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New insight into the anisotropic effects in solution-state NMR spectroscopy
(Royal Soc Chemistry, Cambridge, 2014)
Nuclear magnetic resonance (NMR) spectroscopy is an important technique for structure determination. Within it, anisotropic effects of different functional groups and ring systems, depicted as familiar "anisotropy cones", ...
Voltammetric determination of an antipsychotic agent trifluoperazine at a boron-doped diamond electrode in human urine
(Royal Soc Chemistry, Cambridge, 2015)
A simple and efficient procedure is described for electrochemical determination of trifluoperazine (TFP), a prominent compound in a large group of phenothiazine derivatives with potent physiological activity. This method ...
Gauche preference in 1,2-difluoroethane originates from both orbital and electrostatic stabilization interactions
(Royal Soc Chemistry, Cambridge, 2014)
The origin of the gauche preference in 1,2-difluoroethane has been investigated by using an energy decomposition analysis (EDA). The EDA results show that favourable orbital interactions are not the sole source of stabilization ...
Synthesis of gamma-nitroaldehydes containing quaternary carbon in the alpha-position using a 4-oxalocrotonate tautomerase whole-cell biocatalyst
(Royal Soc Chemistry, Cambridge, 2014)
Synthesis of gamma-nitroaldehydes from branched chain aldehydes and a range of alpha,beta-unsaturated nitroalkenes was achieved by a whole-cell biocatalytic reaction using 4-oxalocrotonate tautomerase as catalyst. Under ...
Phycocyanobilin, a bioactive tetrapyrrolic compound of blue-green alga Spirulina, binds with high affinity and competes with bilirubin for binding on human serum albumin
(Royal Soc Chemistry, Cambridge, 2015)
Human serum albumin (HSA) is an important regulator of the pharmacokinetic properties of bioactive compounds. Phycocyanobilin is a blue tetrapyrrole chromophore of C-phycocyanin with proven health-promoting activities. ...
Diamide-based fullerosteroidal and disteroidal [2] rotaxanes: solvent-induced macrocycle translocation and/or unthreading
(Royal Soc Chemistry, Cambridge, 2016)
The synthesis, characterization and behaviour of two novel Leigh-type amide [2]rotaxanes are reported. NMR study shows that fullerosteroidal and disteroidal rotaxanes occur in a peptide co-conformation in CDCl3. [D-6]DMSO ...
Fulleropyrrolidines derived from dioxa- and trioxaalkyl-tethered diglycines
(Royal Soc Chemistry, Cambridge, 2015)
Two different alpha,omega-diglicynes linked by linear polyoxaalkyl chains in the presence of formaldehyde underwent Prato reaction to the fullerene C-60. The shorter linker templated formation of only cis-bisadducts, while ...
Supplementary data for the article: Pavlović, R. Z.; Bjelaković, M. S.; Milić, D. Diamide-Based Fullerosteroidal and Disteroidal [2] Rotaxanes: Solvent-Induced Macrocycle Translocation and/or Unthreading. RSC Advances 2016, 6 (43), 37246–37253. https://doi.org/10.1039/c6ra03872g
(Royal Soc Chemistry, Cambridge, 2016)