Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst
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2018
Authors
Ajdačić, VladimirNikolić, Andrea
Simić, Stefan
Manojlović, Dragan D.
Stojanović, Zoran
Nikodinović-Runić, Jasmina
Opsenica, Igor
Article (Published version)
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Show full item recordAbstract
A facile decarbonylation reaction of a variety of aromatic and heteroaromatic aldehydes using maghemite-supported palladium catalyst has been developed. The magnetic properties of catalyst facilitated an easy and efficient recovery of the catalyst from the reaction mixture using an external magnet. It was found that the catalyst could be reused up to four consecutive catalytic runs without a significant change in activity. In addition, the catalyst was also very effective in the dehalogenation of aryl halides. This is the first report on efficient utilization of directly immobilized Pd on maghemite in decarbonylation and dehalogenation reactions.
Keywords:
decarbonylation / dehalogenation / palladium catalyst / maghemite / magnetically recoverable catalystSource:
Synthesis, Stuttgart, 2018, 50, 1, 119-126Publisher:
- Georg Thieme Verlag Kg, Stuttgart
Funding / projects:
- The synthesis of aminoquinoline-based antimalarials and botulinum neurotoxin A inhibitors (RS-MESTD-Basic Research (BR or ON)-172008)
- Molecular designing of nanoparticles with controlled morphological and physicochemical characteristics and functional materials based on them (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45004)
Note:
- Supplementary material: http://cherry.chem.bg.ac.rs/handle/123456789/2995
DOI: 10.1055/s-0036-1590892
ISSN: 0039-7881
WoS: 000418280600010
Scopus: 2-s2.0-85038632737
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Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Ajdačić, Vladimir AU - Nikolić, Andrea AU - Simić, Stefan AU - Manojlović, Dragan D. AU - Stojanović, Zoran AU - Nikodinović-Runić, Jasmina AU - Opsenica, Igor PY - 2018 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2569 AB - A facile decarbonylation reaction of a variety of aromatic and heteroaromatic aldehydes using maghemite-supported palladium catalyst has been developed. The magnetic properties of catalyst facilitated an easy and efficient recovery of the catalyst from the reaction mixture using an external magnet. It was found that the catalyst could be reused up to four consecutive catalytic runs without a significant change in activity. In addition, the catalyst was also very effective in the dehalogenation of aryl halides. This is the first report on efficient utilization of directly immobilized Pd on maghemite in decarbonylation and dehalogenation reactions. PB - Georg Thieme Verlag Kg, Stuttgart T2 - Synthesis, Stuttgart T1 - Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst VL - 50 IS - 1 SP - 119 EP - 126 DO - 10.1055/s-0036-1590892 ER -
@article{ author = "Ajdačić, Vladimir and Nikolić, Andrea and Simić, Stefan and Manojlović, Dragan D. and Stojanović, Zoran and Nikodinović-Runić, Jasmina and Opsenica, Igor", year = "2018", abstract = "A facile decarbonylation reaction of a variety of aromatic and heteroaromatic aldehydes using maghemite-supported palladium catalyst has been developed. The magnetic properties of catalyst facilitated an easy and efficient recovery of the catalyst from the reaction mixture using an external magnet. It was found that the catalyst could be reused up to four consecutive catalytic runs without a significant change in activity. In addition, the catalyst was also very effective in the dehalogenation of aryl halides. This is the first report on efficient utilization of directly immobilized Pd on maghemite in decarbonylation and dehalogenation reactions.", publisher = "Georg Thieme Verlag Kg, Stuttgart", journal = "Synthesis, Stuttgart", title = "Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst", volume = "50", number = "1", pages = "119-126", doi = "10.1055/s-0036-1590892" }
Ajdačić, V., Nikolić, A., Simić, S., Manojlović, D. D., Stojanović, Z., Nikodinović-Runić, J.,& Opsenica, I.. (2018). Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst. in Synthesis, Stuttgart Georg Thieme Verlag Kg, Stuttgart., 50(1), 119-126. https://doi.org/10.1055/s-0036-1590892
Ajdačić V, Nikolić A, Simić S, Manojlović DD, Stojanović Z, Nikodinović-Runić J, Opsenica I. Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst. in Synthesis, Stuttgart. 2018;50(1):119-126. doi:10.1055/s-0036-1590892 .
Ajdačić, Vladimir, Nikolić, Andrea, Simić, Stefan, Manojlović, Dragan D., Stojanović, Zoran, Nikodinović-Runić, Jasmina, Opsenica, Igor, "Decarbonylation of Aromatic Aldehydes and Dehalogenation of Aryl Halides Using Maghemite-Supported Palladium Catalyst" in Synthesis, Stuttgart, 50, no. 1 (2018):119-126, https://doi.org/10.1055/s-0036-1590892 . .