Development and validation of a simple thin-layer chromatographic method for the analysis of p-chlorophenol in treated wastewater
Validacija tankoslojne hromatografije kao metode za jednostavno određivanje p-hlorfenola u tretiranoj otpadnoj vodi
2012
Аутори
Natić, MajaDabić Zagorac, Dragana
Milojković-Opsenica, Dušanka
Dojčinović, Biljana P.
Roglić, Goran
Manojlović, Dragan D.
Tešić, Živoslav Lj.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
A thin-layer chromatographic (TLC) method with densitometric detection was established for the quantification of p-chlorophenol in wastewater. Degradation efficiency of p-chlorophenol was monitored after each treatment of the wastewater samples. Degradation of p-chlorophenol was performed by advanced oxidation processes (AOPs), using UV, H2O2/UV, O-3/H2O2/UV, O-3 and O-3/UV. The developed TLC procedure was found to be simple, rapid and precise. The method is characterized by high sensitivity (the limit of detection was 11 ng per band and limit of quantification 35 ng per band), a linear range from 75 to 500 ng per band, r = 0.9965), and high precision, accuracy (mean percentage recovery 98.6 %), and specificity. Additionally, the efficiency of degradation was monitored using HPLC giving comparable results with the reversed phase TLC measurements.
Kvantifikacija p-hlorfenola u uzorcima otpadnih voda urađena je primenom tankoslojne hromatografije sa denzitometrijskom detekcijom. Efikasnost degradacije p-hlorfenola praćena je nakon svakog tretmana uzorka otpadne vode. UV svetlost, O3, kao i kombinacija H2O2/UV, O3/H2O2/UV i O3/UV su korišćeni za degradaciju p-hlorfenola. Primenjen TLC postupak je jednostavan, brz i precizan. Visoka osetljivost (limit detekcije je 11 ng po traci i limit kvantifikacije je 35 ng po traci), opseg linearnosti (od 75 do 500 ng po traci, r = 0,9965), visoka preciznost i tačnost, kao i specifičnost su karakteristike korišćenog TLC postupka. HPLC metoda, kao standardna metoda za određivanje p-hlorfenola je takođe primenjena za proučavanje efikasnosti postupka degradacije. Rezultati dobijeni primenom TLC metode su uporedivi sa HPLC merenjima.
Кључне речи:
p-chlorophenol / TLC-scanner / TLC-scanner / HPLC / HPLC / AOPs / AOPs / wastewater treatment / wastewater treatmentИзвор:
Journal of the Serbian Chemical Society, 2012, 77, 11, 1649-1659Издавач:
- Serbian Chemical Soc, Belgrade
Финансирање / пројекти:
- Корелација структуре и особина природних и синтетичких молекула и њихових комплекса са металима (RS-172017)
DOI: 10.2298/JSC120509087N
ISSN: 0352-5139
WoS: 000312746700012
Scopus: 2-s2.0-84871845478
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Natić, Maja AU - Dabić Zagorac, Dragana AU - Milojković-Opsenica, Dušanka AU - Dojčinović, Biljana P. AU - Roglić, Goran AU - Manojlović, Dragan D. AU - Tešić, Živoslav Lj. PY - 2012 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1570 AB - A thin-layer chromatographic (TLC) method with densitometric detection was established for the quantification of p-chlorophenol in wastewater. Degradation efficiency of p-chlorophenol was monitored after each treatment of the wastewater samples. Degradation of p-chlorophenol was performed by advanced oxidation processes (AOPs), using UV, H2O2/UV, O-3/H2O2/UV, O-3 and O-3/UV. The developed TLC procedure was found to be simple, rapid and precise. The method is characterized by high sensitivity (the limit of detection was 11 ng per band and limit of quantification 35 ng per band), a linear range from 75 to 500 ng per band, r = 0.9965), and high precision, accuracy (mean percentage recovery 98.6 %), and specificity. Additionally, the efficiency of degradation was monitored using HPLC giving comparable results with the reversed phase TLC measurements. AB - Kvantifikacija p-hlorfenola u uzorcima otpadnih voda urađena je primenom tankoslojne hromatografije sa denzitometrijskom detekcijom. Efikasnost degradacije p-hlorfenola praćena je nakon svakog tretmana uzorka otpadne vode. UV svetlost, O3, kao i kombinacija H2O2/UV, O3/H2O2/UV i O3/UV su korišćeni za degradaciju p-hlorfenola. Primenjen TLC postupak je jednostavan, brz i precizan. Visoka osetljivost (limit detekcije je 11 ng po traci i limit kvantifikacije je 35 ng po traci), opseg linearnosti (od 75 do 500 ng po traci, r = 0,9965), visoka preciznost i tačnost, kao i specifičnost su karakteristike korišćenog TLC postupka. HPLC metoda, kao standardna metoda za određivanje p-hlorfenola je takođe primenjena za proučavanje efikasnosti postupka degradacije. Rezultati dobijeni primenom TLC metode su uporedivi sa HPLC merenjima. PB - Serbian Chemical Soc, Belgrade T2 - Journal of the Serbian Chemical Society T1 - Development and validation of a simple thin-layer chromatographic method for the analysis of p-chlorophenol in treated wastewater T1 - Validacija tankoslojne hromatografije kao metode za jednostavno određivanje p-hlorfenola u tretiranoj otpadnoj vodi VL - 77 IS - 11 SP - 1649 EP - 1659 DO - 10.2298/JSC120509087N ER -
@article{ author = "Natić, Maja and Dabić Zagorac, Dragana and Milojković-Opsenica, Dušanka and Dojčinović, Biljana P. and Roglić, Goran and Manojlović, Dragan D. and Tešić, Živoslav Lj.", year = "2012", abstract = "A thin-layer chromatographic (TLC) method with densitometric detection was established for the quantification of p-chlorophenol in wastewater. Degradation efficiency of p-chlorophenol was monitored after each treatment of the wastewater samples. Degradation of p-chlorophenol was performed by advanced oxidation processes (AOPs), using UV, H2O2/UV, O-3/H2O2/UV, O-3 and O-3/UV. The developed TLC procedure was found to be simple, rapid and precise. The method is characterized by high sensitivity (the limit of detection was 11 ng per band and limit of quantification 35 ng per band), a linear range from 75 to 500 ng per band, r = 0.9965), and high precision, accuracy (mean percentage recovery 98.6 %), and specificity. Additionally, the efficiency of degradation was monitored using HPLC giving comparable results with the reversed phase TLC measurements., Kvantifikacija p-hlorfenola u uzorcima otpadnih voda urađena je primenom tankoslojne hromatografije sa denzitometrijskom detekcijom. Efikasnost degradacije p-hlorfenola praćena je nakon svakog tretmana uzorka otpadne vode. UV svetlost, O3, kao i kombinacija H2O2/UV, O3/H2O2/UV i O3/UV su korišćeni za degradaciju p-hlorfenola. Primenjen TLC postupak je jednostavan, brz i precizan. Visoka osetljivost (limit detekcije je 11 ng po traci i limit kvantifikacije je 35 ng po traci), opseg linearnosti (od 75 do 500 ng po traci, r = 0,9965), visoka preciznost i tačnost, kao i specifičnost su karakteristike korišćenog TLC postupka. HPLC metoda, kao standardna metoda za određivanje p-hlorfenola je takođe primenjena za proučavanje efikasnosti postupka degradacije. Rezultati dobijeni primenom TLC metode su uporedivi sa HPLC merenjima.", publisher = "Serbian Chemical Soc, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "Development and validation of a simple thin-layer chromatographic method for the analysis of p-chlorophenol in treated wastewater, Validacija tankoslojne hromatografije kao metode za jednostavno određivanje p-hlorfenola u tretiranoj otpadnoj vodi", volume = "77", number = "11", pages = "1649-1659", doi = "10.2298/JSC120509087N" }
Natić, M., Dabić Zagorac, D., Milojković-Opsenica, D., Dojčinović, B. P., Roglić, G., Manojlović, D. D.,& Tešić, Ž. Lj.. (2012). Development and validation of a simple thin-layer chromatographic method for the analysis of p-chlorophenol in treated wastewater. in Journal of the Serbian Chemical Society Serbian Chemical Soc, Belgrade., 77(11), 1649-1659. https://doi.org/10.2298/JSC120509087N
Natić M, Dabić Zagorac D, Milojković-Opsenica D, Dojčinović BP, Roglić G, Manojlović DD, Tešić ŽL. Development and validation of a simple thin-layer chromatographic method for the analysis of p-chlorophenol in treated wastewater. in Journal of the Serbian Chemical Society. 2012;77(11):1649-1659. doi:10.2298/JSC120509087N .
Natić, Maja, Dabić Zagorac, Dragana, Milojković-Opsenica, Dušanka, Dojčinović, Biljana P., Roglić, Goran, Manojlović, Dragan D., Tešić, Živoslav Lj., "Development and validation of a simple thin-layer chromatographic method for the analysis of p-chlorophenol in treated wastewater" in Journal of the Serbian Chemical Society, 77, no. 11 (2012):1649-1659, https://doi.org/10.2298/JSC120509087N . .