mer-[2'-(2-Benzoyl-1-methylethylidene)-1-napthtohydrazido(2-)](methanol)-cis-dioxo-molybdenum(VI)
Abstract
In the molecule of the title compound, [MoO2(L)(CH3-OH)] [L is the dianion of 2'-(2-benzoyl-1-methylethylidene)-1-naphthohydrazide, C21H16N2O2], the Mo atom displays distorted octahedral coordination geometry, being coordinated by two mutually cis oxo ligands, the methanol O atom and the tridentate ligand L bonded through the azomethine N atom, the enolic O atom and the oxazine O atom (equatorially disposed). The packing in the crystal structure involves a hydrogen bond from the methanol OH as donor to an oxo ligand as acceptor.
Source:
Acta Crystallographica. Section C: Crystal Structure Communications, 1996, 52, 1375-1377Publisher:
- Munksgaard Int Publ Ltd, Copenhagen
DOI: 10.1107/S010827019600039X
ISSN: 0108-2701
WoS: A1996UX29800025
Scopus: 2-s2.0-3142570781
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Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Prelesnik, B AU - Ivanović, I. AU - Leovac, Vukadin M. AU - Anđelković, Katarina K. PY - 1996 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2243 AB - In the molecule of the title compound, [MoO2(L)(CH3-OH)] [L is the dianion of 2'-(2-benzoyl-1-methylethylidene)-1-naphthohydrazide, C21H16N2O2], the Mo atom displays distorted octahedral coordination geometry, being coordinated by two mutually cis oxo ligands, the methanol O atom and the tridentate ligand L bonded through the azomethine N atom, the enolic O atom and the oxazine O atom (equatorially disposed). The packing in the crystal structure involves a hydrogen bond from the methanol OH as donor to an oxo ligand as acceptor. PB - Munksgaard Int Publ Ltd, Copenhagen T2 - Acta Crystallographica. Section C: Crystal Structure Communications T1 - mer-[2'-(2-Benzoyl-1-methylethylidene)-1-napthtohydrazido(2-)](methanol)-cis-dioxo-molybdenum(VI) VL - 52 SP - 1375 EP - 1377 DO - 10.1107/S010827019600039X ER -
@article{ author = "Prelesnik, B and Ivanović, I. and Leovac, Vukadin M. and Anđelković, Katarina K.", year = "1996", abstract = "In the molecule of the title compound, [MoO2(L)(CH3-OH)] [L is the dianion of 2'-(2-benzoyl-1-methylethylidene)-1-naphthohydrazide, C21H16N2O2], the Mo atom displays distorted octahedral coordination geometry, being coordinated by two mutually cis oxo ligands, the methanol O atom and the tridentate ligand L bonded through the azomethine N atom, the enolic O atom and the oxazine O atom (equatorially disposed). The packing in the crystal structure involves a hydrogen bond from the methanol OH as donor to an oxo ligand as acceptor.", publisher = "Munksgaard Int Publ Ltd, Copenhagen", journal = "Acta Crystallographica. Section C: Crystal Structure Communications", title = "mer-[2'-(2-Benzoyl-1-methylethylidene)-1-napthtohydrazido(2-)](methanol)-cis-dioxo-molybdenum(VI)", volume = "52", pages = "1375-1377", doi = "10.1107/S010827019600039X" }
Prelesnik, B., Ivanović, I., Leovac, V. M.,& Anđelković, K. K.. (1996). mer-[2'-(2-Benzoyl-1-methylethylidene)-1-napthtohydrazido(2-)](methanol)-cis-dioxo-molybdenum(VI). in Acta Crystallographica. Section C: Crystal Structure Communications Munksgaard Int Publ Ltd, Copenhagen., 52, 1375-1377. https://doi.org/10.1107/S010827019600039X
Prelesnik B, Ivanović I, Leovac VM, Anđelković KK. mer-[2'-(2-Benzoyl-1-methylethylidene)-1-napthtohydrazido(2-)](methanol)-cis-dioxo-molybdenum(VI). in Acta Crystallographica. Section C: Crystal Structure Communications. 1996;52:1375-1377. doi:10.1107/S010827019600039X .
Prelesnik, B, Ivanović, I., Leovac, Vukadin M., Anđelković, Katarina K., "mer-[2'-(2-Benzoyl-1-methylethylidene)-1-napthtohydrazido(2-)](methanol)-cis-dioxo-molybdenum(VI)" in Acta Crystallographica. Section C: Crystal Structure Communications, 52 (1996):1375-1377, https://doi.org/10.1107/S010827019600039X . .