Transition metal complexes with thiosemicarbazide-based ligands .28. Synthesis and x-ray crystal structure of the first phosphorus-bonded thiosemicarbazide complex: [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(1-)]pyridinenickel(II)-nitrate
Апстракт
The synthesis and crystal structure analysis of the diamagnetic complex [Ni(L)Py]NO3 (L = the monoanion of the newly synthesized ligand 2-(diphenylphosphino)benzaldehyde thiosemicarbazone) are reported. The complex crystallizes in the space group P2(1)/n (No. 14) with a = 8.533(1), b = 29.123(3), c = 10.627(a) Angstrom, beta = 110.36(1)degrees, V = 2597.8(5) Angstrom(3). As revealed X-ray analysis, the 2-(diphenylphosphino)benzaldehyde thiosemicarbazone ligand deprotonated at N(3) acts as a monoanionic tridentate donor, coordinating through SNP. The core of the bulky {Ni[(C6H5)(2)P-(C6H4CH=N-N=CS-NH2).]}(+) cation is a slightly puckered quadrangle formed around Ni2+ by SNP accompanied by a pyridine nitrogen. The dihedral angle of the atomic triangles S/N(4)/N(41) and P(2)/N(4)/N(41) is 18.0(4)degrees. The NO3- anions are well separated from the cations which may account for the observed disorder of the oxygen atoms.
Кључне речи:
nickel(II) complex / 2-(diphenylphosphino)benzaldehydethiosemicarbazone / Schiff base / X-ray structureИзвор:
Journal of Coordination Chemistry, 1996, 39, 1, 11-19Издавач:
- Taylor & Francis Ltd, Abingdon
DOI: 10.1080/00958979608028171
ISSN: 0095-8972
WoS: A1996UZ47700002
Scopus: 2-s2.0-0006657839
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Leovac, Vukadin M. AU - Ribar, B AU - Argay, G AU - Kalman, A AU - Brčeski, Ilija PY - 1996 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2245 AB - The synthesis and crystal structure analysis of the diamagnetic complex [Ni(L)Py]NO3 (L = the monoanion of the newly synthesized ligand 2-(diphenylphosphino)benzaldehyde thiosemicarbazone) are reported. The complex crystallizes in the space group P2(1)/n (No. 14) with a = 8.533(1), b = 29.123(3), c = 10.627(a) Angstrom, beta = 110.36(1)degrees, V = 2597.8(5) Angstrom(3). As revealed X-ray analysis, the 2-(diphenylphosphino)benzaldehyde thiosemicarbazone ligand deprotonated at N(3) acts as a monoanionic tridentate donor, coordinating through SNP. The core of the bulky {Ni[(C6H5)(2)P-(C6H4CH=N-N=CS-NH2).]}(+) cation is a slightly puckered quadrangle formed around Ni2+ by SNP accompanied by a pyridine nitrogen. The dihedral angle of the atomic triangles S/N(4)/N(41) and P(2)/N(4)/N(41) is 18.0(4)degrees. The NO3- anions are well separated from the cations which may account for the observed disorder of the oxygen atoms. PB - Taylor & Francis Ltd, Abingdon T2 - Journal of Coordination Chemistry T1 - Transition metal complexes with thiosemicarbazide-based ligands .28. Synthesis and x-ray crystal structure of the first phosphorus-bonded thiosemicarbazide complex: [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(1-)]pyridinenickel(II)-nitrate VL - 39 IS - 1 SP - 11 EP - 19 DO - 10.1080/00958979608028171 ER -
@article{ author = "Leovac, Vukadin M. and Ribar, B and Argay, G and Kalman, A and Brčeski, Ilija", year = "1996", abstract = "The synthesis and crystal structure analysis of the diamagnetic complex [Ni(L)Py]NO3 (L = the monoanion of the newly synthesized ligand 2-(diphenylphosphino)benzaldehyde thiosemicarbazone) are reported. The complex crystallizes in the space group P2(1)/n (No. 14) with a = 8.533(1), b = 29.123(3), c = 10.627(a) Angstrom, beta = 110.36(1)degrees, V = 2597.8(5) Angstrom(3). As revealed X-ray analysis, the 2-(diphenylphosphino)benzaldehyde thiosemicarbazone ligand deprotonated at N(3) acts as a monoanionic tridentate donor, coordinating through SNP. The core of the bulky {Ni[(C6H5)(2)P-(C6H4CH=N-N=CS-NH2).]}(+) cation is a slightly puckered quadrangle formed around Ni2+ by SNP accompanied by a pyridine nitrogen. The dihedral angle of the atomic triangles S/N(4)/N(41) and P(2)/N(4)/N(41) is 18.0(4)degrees. The NO3- anions are well separated from the cations which may account for the observed disorder of the oxygen atoms.", publisher = "Taylor & Francis Ltd, Abingdon", journal = "Journal of Coordination Chemistry", title = "Transition metal complexes with thiosemicarbazide-based ligands .28. Synthesis and x-ray crystal structure of the first phosphorus-bonded thiosemicarbazide complex: [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(1-)]pyridinenickel(II)-nitrate", volume = "39", number = "1", pages = "11-19", doi = "10.1080/00958979608028171" }
Leovac, V. M., Ribar, B., Argay, G., Kalman, A.,& Brčeski, I.. (1996). Transition metal complexes with thiosemicarbazide-based ligands .28. Synthesis and x-ray crystal structure of the first phosphorus-bonded thiosemicarbazide complex: [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(1-)]pyridinenickel(II)-nitrate. in Journal of Coordination Chemistry Taylor & Francis Ltd, Abingdon., 39(1), 11-19. https://doi.org/10.1080/00958979608028171
Leovac VM, Ribar B, Argay G, Kalman A, Brčeski I. Transition metal complexes with thiosemicarbazide-based ligands .28. Synthesis and x-ray crystal structure of the first phosphorus-bonded thiosemicarbazide complex: [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(1-)]pyridinenickel(II)-nitrate. in Journal of Coordination Chemistry. 1996;39(1):11-19. doi:10.1080/00958979608028171 .
Leovac, Vukadin M., Ribar, B, Argay, G, Kalman, A, Brčeski, Ilija, "Transition metal complexes with thiosemicarbazide-based ligands .28. Synthesis and x-ray crystal structure of the first phosphorus-bonded thiosemicarbazide complex: [2-(diphenylphosphino)benzaldehyde thiosemicarbazonato(1-)]pyridinenickel(II)-nitrate" in Journal of Coordination Chemistry, 39, no. 1 (1996):11-19, https://doi.org/10.1080/00958979608028171 . .