Degradation and detoxification of the 4-chlorophenol by non-thermal plasma-influence of homogeneous catalysts
Samo za registrovane korisnike
2015
Autori
Marković, MarijanaDojčinović, Biljana P.
Obradović, Bratislav M.
Nešić, Jelena
Natić, Maja
Tosti, Tomislav
Kuraica, Milorad M.
Manojlović, Dragan D.
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Experimental results of non-thermal plasma (NTP) utilization for degradation of 4-chlorphenol (4CP) with screening of toxicity were presented in this study. Degradation of 4CP was tested in the presence of homogeneous catalysts: hydrogen peroxide (H2O2) and iron (II) (Fe2+). The rate of degradation through eight consecutive passes of the 4CP solution in the NTP reactor was considered. Products of degradation as organic acids (acetic, formic or oxalic acid) and chloride were quantified using ion chromatography (IC). Anemia salina was used for the toxicity screening assay in order to estimate the potential and consequences of NTP reactor application in water treatment. The measured concentration of 4CP and degradation products confirmed very efficient removal of these substances from the water during the NTP treatment with the addition of a catalyst. Concerning bioassay, a significant difference in toxicity was determined between initial solution of 4CP in comparison with the solution ex...posed to catalytic NTP treatment. (C) 2015 Elsevier B.V. All rights reserved.
Ključne reči:
Advanced oxidation processes (AOP) / 4-Chlorphenol / Dielectric barrier discharge (DBD) / Ecotoxicity / Non-thermal plasma (NTP)Izvor:
Separation and Purification Technology, 2015, 154, 246-254Izdavač:
- Elsevier Science Bv, Amsterdam
Finansiranje / projekti:
- Primena unapređenih oksidacionih procesa i nanostrukturisanih oksidnih materijala za uklanjanje zagađivača iz životne sredine, razvoj i optimizacija instrumentalnih tehnika za praćenje efikasnosti (RS-MESTD-Basic Research (BR or ON)-172030)
- Simultana bioremedijacija i soilifikacija degradiranih prostora, za očuvanje prirodnih resursa biološki aktivnih supstanci i razvoj i proizvodnju biomaterijala i dijetetskih proizvoda (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-43004)
DOI: 10.1016/j.seppur.2015.09.030
ISSN: 1383-5866
WoS: 000364245500031
Scopus: 2-s2.0-84942890822
Kolekcije
Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Marković, Marijana AU - Dojčinović, Biljana P. AU - Obradović, Bratislav M. AU - Nešić, Jelena AU - Natić, Maja AU - Tosti, Tomislav AU - Kuraica, Milorad M. AU - Manojlović, Dragan D. PY - 2015 UR - https://cherry.chem.bg.ac.rs/handle/123456789/1995 AB - Experimental results of non-thermal plasma (NTP) utilization for degradation of 4-chlorphenol (4CP) with screening of toxicity were presented in this study. Degradation of 4CP was tested in the presence of homogeneous catalysts: hydrogen peroxide (H2O2) and iron (II) (Fe2+). The rate of degradation through eight consecutive passes of the 4CP solution in the NTP reactor was considered. Products of degradation as organic acids (acetic, formic or oxalic acid) and chloride were quantified using ion chromatography (IC). Anemia salina was used for the toxicity screening assay in order to estimate the potential and consequences of NTP reactor application in water treatment. The measured concentration of 4CP and degradation products confirmed very efficient removal of these substances from the water during the NTP treatment with the addition of a catalyst. Concerning bioassay, a significant difference in toxicity was determined between initial solution of 4CP in comparison with the solution exposed to catalytic NTP treatment. (C) 2015 Elsevier B.V. All rights reserved. PB - Elsevier Science Bv, Amsterdam T2 - Separation and Purification Technology T1 - Degradation and detoxification of the 4-chlorophenol by non-thermal plasma-influence of homogeneous catalysts VL - 154 SP - 246 EP - 254 DO - 10.1016/j.seppur.2015.09.030 ER -
@article{ author = "Marković, Marijana and Dojčinović, Biljana P. and Obradović, Bratislav M. and Nešić, Jelena and Natić, Maja and Tosti, Tomislav and Kuraica, Milorad M. and Manojlović, Dragan D.", year = "2015", abstract = "Experimental results of non-thermal plasma (NTP) utilization for degradation of 4-chlorphenol (4CP) with screening of toxicity were presented in this study. Degradation of 4CP was tested in the presence of homogeneous catalysts: hydrogen peroxide (H2O2) and iron (II) (Fe2+). The rate of degradation through eight consecutive passes of the 4CP solution in the NTP reactor was considered. Products of degradation as organic acids (acetic, formic or oxalic acid) and chloride were quantified using ion chromatography (IC). Anemia salina was used for the toxicity screening assay in order to estimate the potential and consequences of NTP reactor application in water treatment. The measured concentration of 4CP and degradation products confirmed very efficient removal of these substances from the water during the NTP treatment with the addition of a catalyst. Concerning bioassay, a significant difference in toxicity was determined between initial solution of 4CP in comparison with the solution exposed to catalytic NTP treatment. (C) 2015 Elsevier B.V. All rights reserved.", publisher = "Elsevier Science Bv, Amsterdam", journal = "Separation and Purification Technology", title = "Degradation and detoxification of the 4-chlorophenol by non-thermal plasma-influence of homogeneous catalysts", volume = "154", pages = "246-254", doi = "10.1016/j.seppur.2015.09.030" }
Marković, M., Dojčinović, B. P., Obradović, B. M., Nešić, J., Natić, M., Tosti, T., Kuraica, M. M.,& Manojlović, D. D.. (2015). Degradation and detoxification of the 4-chlorophenol by non-thermal plasma-influence of homogeneous catalysts. in Separation and Purification Technology Elsevier Science Bv, Amsterdam., 154, 246-254. https://doi.org/10.1016/j.seppur.2015.09.030
Marković M, Dojčinović BP, Obradović BM, Nešić J, Natić M, Tosti T, Kuraica MM, Manojlović DD. Degradation and detoxification of the 4-chlorophenol by non-thermal plasma-influence of homogeneous catalysts. in Separation and Purification Technology. 2015;154:246-254. doi:10.1016/j.seppur.2015.09.030 .
Marković, Marijana, Dojčinović, Biljana P., Obradović, Bratislav M., Nešić, Jelena, Natić, Maja, Tosti, Tomislav, Kuraica, Milorad M., Manojlović, Dragan D., "Degradation and detoxification of the 4-chlorophenol by non-thermal plasma-influence of homogeneous catalysts" in Separation and Purification Technology, 154 (2015):246-254, https://doi.org/10.1016/j.seppur.2015.09.030 . .