Dibromido[(S,S)-ethylenediamine-N,N '-di-2-(3-cyclohexyl)propanoato]platinum(IV): synthesis, characterization, and DFT calculations
Abstract
Bromido complex of platinum(IV) with (S, S)-ethylenediamine-N, N'-di-2-(3-cyclohexyl) propanoic acid was synthesized. The reaction was performed in water solution in the presence of lithium hydroxide. In this reaction system, (S, S)-ethylenediamine-N, N'-di-2-(3-cyclohexyl) propanoic acid exists as the dicarboxylato anion and coordinates as a tetradentate ONNO ligand. The complex was characterized by (1)H and (13)C NMR, IR and UV-Vis spectroscopy. The sym-cis configuration has been elucidated using DFT calculations.
Keywords:
Platinum(IV) complexes / edda-Type ligand / DFT calculationSource:
Journal of Coordination Chemistry, 2011, 64, 6, 1016-1022Publisher:
- Taylor & Francis Ltd, Abingdon
Funding / projects:
- Synthesis, characterization and activity of organic and coordination composition and their application in (bio) nanotechnology (RS-MESTD-MPN2006-2010-142010)
Note:
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/3610
DOI: 10.1080/00958972.2011.560940
ISSN: 0095-8972
WoS: 000288270500009
Scopus: 2-s2.0-79952614897
Collections
Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Poljarević, Jelena AU - Grgurić-Šipka, Sanja AU - Kaluđerović, Goran N. AU - Sabo, Tibor PY - 2011 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1160 AB - Bromido complex of platinum(IV) with (S, S)-ethylenediamine-N, N'-di-2-(3-cyclohexyl) propanoic acid was synthesized. The reaction was performed in water solution in the presence of lithium hydroxide. In this reaction system, (S, S)-ethylenediamine-N, N'-di-2-(3-cyclohexyl) propanoic acid exists as the dicarboxylato anion and coordinates as a tetradentate ONNO ligand. The complex was characterized by (1)H and (13)C NMR, IR and UV-Vis spectroscopy. The sym-cis configuration has been elucidated using DFT calculations. PB - Taylor & Francis Ltd, Abingdon T2 - Journal of Coordination Chemistry T1 - Dibromido[(S,S)-ethylenediamine-N,N '-di-2-(3-cyclohexyl)propanoato]platinum(IV): synthesis, characterization, and DFT calculations VL - 64 IS - 6 SP - 1016 EP - 1022 DO - 10.1080/00958972.2011.560940 ER -
@article{ author = "Poljarević, Jelena and Grgurić-Šipka, Sanja and Kaluđerović, Goran N. and Sabo, Tibor", year = "2011", abstract = "Bromido complex of platinum(IV) with (S, S)-ethylenediamine-N, N'-di-2-(3-cyclohexyl) propanoic acid was synthesized. The reaction was performed in water solution in the presence of lithium hydroxide. In this reaction system, (S, S)-ethylenediamine-N, N'-di-2-(3-cyclohexyl) propanoic acid exists as the dicarboxylato anion and coordinates as a tetradentate ONNO ligand. The complex was characterized by (1)H and (13)C NMR, IR and UV-Vis spectroscopy. The sym-cis configuration has been elucidated using DFT calculations.", publisher = "Taylor & Francis Ltd, Abingdon", journal = "Journal of Coordination Chemistry", title = "Dibromido[(S,S)-ethylenediamine-N,N '-di-2-(3-cyclohexyl)propanoato]platinum(IV): synthesis, characterization, and DFT calculations", volume = "64", number = "6", pages = "1016-1022", doi = "10.1080/00958972.2011.560940" }
Poljarević, J., Grgurić-Šipka, S., Kaluđerović, G. N.,& Sabo, T.. (2011). Dibromido[(S,S)-ethylenediamine-N,N '-di-2-(3-cyclohexyl)propanoato]platinum(IV): synthesis, characterization, and DFT calculations. in Journal of Coordination Chemistry Taylor & Francis Ltd, Abingdon., 64(6), 1016-1022. https://doi.org/10.1080/00958972.2011.560940
Poljarević J, Grgurić-Šipka S, Kaluđerović GN, Sabo T. Dibromido[(S,S)-ethylenediamine-N,N '-di-2-(3-cyclohexyl)propanoato]platinum(IV): synthesis, characterization, and DFT calculations. in Journal of Coordination Chemistry. 2011;64(6):1016-1022. doi:10.1080/00958972.2011.560940 .
Poljarević, Jelena, Grgurić-Šipka, Sanja, Kaluđerović, Goran N., Sabo, Tibor, "Dibromido[(S,S)-ethylenediamine-N,N '-di-2-(3-cyclohexyl)propanoato]platinum(IV): synthesis, characterization, and DFT calculations" in Journal of Coordination Chemistry, 64, no. 6 (2011):1016-1022, https://doi.org/10.1080/00958972.2011.560940 . .