Reevaluation of the Palladium/Carbon-Catalyzed Decarbonylation of Aliphatic Aldehydes
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2018
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Prikaz svih podataka o dokumentuApstrakt
An improved method for the decarbonylation of aliphatic aldehydes by using a commercially available Pd/C catalyst is described. The reaction conditions are suitable for linear, cyclic, or sterically demanding substrates, as they afford the corresponding alkanes in yields of up to 99%. In addition, this Pd/C-catalyzed method exhibits good functional-group tolerance. A comparison of previously reported methods with the present one showed that the reaction conditions play a crucial role in the outcome of the reaction. The method can also be applied in a two-step reaction sequence for the synthesis of industrially important compounds.
Ključne reči:
decarbonylation / aldehydes / palladium catalysis / adamantine / alkylated aromatic compounds / natural productsIzvor:
Synlett, 2018, 29, 13, 1781-1785Izdavač:
- Georg Thieme Verlag Kg, Stuttgart
Finansiranje / projekti:
- Sinteza aminohinolina i njihovih derivata kao antimalarika i inhibitora botulinum neurotoksina A (RS-MESTD-Basic Research (BR or ON)-172008)
- Reinforcement of the Faculty of Chemistry, University of Belgrade, towards becoming a Center of Excellence in the region of WB for Molecular Biotechnology and Food research (EU-FP7-256716)
Napomena:
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/3252
DOI: 10.1055/s-0037-1610433
ISSN: 0936-5214
WoS: 000440447700024
Scopus: 2-s2.0-85051072382
Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Ajdačić, Vladimir AU - Nikolić, Andrea AU - Kerner, Michael AU - Wipf, Peter AU - Opsenica, Igor PY - 2018 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2192 AB - An improved method for the decarbonylation of aliphatic aldehydes by using a commercially available Pd/C catalyst is described. The reaction conditions are suitable for linear, cyclic, or sterically demanding substrates, as they afford the corresponding alkanes in yields of up to 99%. In addition, this Pd/C-catalyzed method exhibits good functional-group tolerance. A comparison of previously reported methods with the present one showed that the reaction conditions play a crucial role in the outcome of the reaction. The method can also be applied in a two-step reaction sequence for the synthesis of industrially important compounds. PB - Georg Thieme Verlag Kg, Stuttgart T2 - Synlett T1 - Reevaluation of the Palladium/Carbon-Catalyzed Decarbonylation of Aliphatic Aldehydes VL - 29 IS - 13 SP - 1781 EP - 1785 DO - 10.1055/s-0037-1610433 ER -
@article{ author = "Ajdačić, Vladimir and Nikolić, Andrea and Kerner, Michael and Wipf, Peter and Opsenica, Igor", year = "2018", abstract = "An improved method for the decarbonylation of aliphatic aldehydes by using a commercially available Pd/C catalyst is described. The reaction conditions are suitable for linear, cyclic, or sterically demanding substrates, as they afford the corresponding alkanes in yields of up to 99%. In addition, this Pd/C-catalyzed method exhibits good functional-group tolerance. A comparison of previously reported methods with the present one showed that the reaction conditions play a crucial role in the outcome of the reaction. The method can also be applied in a two-step reaction sequence for the synthesis of industrially important compounds.", publisher = "Georg Thieme Verlag Kg, Stuttgart", journal = "Synlett", title = "Reevaluation of the Palladium/Carbon-Catalyzed Decarbonylation of Aliphatic Aldehydes", volume = "29", number = "13", pages = "1781-1785", doi = "10.1055/s-0037-1610433" }
Ajdačić, V., Nikolić, A., Kerner, M., Wipf, P.,& Opsenica, I.. (2018). Reevaluation of the Palladium/Carbon-Catalyzed Decarbonylation of Aliphatic Aldehydes. in Synlett Georg Thieme Verlag Kg, Stuttgart., 29(13), 1781-1785. https://doi.org/10.1055/s-0037-1610433
Ajdačić V, Nikolić A, Kerner M, Wipf P, Opsenica I. Reevaluation of the Palladium/Carbon-Catalyzed Decarbonylation of Aliphatic Aldehydes. in Synlett. 2018;29(13):1781-1785. doi:10.1055/s-0037-1610433 .
Ajdačić, Vladimir, Nikolić, Andrea, Kerner, Michael, Wipf, Peter, Opsenica, Igor, "Reevaluation of the Palladium/Carbon-Catalyzed Decarbonylation of Aliphatic Aldehydes" in Synlett, 29, no. 13 (2018):1781-1785, https://doi.org/10.1055/s-0037-1610433 . .