The comparison of sample extraction procedures for the determination of cations in soil by IC and ICP-AES
Апстракт
This paper presents the extraction of cations from a soil sample, type ranker on serpentinite, in deionized water, by use of three different extraction techniques. The first extraction technique included the use of a rotary mixer, the second technique involved the use of a microwave digestion system with different extraction temperatures, and the third technique employed an ultrasonic bath with different extraction times. Ion chromatography was used for determining the concentration of Li, Na, K, Ca, Mg and ammonium ions in soil extracts with subsequent determination of concentrations for all cations, except for ammonium ion extraction, conducted by Inductively Coupled Plasma-Atomic Emission Spectrometry. The results of cation extractions showed that microwave assisted extraction was most efficient for the Li, Na, K, Ca, Mg, Co, Mn, Ni, Pb and ammonium ions. Use of a rotary mixer for extraction was most efficient for Cd and Zn ions, while use of ultrasound bath was most efficient for C...r, Cu, Fe and Al ions. Several times higher amount of cations extracted by the most efficient, compared to the second best technique, under optimal conditions, were noticed in the case of: Ca, Mg, Co, Mn, Fe, Al, and Zn ions.
Кључне речи:
Soil sample extraction / Cation extraction / Sequential extraction procedure / Ion chromatography / ICP-AESИзвор:
Central European Journal of Chemistry, 2011, 9, 3, 481-491Издавач:
- Versita, Warsaw
DOI: 10.2478/s11532-011-0031-9
ISSN: 1895-1066
WoS: 000291253000016
Scopus: 2-s2.0-79958708488
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Stanišić, Svetlana M. AU - Ignjatovic, Ljubisa M. AU - Manojlović, Dragan D. AU - Dojčinović, Biljana P. PY - 2011 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1349 AB - This paper presents the extraction of cations from a soil sample, type ranker on serpentinite, in deionized water, by use of three different extraction techniques. The first extraction technique included the use of a rotary mixer, the second technique involved the use of a microwave digestion system with different extraction temperatures, and the third technique employed an ultrasonic bath with different extraction times. Ion chromatography was used for determining the concentration of Li, Na, K, Ca, Mg and ammonium ions in soil extracts with subsequent determination of concentrations for all cations, except for ammonium ion extraction, conducted by Inductively Coupled Plasma-Atomic Emission Spectrometry. The results of cation extractions showed that microwave assisted extraction was most efficient for the Li, Na, K, Ca, Mg, Co, Mn, Ni, Pb and ammonium ions. Use of a rotary mixer for extraction was most efficient for Cd and Zn ions, while use of ultrasound bath was most efficient for Cr, Cu, Fe and Al ions. Several times higher amount of cations extracted by the most efficient, compared to the second best technique, under optimal conditions, were noticed in the case of: Ca, Mg, Co, Mn, Fe, Al, and Zn ions. PB - Versita, Warsaw T2 - Central European Journal of Chemistry T1 - The comparison of sample extraction procedures for the determination of cations in soil by IC and ICP-AES VL - 9 IS - 3 SP - 481 EP - 491 DO - 10.2478/s11532-011-0031-9 ER -
@article{ author = "Stanišić, Svetlana M. and Ignjatovic, Ljubisa M. and Manojlović, Dragan D. and Dojčinović, Biljana P.", year = "2011", abstract = "This paper presents the extraction of cations from a soil sample, type ranker on serpentinite, in deionized water, by use of three different extraction techniques. The first extraction technique included the use of a rotary mixer, the second technique involved the use of a microwave digestion system with different extraction temperatures, and the third technique employed an ultrasonic bath with different extraction times. Ion chromatography was used for determining the concentration of Li, Na, K, Ca, Mg and ammonium ions in soil extracts with subsequent determination of concentrations for all cations, except for ammonium ion extraction, conducted by Inductively Coupled Plasma-Atomic Emission Spectrometry. The results of cation extractions showed that microwave assisted extraction was most efficient for the Li, Na, K, Ca, Mg, Co, Mn, Ni, Pb and ammonium ions. Use of a rotary mixer for extraction was most efficient for Cd and Zn ions, while use of ultrasound bath was most efficient for Cr, Cu, Fe and Al ions. Several times higher amount of cations extracted by the most efficient, compared to the second best technique, under optimal conditions, were noticed in the case of: Ca, Mg, Co, Mn, Fe, Al, and Zn ions.", publisher = "Versita, Warsaw", journal = "Central European Journal of Chemistry", title = "The comparison of sample extraction procedures for the determination of cations in soil by IC and ICP-AES", volume = "9", number = "3", pages = "481-491", doi = "10.2478/s11532-011-0031-9" }
Stanišić, S. M., Ignjatovic, L. M., Manojlović, D. D.,& Dojčinović, B. P.. (2011). The comparison of sample extraction procedures for the determination of cations in soil by IC and ICP-AES. in Central European Journal of Chemistry Versita, Warsaw., 9(3), 481-491. https://doi.org/10.2478/s11532-011-0031-9
Stanišić SM, Ignjatovic LM, Manojlović DD, Dojčinović BP. The comparison of sample extraction procedures for the determination of cations in soil by IC and ICP-AES. in Central European Journal of Chemistry. 2011;9(3):481-491. doi:10.2478/s11532-011-0031-9 .
Stanišić, Svetlana M., Ignjatovic, Ljubisa M., Manojlović, Dragan D., Dojčinović, Biljana P., "The comparison of sample extraction procedures for the determination of cations in soil by IC and ICP-AES" in Central European Journal of Chemistry, 9, no. 3 (2011):481-491, https://doi.org/10.2478/s11532-011-0031-9 . .