Synthesis, Characterization and Adsorptive Properties of Organobentonites
2010
Authors
Jovic-Jovicic, N.Milutinović-Nikolić, Aleksandra D.
Bankovic, P.
Dojčinović, Biljana P.
Nedic, B.
Gržetić, Ivan
Jovanovic, D.
Article (Published version)
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In this paper partial and complete substitution of cations in the interlayer region of clay with different amounts of two aliphatic ammonium cations was performed with aim of synthesis of organobentonites with multipurpose adsorption properties. Domestic clay from Bogovina was submitted according to a common procedure used for the obtention of organobentonite, which comprises the following steps: grinding, sieving, Na-exchange, cation exchange and drying. The samples were characterized by X-ray diffraction and infrared spectroscopy. The incorporation of surfactant molecules into smectite structure lead to constant increase of d(001) basal spacing. IR absorption bands assigned to methyl and methylene vibrations increased with the increase of surfactant/bentonite ratio and length of aliphatic chain in surfactant molecules. Adsorptive properties of the obtained materials were in accordance with their organophylicity: the adsorption of organic dye increased while the rate of removal of Pb2...+ by adsorption decreased.
Source:
Acta Physica Polonica. Series A: General Physics, Physics of Condensed Matter, Optics and Quantum El, 2010, 117, 5, 849-854Publisher:
- Polish Acad Sciences Inst Physics, Warsaw
Funding / projects:
- Sinteza, karakterizacija i testiranje katalitičkih svojstava specijalno dizajniranih materijala (RS-MESTD-MPN2006-2010-142019)
- Mezoporozni i nanomaterijali u katalitičkim i sorpcionim procesima (RS-MESTD-MPN2006-2010-166001)
DOI: 10.12693/APhysPolA.117.849
ISSN: 0587-4246
WoS: 000278221700028
Scopus: 2-s2.0-77952687067
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Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Jovic-Jovicic, N. AU - Milutinović-Nikolić, Aleksandra D. AU - Bankovic, P. AU - Dojčinović, Biljana P. AU - Nedic, B. AU - Gržetić, Ivan AU - Jovanovic, D. PY - 2010 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1083 AB - In this paper partial and complete substitution of cations in the interlayer region of clay with different amounts of two aliphatic ammonium cations was performed with aim of synthesis of organobentonites with multipurpose adsorption properties. Domestic clay from Bogovina was submitted according to a common procedure used for the obtention of organobentonite, which comprises the following steps: grinding, sieving, Na-exchange, cation exchange and drying. The samples were characterized by X-ray diffraction and infrared spectroscopy. The incorporation of surfactant molecules into smectite structure lead to constant increase of d(001) basal spacing. IR absorption bands assigned to methyl and methylene vibrations increased with the increase of surfactant/bentonite ratio and length of aliphatic chain in surfactant molecules. Adsorptive properties of the obtained materials were in accordance with their organophylicity: the adsorption of organic dye increased while the rate of removal of Pb2+ by adsorption decreased. PB - Polish Acad Sciences Inst Physics, Warsaw T2 - Acta Physica Polonica. Series A: General Physics, Physics of Condensed Matter, Optics and Quantum El T1 - Synthesis, Characterization and Adsorptive Properties of Organobentonites VL - 117 IS - 5 SP - 849 EP - 854 DO - 10.12693/APhysPolA.117.849 ER -
@article{ author = "Jovic-Jovicic, N. and Milutinović-Nikolić, Aleksandra D. and Bankovic, P. and Dojčinović, Biljana P. and Nedic, B. and Gržetić, Ivan and Jovanovic, D.", year = "2010", abstract = "In this paper partial and complete substitution of cations in the interlayer region of clay with different amounts of two aliphatic ammonium cations was performed with aim of synthesis of organobentonites with multipurpose adsorption properties. Domestic clay from Bogovina was submitted according to a common procedure used for the obtention of organobentonite, which comprises the following steps: grinding, sieving, Na-exchange, cation exchange and drying. The samples were characterized by X-ray diffraction and infrared spectroscopy. The incorporation of surfactant molecules into smectite structure lead to constant increase of d(001) basal spacing. IR absorption bands assigned to methyl and methylene vibrations increased with the increase of surfactant/bentonite ratio and length of aliphatic chain in surfactant molecules. Adsorptive properties of the obtained materials were in accordance with their organophylicity: the adsorption of organic dye increased while the rate of removal of Pb2+ by adsorption decreased.", publisher = "Polish Acad Sciences Inst Physics, Warsaw", journal = "Acta Physica Polonica. Series A: General Physics, Physics of Condensed Matter, Optics and Quantum El", title = "Synthesis, Characterization and Adsorptive Properties of Organobentonites", volume = "117", number = "5", pages = "849-854", doi = "10.12693/APhysPolA.117.849" }
Jovic-Jovicic, N., Milutinović-Nikolić, A. D., Bankovic, P., Dojčinović, B. P., Nedic, B., Gržetić, I.,& Jovanovic, D.. (2010). Synthesis, Characterization and Adsorptive Properties of Organobentonites. in Acta Physica Polonica. Series A: General Physics, Physics of Condensed Matter, Optics and Quantum El Polish Acad Sciences Inst Physics, Warsaw., 117(5), 849-854. https://doi.org/10.12693/APhysPolA.117.849
Jovic-Jovicic N, Milutinović-Nikolić AD, Bankovic P, Dojčinović BP, Nedic B, Gržetić I, Jovanovic D. Synthesis, Characterization and Adsorptive Properties of Organobentonites. in Acta Physica Polonica. Series A: General Physics, Physics of Condensed Matter, Optics and Quantum El. 2010;117(5):849-854. doi:10.12693/APhysPolA.117.849 .
Jovic-Jovicic, N., Milutinović-Nikolić, Aleksandra D., Bankovic, P., Dojčinović, Biljana P., Nedic, B., Gržetić, Ivan, Jovanovic, D., "Synthesis, Characterization and Adsorptive Properties of Organobentonites" in Acta Physica Polonica. Series A: General Physics, Physics of Condensed Matter, Optics and Quantum El, 117, no. 5 (2010):849-854, https://doi.org/10.12693/APhysPolA.117.849 . .