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Palladium(II) complexes with R(2)edda derived ligands. Part I. Reaction of diisopropyl (S,S)-2,2 '-(1,2-ethanediyldiimino)-dipropanoate with K-2[PdCl4]
Kompleksi paladijuma(II) sa ligandima R2edda tipa, deo I - reakcija diizopropil-(S,S)-2,2'-(1,2-etandiildiimino)dipropanoata sa K2[PdCl4]
dc.creator | Krajcinovic, Bojana B. | |
dc.creator | Kaluđerović, Goran N. | |
dc.creator | Steinborn, Dirk | |
dc.creator | Schmidt, Harry | |
dc.creator | Wagner, Christoph | |
dc.creator | Merzweiler, Kurt | |
dc.creator | Trifunović, Srećko R. | |
dc.creator | Sabo, Tibor | |
dc.date.accessioned | 2018-11-22T00:14:45Z | |
dc.date.available | 2018-11-22T00:14:45Z | |
dc.date.issued | 2009 | |
dc.identifier.issn | 0352-5139 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/989 | |
dc.description.abstract | The reaction of K-2[PdCl4] with (S,S)-(i-Pr)(2)eddip diester (diisopropyl (S,S)-2,2'-(1,2-ethanediyldiimino)dipropanoate) resulted in {PdCl2[(S,S)-(i-Pr)-Pr)(2)eddip-kappa N-2,N']} (1) and {PdCl[(S,S)-(i-Pr)eddip-kappa N-2,N',kappa O]} (2) with one hydrolyzed ester group. The compounds were characterized by spectroscopic methods and it was proved that the reaction is diastereoselective (H-1- and C-13-NMR) in the case of 2 (one diastereoisomer of four possible). The structure of 2 was determined by X-ray diffraction analysis, indicating that the product is the (R,R)-N,N' configured isomer. In contrast, the reaction yielding 1 produced two of three possible diastereoisomers. DFT calculations support the formation of two diastereoisomers of I and of one diastereoisomer of 2. | en |
dc.description.abstract | U reakciji K2[PdCl4] sa (S,S)-(i-Pr)2eddip diestrom [diizopropil-(S,S)-2,2'-(1,2-etandi-ildiimino)dipropanoat] dobijaju se {PdCl2[(S,S)-(i-Pr)2eddip-κ2N,N']} (1) i {PdCl[(S,S)-(i-Pr)eddip-κ2N,N',κO]} (2) sa jednom hidrolizovanom estarskom grupom. Jedinjenja su okarakterisana spektroskopskim metodama i dokazano je da je ova reakcija dijastereoselektivna (1H- i 13C-NMR) u slučaju 2 (jedan dijastereoizomer od moguća četiri). Struktura jedinjenja 2 je određena rendgenskom strukturnom analizom i nađeno je da je dobijeni proizvod (R,R)-N,N' izomer. Suprotno tome, u slučaju jedinjenja 1 dobijeni proizvod je smeša dva od tri moguća dijastereoizomera. DFT proračuni potvrđuju formiranje dva dijastereoizomera jedinjenja 1 i jednog dijastereoizomera jedinjenja 2. | sr |
dc.publisher | Serbian Chemical Soc, Belgrade | |
dc.relation | info:eu-repo/grantAgreement/MESTD/MPN2006-2010/142010/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/MPN2006-2010/142008/RS// | |
dc.relation | Alexander von Humboldt Foundation | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | Journal of the Serbian Chemical Society | |
dc.subject | palladium complexes | en |
dc.subject | crystal structure | en |
dc.subject | crystal structure | en |
dc.subject | EDDP ligands | en |
dc.subject | EDDP ligands | en |
dc.subject | DFT calculations | en |
dc.subject | DFT calculations | en |
dc.title | Palladium(II) complexes with R(2)edda derived ligands. Part I. Reaction of diisopropyl (S,S)-2,2 '-(1,2-ethanediyldiimino)-dipropanoate with K-2[PdCl4] | en |
dc.title | Kompleksi paladijuma(II) sa ligandima R2edda tipa, deo I - reakcija diizopropil-(S,S)-2,2'-(1,2-etandiildiimino)dipropanoata sa K2[PdCl4] | sr |
dc.type | article | |
dc.rights.license | BY-NC-ND | |
dcterms.abstract | Стеинборн, Дирк; Крајциновиц, Бојана Б.; Сцхмидт, Харрy; Wагнер, Цхристопх; Мерзwеилер, Курт; Калудеровиц, Горан Н.; Трифуновиц, Срецко Р.; Сабо, Тибор; Комплекси паладијума(ИИ) са лигандима Р2едда типа, део И - реакција диизопропил-(С,С)-2,2'-(1,2-етандиилдиимино)дипропаноата са К2[ПдЦл4]; Комплекси паладијума(ИИ) са лигандима Р2едда типа, део И - реакција диизопропил-(С,С)-2,2'-(1,2-етандиилдиимино)дипропаноата са К2[ПдЦл4]; | |
dc.citation.volume | 74 | |
dc.citation.issue | 4 | |
dc.citation.spage | 389 | |
dc.citation.epage | 400 | |
dc.identifier.wos | 000266210200004 | |
dc.identifier.doi | 10.2298/JSC0904389K | |
dc.citation.other | 74(4): 389-400 | |
dc.citation.rank | M23 | |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-68949178838 | |
dc.identifier.fulltext | https://cherry.chem.bg.ac.rs/bitstream/id/10152/987.pdf |