Fractionation of soil phosphorus in a long-term phosphate fertilization
Frakcionisanje fosfora u zemljištu nakon dugotrajne primene fosfornog đubriva
2012
Authors
Amaizah, Nasser RamdanČakmak, Dragan
Saljnikov, Elmira
Roglić, Goran
Mrvic, Vesna
Krgović, Rada
Manojlović, Dragan D.
Article (Published version)
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The changes in inorganic and organic phosphorus (P) fractions of soil resulting from long-term fertilization (40 years) were investigated. In order to improve understanding of the sink and sources of phosphorus, P-fractions were extracted from soil samples from depths of 0-30 and 30-60 cm with different amounts of monoammonium-phosphate (MAP) and then determined. The studied soil was of the Stagnosol type. Phosphate fertilizer was applied in 26, 39 and 52 kg P ha(-1) amounts during a period of 40 years. Samples were subjected to sequential extraction according to a modified Chang and Jackson method and the Community Bureau of Reference (BCR) sequential extraction procedure in order to extract different forms of phosphorus. The certified reference material CRM 684 (river sediment extractable phosphorus) was used to confirm the accuracy of the instrument and of both employed methods. Furthermore, the association of phosphorus with substrates was provided by comparison of the results of s...equential methods of phosphorus species with the sequential extraction of metals (Fe, Al, Mn and Ca). The results of continuous fertilization during 40 years indicated increases of all forms phosphorus in the soil except of phosphorus bound to calcium and organic phosphorus. Application of higher amounts of P-fertilizer resulted in the dominance of the Al P fraction in the studied soil, which indicated that this fraction was the most responsible for the migration of phosphorus along the soil profile.
U ovom radu ispitivane su promene u frakcijama neorganskog i organskog fosfora (P) u zemljištu koje su izazvane 40 godišnjim đubrenjem amonijum-fosfatom (MAR). Đubrivo je dodavano u količinama od 26, 39 i 52 kg P po hektaru zemljišta. U cilju praćenja mobilnosti fosfora, ekstrahovane su fosforne frakcije sa dve različite dubine zemljišta: površinski sloj od 0-30 cm i dubina od 30-60 cm. Tip ispitivanog zemljišta je Stagnosol. Uzorci su u cilju ekstrahovanja različitih oblika fosfora podvrgnuti sekvencijalnoj ekstrakciji i to na dva načina: prema modifikovanoj Chang i Jackson metodi i BCR metodi. Sertifikovani referentni materijal CRM 684 (rečni sediment) je korišćen za praćenje tačnosti obe korišćene metode. Osim toga je proučeno vezivanje fosfora sa supstratima (Fe, Al, Mn i Ca) koji su ekstrahovani sekvencijalnom ekstrakcijom metala. Rezultati ukazuju da kontinualno 40 godišnje đubrenje dovodi do povećanja sadržaja svih oblika fosfora u zemljištu osim fosfora koji je vezan za kalciju...m i organskog fosfora. Primenom veće količine fosfornog đubriva dolazi do dominacije frakcije fosfora vezanog za aluminijum u ispitivanom zemljištu što ukazuje da je ta frakcija najodgovornija za migraciju fosfora kroz zemljište.
Keywords:
phosphorus / soil fertilization / soil fertilization / sequential extraction / sequential extraction / CRM 684 / CRM 684Source:
Journal of the Serbian Chemical Society, 2012, 77, 7, 971-981Publisher:
- Serbian Chemical Soc, Belgrade
DOI: 10.2298/JSC110927208A
ISSN: 0352-5139
WoS: 000308382800012
Scopus: 2-s2.0-84864594020
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Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Amaizah, Nasser Ramdan AU - Čakmak, Dragan AU - Saljnikov, Elmira AU - Roglić, Goran AU - Mrvic, Vesna AU - Krgović, Rada AU - Manojlović, Dragan D. PY - 2012 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1529 AB - The changes in inorganic and organic phosphorus (P) fractions of soil resulting from long-term fertilization (40 years) were investigated. In order to improve understanding of the sink and sources of phosphorus, P-fractions were extracted from soil samples from depths of 0-30 and 30-60 cm with different amounts of monoammonium-phosphate (MAP) and then determined. The studied soil was of the Stagnosol type. Phosphate fertilizer was applied in 26, 39 and 52 kg P ha(-1) amounts during a period of 40 years. Samples were subjected to sequential extraction according to a modified Chang and Jackson method and the Community Bureau of Reference (BCR) sequential extraction procedure in order to extract different forms of phosphorus. The certified reference material CRM 684 (river sediment extractable phosphorus) was used to confirm the accuracy of the instrument and of both employed methods. Furthermore, the association of phosphorus with substrates was provided by comparison of the results of sequential methods of phosphorus species with the sequential extraction of metals (Fe, Al, Mn and Ca). The results of continuous fertilization during 40 years indicated increases of all forms phosphorus in the soil except of phosphorus bound to calcium and organic phosphorus. Application of higher amounts of P-fertilizer resulted in the dominance of the Al P fraction in the studied soil, which indicated that this fraction was the most responsible for the migration of phosphorus along the soil profile. AB - U ovom radu ispitivane su promene u frakcijama neorganskog i organskog fosfora (P) u zemljištu koje su izazvane 40 godišnjim đubrenjem amonijum-fosfatom (MAR). Đubrivo je dodavano u količinama od 26, 39 i 52 kg P po hektaru zemljišta. U cilju praćenja mobilnosti fosfora, ekstrahovane su fosforne frakcije sa dve različite dubine zemljišta: površinski sloj od 0-30 cm i dubina od 30-60 cm. Tip ispitivanog zemljišta je Stagnosol. Uzorci su u cilju ekstrahovanja različitih oblika fosfora podvrgnuti sekvencijalnoj ekstrakciji i to na dva načina: prema modifikovanoj Chang i Jackson metodi i BCR metodi. Sertifikovani referentni materijal CRM 684 (rečni sediment) je korišćen za praćenje tačnosti obe korišćene metode. Osim toga je proučeno vezivanje fosfora sa supstratima (Fe, Al, Mn i Ca) koji su ekstrahovani sekvencijalnom ekstrakcijom metala. Rezultati ukazuju da kontinualno 40 godišnje đubrenje dovodi do povećanja sadržaja svih oblika fosfora u zemljištu osim fosfora koji je vezan za kalcijum i organskog fosfora. Primenom veće količine fosfornog đubriva dolazi do dominacije frakcije fosfora vezanog za aluminijum u ispitivanom zemljištu što ukazuje da je ta frakcija najodgovornija za migraciju fosfora kroz zemljište. PB - Serbian Chemical Soc, Belgrade T2 - Journal of the Serbian Chemical Society T1 - Fractionation of soil phosphorus in a long-term phosphate fertilization T1 - Frakcionisanje fosfora u zemljištu nakon dugotrajne primene fosfornog đubriva VL - 77 IS - 7 SP - 971 EP - 981 DO - 10.2298/JSC110927208A ER -
@article{ author = "Amaizah, Nasser Ramdan and Čakmak, Dragan and Saljnikov, Elmira and Roglić, Goran and Mrvic, Vesna and Krgović, Rada and Manojlović, Dragan D.", year = "2012", abstract = "The changes in inorganic and organic phosphorus (P) fractions of soil resulting from long-term fertilization (40 years) were investigated. In order to improve understanding of the sink and sources of phosphorus, P-fractions were extracted from soil samples from depths of 0-30 and 30-60 cm with different amounts of monoammonium-phosphate (MAP) and then determined. The studied soil was of the Stagnosol type. Phosphate fertilizer was applied in 26, 39 and 52 kg P ha(-1) amounts during a period of 40 years. Samples were subjected to sequential extraction according to a modified Chang and Jackson method and the Community Bureau of Reference (BCR) sequential extraction procedure in order to extract different forms of phosphorus. The certified reference material CRM 684 (river sediment extractable phosphorus) was used to confirm the accuracy of the instrument and of both employed methods. Furthermore, the association of phosphorus with substrates was provided by comparison of the results of sequential methods of phosphorus species with the sequential extraction of metals (Fe, Al, Mn and Ca). The results of continuous fertilization during 40 years indicated increases of all forms phosphorus in the soil except of phosphorus bound to calcium and organic phosphorus. Application of higher amounts of P-fertilizer resulted in the dominance of the Al P fraction in the studied soil, which indicated that this fraction was the most responsible for the migration of phosphorus along the soil profile., U ovom radu ispitivane su promene u frakcijama neorganskog i organskog fosfora (P) u zemljištu koje su izazvane 40 godišnjim đubrenjem amonijum-fosfatom (MAR). Đubrivo je dodavano u količinama od 26, 39 i 52 kg P po hektaru zemljišta. U cilju praćenja mobilnosti fosfora, ekstrahovane su fosforne frakcije sa dve različite dubine zemljišta: površinski sloj od 0-30 cm i dubina od 30-60 cm. Tip ispitivanog zemljišta je Stagnosol. Uzorci su u cilju ekstrahovanja različitih oblika fosfora podvrgnuti sekvencijalnoj ekstrakciji i to na dva načina: prema modifikovanoj Chang i Jackson metodi i BCR metodi. Sertifikovani referentni materijal CRM 684 (rečni sediment) je korišćen za praćenje tačnosti obe korišćene metode. Osim toga je proučeno vezivanje fosfora sa supstratima (Fe, Al, Mn i Ca) koji su ekstrahovani sekvencijalnom ekstrakcijom metala. Rezultati ukazuju da kontinualno 40 godišnje đubrenje dovodi do povećanja sadržaja svih oblika fosfora u zemljištu osim fosfora koji je vezan za kalcijum i organskog fosfora. Primenom veće količine fosfornog đubriva dolazi do dominacije frakcije fosfora vezanog za aluminijum u ispitivanom zemljištu što ukazuje da je ta frakcija najodgovornija za migraciju fosfora kroz zemljište.", publisher = "Serbian Chemical Soc, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "Fractionation of soil phosphorus in a long-term phosphate fertilization, Frakcionisanje fosfora u zemljištu nakon dugotrajne primene fosfornog đubriva", volume = "77", number = "7", pages = "971-981", doi = "10.2298/JSC110927208A" }
Amaizah, N. R., Čakmak, D., Saljnikov, E., Roglić, G., Mrvic, V., Krgović, R.,& Manojlović, D. D.. (2012). Fractionation of soil phosphorus in a long-term phosphate fertilization. in Journal of the Serbian Chemical Society Serbian Chemical Soc, Belgrade., 77(7), 971-981. https://doi.org/10.2298/JSC110927208A
Amaizah NR, Čakmak D, Saljnikov E, Roglić G, Mrvic V, Krgović R, Manojlović DD. Fractionation of soil phosphorus in a long-term phosphate fertilization. in Journal of the Serbian Chemical Society. 2012;77(7):971-981. doi:10.2298/JSC110927208A .
Amaizah, Nasser Ramdan, Čakmak, Dragan, Saljnikov, Elmira, Roglić, Goran, Mrvic, Vesna, Krgović, Rada, Manojlović, Dragan D., "Fractionation of soil phosphorus in a long-term phosphate fertilization" in Journal of the Serbian Chemical Society, 77, no. 7 (2012):971-981, https://doi.org/10.2298/JSC110927208A . .