Infrared spectra of three M(I)M(III)S(2) type synthetic minerals (M(I)=Ag or Tl, M(III)=Sb or As)
Апстракт
The infrared spectra of three compounds of the M(I)M(III)S(2) type (smithite, AgAsS2; weissbergite, TlSbS2; and miargyrite, AgSbS2) were studied at room temperature (RT) and at the boiling temperature of liquid nitrogen (LNT). The infrared spectrum of smithite was compared with that of the formally analogous mineral lorandite, TlAsS2. Although the mentioned synthetic minerals have crystal structures which differ from each other, the infrared spectra of smithite and lorandite, on the one hand, and of weissbergite and miargyrite on the other, are similar. The analysis of the spectra indicate that the Tl-S interaction has a more pronounced ionic character than the Ag-S one.
Кључне речи:
infrared spectra / synthetic minerals / smithite / lorandite / weissbergite / miargyriteИзвор:
Spectroscopy Letters, 1997, 30, 1, 79-87Издавач:
- Marcel Dekker Inc, New York
DOI: 10.1080/00387019708002591
ISSN: 0038-7010
WoS: A1997WG89300007
Scopus: 2-s2.0-0038073948
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Soptrajanov, B AU - Trajkovska, M AU - Stafilov, T AU - Jovanovski, G AU - Gržetić, Ivan PY - 1997 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2585 AB - The infrared spectra of three compounds of the M(I)M(III)S(2) type (smithite, AgAsS2; weissbergite, TlSbS2; and miargyrite, AgSbS2) were studied at room temperature (RT) and at the boiling temperature of liquid nitrogen (LNT). The infrared spectrum of smithite was compared with that of the formally analogous mineral lorandite, TlAsS2. Although the mentioned synthetic minerals have crystal structures which differ from each other, the infrared spectra of smithite and lorandite, on the one hand, and of weissbergite and miargyrite on the other, are similar. The analysis of the spectra indicate that the Tl-S interaction has a more pronounced ionic character than the Ag-S one. PB - Marcel Dekker Inc, New York T2 - Spectroscopy Letters T1 - Infrared spectra of three M(I)M(III)S(2) type synthetic minerals (M(I)=Ag or Tl, M(III)=Sb or As) VL - 30 IS - 1 SP - 79 EP - 87 DO - 10.1080/00387019708002591 ER -
@article{ author = "Soptrajanov, B and Trajkovska, M and Stafilov, T and Jovanovski, G and Gržetić, Ivan", year = "1997", abstract = "The infrared spectra of three compounds of the M(I)M(III)S(2) type (smithite, AgAsS2; weissbergite, TlSbS2; and miargyrite, AgSbS2) were studied at room temperature (RT) and at the boiling temperature of liquid nitrogen (LNT). The infrared spectrum of smithite was compared with that of the formally analogous mineral lorandite, TlAsS2. Although the mentioned synthetic minerals have crystal structures which differ from each other, the infrared spectra of smithite and lorandite, on the one hand, and of weissbergite and miargyrite on the other, are similar. The analysis of the spectra indicate that the Tl-S interaction has a more pronounced ionic character than the Ag-S one.", publisher = "Marcel Dekker Inc, New York", journal = "Spectroscopy Letters", title = "Infrared spectra of three M(I)M(III)S(2) type synthetic minerals (M(I)=Ag or Tl, M(III)=Sb or As)", volume = "30", number = "1", pages = "79-87", doi = "10.1080/00387019708002591" }
Soptrajanov, B., Trajkovska, M., Stafilov, T., Jovanovski, G.,& Gržetić, I.. (1997). Infrared spectra of three M(I)M(III)S(2) type synthetic minerals (M(I)=Ag or Tl, M(III)=Sb or As). in Spectroscopy Letters Marcel Dekker Inc, New York., 30(1), 79-87. https://doi.org/10.1080/00387019708002591
Soptrajanov B, Trajkovska M, Stafilov T, Jovanovski G, Gržetić I. Infrared spectra of three M(I)M(III)S(2) type synthetic minerals (M(I)=Ag or Tl, M(III)=Sb or As). in Spectroscopy Letters. 1997;30(1):79-87. doi:10.1080/00387019708002591 .
Soptrajanov, B, Trajkovska, M, Stafilov, T, Jovanovski, G, Gržetić, Ivan, "Infrared spectra of three M(I)M(III)S(2) type synthetic minerals (M(I)=Ag or Tl, M(III)=Sb or As)" in Spectroscopy Letters, 30, no. 1 (1997):79-87, https://doi.org/10.1080/00387019708002591 . .