Identification of Different Sources and Forms of Arsenic in the Vicinity of Ore Mining in Serbia
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Аутори
Čakmak, DraganSaljnikov, Elmira
Škrivanj, Sandra B.
Roglić, Goran
Bakrac, Sasa
Sikiric, Biljana
Manojlović, Dragan D.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Plant available arsenic (As) is not defined by its total content but by the various forms in soil. The aims of this study were to determine the amounts of As phases in soils extracted in the vicinity of the antimony mines; to study soil surface processes affecting formation of most mobile phases of As and the identification of sources of As phases in C soil horizon. Five fractions of soil As were determined by sequential extraction analyses (As F1, As F 2, As F 3, As F 4 and As F 5) in A and C horizons. The identification of the origin of As fractions were made by mean of principal component analyses (PCA) including Pearson correlations. The amount of the most mobile forms of As (As F1 and F2) was below 1%. The content of As F1, As F2 and As F4 decrease with soil depth, while aqua regia As and phases F3 and F5 increase with depth. Principal component analyses (PCA) showed that the content of As F2 is affected by anthropogenic factor and the content of As F4 by biological factor. In C h...orizon, As F2 and F4 are influenced by the leaching processes in soil. Arsenic F5 is bound to sediment rocks. The soil surface processes increases the availability of As in soil. The most mobile forms of As were found in deeper soil horizon that is due to the leaching of As with water from biological sources. The content of semi available phase of As F3 increases with depth, with stronger bounds due to the linkage to the amorphous Fe hydroxides.
Кључне речи:
arsenic / soil / sequential extraction / PCAИзвор:
Fresenius Environmental Bulletin, 2015, 24, 12B, 4635-4643Издавач:
- Parlar Scientific Publications (P S P), Freising
Финансирање / пројекти:
- Проучавање утицаја квалитета земљишта и вода за наводњавање на ефикаснију производњу пољопривредних култура и очување животне средине (RS-MESTD-Technological Development (TD or TR)-37006)
- Испитивање могућности коришћења контаминираних вода за гајење алтернативних, здравствено безбедних жита (RS-MESTD-Technological Development (TD or TR)-31006)
- University of Belgrade
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Čakmak, Dragan AU - Saljnikov, Elmira AU - Škrivanj, Sandra B. AU - Roglić, Goran AU - Bakrac, Sasa AU - Sikiric, Biljana AU - Manojlović, Dragan D. PY - 2015 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2027 AB - Plant available arsenic (As) is not defined by its total content but by the various forms in soil. The aims of this study were to determine the amounts of As phases in soils extracted in the vicinity of the antimony mines; to study soil surface processes affecting formation of most mobile phases of As and the identification of sources of As phases in C soil horizon. Five fractions of soil As were determined by sequential extraction analyses (As F1, As F 2, As F 3, As F 4 and As F 5) in A and C horizons. The identification of the origin of As fractions were made by mean of principal component analyses (PCA) including Pearson correlations. The amount of the most mobile forms of As (As F1 and F2) was below 1%. The content of As F1, As F2 and As F4 decrease with soil depth, while aqua regia As and phases F3 and F5 increase with depth. Principal component analyses (PCA) showed that the content of As F2 is affected by anthropogenic factor and the content of As F4 by biological factor. In C horizon, As F2 and F4 are influenced by the leaching processes in soil. Arsenic F5 is bound to sediment rocks. The soil surface processes increases the availability of As in soil. The most mobile forms of As were found in deeper soil horizon that is due to the leaching of As with water from biological sources. The content of semi available phase of As F3 increases with depth, with stronger bounds due to the linkage to the amorphous Fe hydroxides. PB - Parlar Scientific Publications (P S P), Freising T2 - Fresenius Environmental Bulletin T1 - Identification of Different Sources and Forms of Arsenic in the Vicinity of Ore Mining in Serbia VL - 24 IS - 12B SP - 4635 EP - 4643 UR - https://hdl.handle.net/21.15107/rcub_cherry_2027 ER -
@article{ author = "Čakmak, Dragan and Saljnikov, Elmira and Škrivanj, Sandra B. and Roglić, Goran and Bakrac, Sasa and Sikiric, Biljana and Manojlović, Dragan D.", year = "2015", abstract = "Plant available arsenic (As) is not defined by its total content but by the various forms in soil. The aims of this study were to determine the amounts of As phases in soils extracted in the vicinity of the antimony mines; to study soil surface processes affecting formation of most mobile phases of As and the identification of sources of As phases in C soil horizon. Five fractions of soil As were determined by sequential extraction analyses (As F1, As F 2, As F 3, As F 4 and As F 5) in A and C horizons. The identification of the origin of As fractions were made by mean of principal component analyses (PCA) including Pearson correlations. The amount of the most mobile forms of As (As F1 and F2) was below 1%. The content of As F1, As F2 and As F4 decrease with soil depth, while aqua regia As and phases F3 and F5 increase with depth. Principal component analyses (PCA) showed that the content of As F2 is affected by anthropogenic factor and the content of As F4 by biological factor. In C horizon, As F2 and F4 are influenced by the leaching processes in soil. Arsenic F5 is bound to sediment rocks. The soil surface processes increases the availability of As in soil. The most mobile forms of As were found in deeper soil horizon that is due to the leaching of As with water from biological sources. The content of semi available phase of As F3 increases with depth, with stronger bounds due to the linkage to the amorphous Fe hydroxides.", publisher = "Parlar Scientific Publications (P S P), Freising", journal = "Fresenius Environmental Bulletin", title = "Identification of Different Sources and Forms of Arsenic in the Vicinity of Ore Mining in Serbia", volume = "24", number = "12B", pages = "4635-4643", url = "https://hdl.handle.net/21.15107/rcub_cherry_2027" }
Čakmak, D., Saljnikov, E., Škrivanj, S. B., Roglić, G., Bakrac, S., Sikiric, B.,& Manojlović, D. D.. (2015). Identification of Different Sources and Forms of Arsenic in the Vicinity of Ore Mining in Serbia. in Fresenius Environmental Bulletin Parlar Scientific Publications (P S P), Freising., 24(12B), 4635-4643. https://hdl.handle.net/21.15107/rcub_cherry_2027
Čakmak D, Saljnikov E, Škrivanj SB, Roglić G, Bakrac S, Sikiric B, Manojlović DD. Identification of Different Sources and Forms of Arsenic in the Vicinity of Ore Mining in Serbia. in Fresenius Environmental Bulletin. 2015;24(12B):4635-4643. https://hdl.handle.net/21.15107/rcub_cherry_2027 .
Čakmak, Dragan, Saljnikov, Elmira, Škrivanj, Sandra B., Roglić, Goran, Bakrac, Sasa, Sikiric, Biljana, Manojlović, Dragan D., "Identification of Different Sources and Forms of Arsenic in the Vicinity of Ore Mining in Serbia" in Fresenius Environmental Bulletin, 24, no. 12B (2015):4635-4643, https://hdl.handle.net/21.15107/rcub_cherry_2027 .