3D electrogenerated chemiluminescence: from surface-confined reactions to bulk emission
2015
Аутори
Sentić, MilicaArbault, Stephane
Bouffier, Laurent
Manojlović, Dragan D.
Kuhn, Alexander
Šojić, Nešo
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Among luminescence techniques, electrogenerated chemiluminescence (ECL) provides a unique level of manipulation of the luminescent process by controlling the electrochemical trigger. Despite its attractiveness, ECL is by essence a 2D process where light emission is strictly confined to the electrode surface. To overcome this intrinsic limitation, we added a new spatial dimension to the ECL process by generating 3D ECL at the level of millions of micro-emitters dispersed in solution. Each single object is addressed remotely by bipolar electrochemistry and they generate collectively the luminescence in the bulk. Therefore, the entire volume of the solution produces light. To illustrate the generality of this concept, we extended it to a suspension of multi-walled carbon nanotubes where each one acts as an individual ECL nano-emitter. This approach enables a change of paradigm by switching from a surface-limited process to 3D electrogenerated light emission.
Извор:
Chemical Science, 2015, 6, 8, 4433-4437Издавач:
- Royal Soc Chemistry, Cambridge
Финансирање / пројекти:
- French Foreign Ministry (Bourse dExcellence Eiffel)
- Ministry of Science and Technological Development (Republic of Serbia)
DOI: 10.1039/c5sc01530h
ISSN: 2041-6520
PubMed: 28717470
WoS: 000357931700003
Scopus: 2-s2.0-84937114985
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Sentić, Milica AU - Arbault, Stephane AU - Bouffier, Laurent AU - Manojlović, Dragan D. AU - Kuhn, Alexander AU - Šojić, Nešo PY - 2015 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1737 AB - Among luminescence techniques, electrogenerated chemiluminescence (ECL) provides a unique level of manipulation of the luminescent process by controlling the electrochemical trigger. Despite its attractiveness, ECL is by essence a 2D process where light emission is strictly confined to the electrode surface. To overcome this intrinsic limitation, we added a new spatial dimension to the ECL process by generating 3D ECL at the level of millions of micro-emitters dispersed in solution. Each single object is addressed remotely by bipolar electrochemistry and they generate collectively the luminescence in the bulk. Therefore, the entire volume of the solution produces light. To illustrate the generality of this concept, we extended it to a suspension of multi-walled carbon nanotubes where each one acts as an individual ECL nano-emitter. This approach enables a change of paradigm by switching from a surface-limited process to 3D electrogenerated light emission. PB - Royal Soc Chemistry, Cambridge T2 - Chemical Science T1 - 3D electrogenerated chemiluminescence: from surface-confined reactions to bulk emission VL - 6 IS - 8 SP - 4433 EP - 4437 DO - 10.1039/c5sc01530h ER -
@article{ author = "Sentić, Milica and Arbault, Stephane and Bouffier, Laurent and Manojlović, Dragan D. and Kuhn, Alexander and Šojić, Nešo", year = "2015", abstract = "Among luminescence techniques, electrogenerated chemiluminescence (ECL) provides a unique level of manipulation of the luminescent process by controlling the electrochemical trigger. Despite its attractiveness, ECL is by essence a 2D process where light emission is strictly confined to the electrode surface. To overcome this intrinsic limitation, we added a new spatial dimension to the ECL process by generating 3D ECL at the level of millions of micro-emitters dispersed in solution. Each single object is addressed remotely by bipolar electrochemistry and they generate collectively the luminescence in the bulk. Therefore, the entire volume of the solution produces light. To illustrate the generality of this concept, we extended it to a suspension of multi-walled carbon nanotubes where each one acts as an individual ECL nano-emitter. This approach enables a change of paradigm by switching from a surface-limited process to 3D electrogenerated light emission.", publisher = "Royal Soc Chemistry, Cambridge", journal = "Chemical Science", title = "3D electrogenerated chemiluminescence: from surface-confined reactions to bulk emission", volume = "6", number = "8", pages = "4433-4437", doi = "10.1039/c5sc01530h" }
Sentić, M., Arbault, S., Bouffier, L., Manojlović, D. D., Kuhn, A.,& Šojić, N.. (2015). 3D electrogenerated chemiluminescence: from surface-confined reactions to bulk emission. in Chemical Science Royal Soc Chemistry, Cambridge., 6(8), 4433-4437. https://doi.org/10.1039/c5sc01530h
Sentić M, Arbault S, Bouffier L, Manojlović DD, Kuhn A, Šojić N. 3D electrogenerated chemiluminescence: from surface-confined reactions to bulk emission. in Chemical Science. 2015;6(8):4433-4437. doi:10.1039/c5sc01530h .
Sentić, Milica, Arbault, Stephane, Bouffier, Laurent, Manojlović, Dragan D., Kuhn, Alexander, Šojić, Nešo, "3D electrogenerated chemiluminescence: from surface-confined reactions to bulk emission" in Chemical Science, 6, no. 8 (2015):4433-4437, https://doi.org/10.1039/c5sc01530h . .