Georg Thieme Verlag Kg, Stuttgart