Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent
Samo za registrovane korisnike
2017
Autori
Romanović, MimaČobeljić, Božidar
Pevec, Andrej
Turel, Iztok
Spasojević, Vojislav
Tsaturyan, Arshak A.
Shcherbakov, Igor N.
Anđelković, Katarina K.
Milenković, Marina
Radanović, Dušanka D.
Milenković, Milica R.
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
A dinuclear double end-on azido bridged KM complex [Ni2L2(mu-(1),(1)-N-3)(2)(N-3)(2)] (1) with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) has been synthesized and characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, magnetic measurements and DFT studies. In complex 1 intra-dimer ferromagnetic coupling between Ni2+ ions (J= +12.0(2) cm(-1)) and inter-dimer antiferromagnetic interaction (delta = -0.8(3) cm(-1)) were observed. DFT-BS calculations provided explanation of ferromagnetic exchange coupling in complex 1.
Ključne reči:
Ni(II) complex / Hydrazones / DFT / Magnetic properties / Crystal structureIzvor:
Polyhedron, 2017, 128, 30-37Izdavač:
- Pergamon-Elsevier Science Ltd, Oxford
Finansiranje / projekti:
- Interakcije prirodnih proizvoda, njihovih derivata i kompleksnih jedinjenja sa proteinima i nukleinskim kiselinama (RS-MESTD-Basic Research (BR or ON)-172055)
- COST Action
- Slovenian Research Agency [P-0175]
- SFedU [213.01-07-2014/03PChVG]
Napomena:
- Peer-reviewed manuscript: http://cherry.chem.bg.ac.rs/handle/123456789/3100
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/3101
DOI: 10.1016/j.poly.2017.02.039
ISSN: 0277-5387
WoS: 000401047100005
Scopus: 2-s2.0-85015629397
Kolekcije
Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Romanović, Mima AU - Čobeljić, Božidar AU - Pevec, Andrej AU - Turel, Iztok AU - Spasojević, Vojislav AU - Tsaturyan, Arshak A. AU - Shcherbakov, Igor N. AU - Anđelković, Katarina K. AU - Milenković, Marina AU - Radanović, Dušanka D. AU - Milenković, Milica R. PY - 2017 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2455 AB - A dinuclear double end-on azido bridged KM complex [Ni2L2(mu-(1),(1)-N-3)(2)(N-3)(2)] (1) with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) has been synthesized and characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, magnetic measurements and DFT studies. In complex 1 intra-dimer ferromagnetic coupling between Ni2+ ions (J= +12.0(2) cm(-1)) and inter-dimer antiferromagnetic interaction (delta = -0.8(3) cm(-1)) were observed. DFT-BS calculations provided explanation of ferromagnetic exchange coupling in complex 1. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Polyhedron T1 - Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent VL - 128 SP - 30 EP - 37 DO - 10.1016/j.poly.2017.02.039 ER -
@article{ author = "Romanović, Mima and Čobeljić, Božidar and Pevec, Andrej and Turel, Iztok and Spasojević, Vojislav and Tsaturyan, Arshak A. and Shcherbakov, Igor N. and Anđelković, Katarina K. and Milenković, Marina and Radanović, Dušanka D. and Milenković, Milica R.", year = "2017", abstract = "A dinuclear double end-on azido bridged KM complex [Ni2L2(mu-(1),(1)-N-3)(2)(N-3)(2)] (1) with the condensation product of 2-quinolinecarboxaldehyde and trimethylammonium acetohydrazide chloride (Girard's T reagent) (HLCl) has been synthesized and characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, magnetic measurements and DFT studies. In complex 1 intra-dimer ferromagnetic coupling between Ni2+ ions (J= +12.0(2) cm(-1)) and inter-dimer antiferromagnetic interaction (delta = -0.8(3) cm(-1)) were observed. DFT-BS calculations provided explanation of ferromagnetic exchange coupling in complex 1.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Polyhedron", title = "Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent", volume = "128", pages = "30-37", doi = "10.1016/j.poly.2017.02.039" }
Romanović, M., Čobeljić, B., Pevec, A., Turel, I., Spasojević, V., Tsaturyan, A. A., Shcherbakov, I. N., Anđelković, K. K., Milenković, M., Radanović, D. D.,& Milenković, M. R.. (2017). Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent. in Polyhedron Pergamon-Elsevier Science Ltd, Oxford., 128, 30-37. https://doi.org/10.1016/j.poly.2017.02.039
Romanović M, Čobeljić B, Pevec A, Turel I, Spasojević V, Tsaturyan AA, Shcherbakov IN, Anđelković KK, Milenković M, Radanović DD, Milenković MR. Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent. in Polyhedron. 2017;128:30-37. doi:10.1016/j.poly.2017.02.039 .
Romanović, Mima, Čobeljić, Božidar, Pevec, Andrej, Turel, Iztok, Spasojević, Vojislav, Tsaturyan, Arshak A., Shcherbakov, Igor N., Anđelković, Katarina K., Milenković, Marina, Radanović, Dušanka D., Milenković, Milica R., "Synthesis, crystal structure, magnetic properties and DFT study of dinuclear Ni(II) complex with the condensation product of 2-quinolinecarboxaldehyde and Girard's T reagent" in Polyhedron, 128 (2017):30-37, https://doi.org/10.1016/j.poly.2017.02.039 . .