The anisotropic pi-effect of the nitro group in ammine-nitro cobalt(III) complexes
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1997
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Prikaz svih podataka o dokumentuApstrakt
The analysis of crystal structures of the series of ammine-nitro cobalt(III) complexes has shown that Co-NO2 bond lengths can be successfully rationalized on the basis of the anisotropic pi-effect of nitro groups. This effect governs both the orientation of the nitro group and the Co-NO2 length, and explains the irregularities in the increase of the latter with the increasing number of NO2 groups present in the coordination sphere. (C) 1997 Elsevier Science Ltd.
Ključne reči:
anisotropic pi-effect / ammine-nitro complexes / cobalt(III) complexes / metal-ligand bond / pi-bonding / stereochemistryIzvor:
Polyhedron, 1997, 16, 20, 3565-3569Izdavač:
- Pergamon-Elsevier Science Ltd, Oxford
DOI: 10.1016/S0277-5387(97)00112-5
ISSN: 0277-5387
WoS: A1997XQ92400014
Scopus: 2-s2.0-0039054225
Kolekcije
Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Zarić, Snežana D. AU - Niketic, SR PY - 1997 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2594 AB - The analysis of crystal structures of the series of ammine-nitro cobalt(III) complexes has shown that Co-NO2 bond lengths can be successfully rationalized on the basis of the anisotropic pi-effect of nitro groups. This effect governs both the orientation of the nitro group and the Co-NO2 length, and explains the irregularities in the increase of the latter with the increasing number of NO2 groups present in the coordination sphere. (C) 1997 Elsevier Science Ltd. PB - Pergamon-Elsevier Science Ltd, Oxford T2 - Polyhedron T1 - The anisotropic pi-effect of the nitro group in ammine-nitro cobalt(III) complexes VL - 16 IS - 20 SP - 3565 EP - 3569 DO - 10.1016/S0277-5387(97)00112-5 ER -
@article{ author = "Zarić, Snežana D. and Niketic, SR", year = "1997", abstract = "The analysis of crystal structures of the series of ammine-nitro cobalt(III) complexes has shown that Co-NO2 bond lengths can be successfully rationalized on the basis of the anisotropic pi-effect of nitro groups. This effect governs both the orientation of the nitro group and the Co-NO2 length, and explains the irregularities in the increase of the latter with the increasing number of NO2 groups present in the coordination sphere. (C) 1997 Elsevier Science Ltd.", publisher = "Pergamon-Elsevier Science Ltd, Oxford", journal = "Polyhedron", title = "The anisotropic pi-effect of the nitro group in ammine-nitro cobalt(III) complexes", volume = "16", number = "20", pages = "3565-3569", doi = "10.1016/S0277-5387(97)00112-5" }
Zarić, S. D.,& Niketic, S.. (1997). The anisotropic pi-effect of the nitro group in ammine-nitro cobalt(III) complexes. in Polyhedron Pergamon-Elsevier Science Ltd, Oxford., 16(20), 3565-3569. https://doi.org/10.1016/S0277-5387(97)00112-5
Zarić SD, Niketic S. The anisotropic pi-effect of the nitro group in ammine-nitro cobalt(III) complexes. in Polyhedron. 1997;16(20):3565-3569. doi:10.1016/S0277-5387(97)00112-5 .
Zarić, Snežana D., Niketic, SR, "The anisotropic pi-effect of the nitro group in ammine-nitro cobalt(III) complexes" in Polyhedron, 16, no. 20 (1997):3565-3569, https://doi.org/10.1016/S0277-5387(97)00112-5 . .