dc.creator | Triana, Carlos A. | |
dc.creator | Moré, René | |
dc.creator | Bloomfield, Aaron J. | |
dc.creator | Petrović, Predrag | |
dc.creator | Goberna Ferron, Sara | |
dc.creator | Stanley, George | |
dc.creator | Zarić, Snežana D. | |
dc.creator | Fox, Thomas | |
dc.creator | Brothers, Edward N. | |
dc.creator | Sheehan, Stafford W. | |
dc.creator | Anastas, Paul T. | |
dc.creator | Patzke, Greta R. | |
dc.date.accessioned | 2020-05-13T09:50:16Z | |
dc.date.available | 2020-05-13T09:50:16Z | |
dc.date.issued | 2019 | |
dc.identifier.issn | 1354-1369 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/3935 | |
dc.description.abstract | Disordered materials with resilient and soft-templated functional units bear thepotential to fill the pipeline of robust catalysts for renewable energy storage.However, for novel materials lacking long-range order, the ability to discernlocal structure with atomic resolution still pushes the boundaries of currentanalytical and modeling approaches. We introduce a two-pillar strategy tomonitor the formation and unravel the structure of the first disordered one-dimensional cobalt coordination polymer catalyst, Co-dppeO2.Thistargetmaterial excels through proven high performance in commercial alkalineelectrolyzers and organic transformations. We demonstrate that the key archi-tecture behind this activity is the unconventional embedding of hydrated{H2O-Co2(OH)2-OH2} edge-site motifs, nested into a flexible organic matrix ofhighly oxidized and bridging hydrophobic dppeO2ligands. Our combinationofin situspectroscopy and computational modeling of X-ray scattering andabsorption spectra, backed with complementary experimental techniques,holds the key to understanding the atomic-range structure of importantdisordered materials. | sr |
dc.language.iso | en | sr |
dc.publisher | Cell Press | sr |
dc.relation | University of Zurich, Switzerland, and the Univer-sity Research Priority Program (URPP) forSolar Light to Chemical Energy Conver-sion (LightChEC). | sr |
dc.relation | wiss NationalScience Foundation, Switzerland (Sinergia grant no. CRSII2_160801/1). | sr |
dc.relation | QAFCO | sr |
dc.relation | Qatar National Research Foundation, Qatar,under NPRP10-0125-1702. | sr |
dc.rights | restrictedAccess | sr |
dc.source | Matter | sr |
dc.title | Soft Templating and Disorder in an Applied 1D Cobalt Coordination Polymer Electrocatalyst | sr |
dc.type | article | sr |
dc.rights.license | ARR | sr |
dcterms.abstract | Бротхерс, Едwард Н.; Схеехан, Стаффорд W.; Aнастас, Паул Т.; Патзке, Грета Р.; Фоx, Тхомас; Зарић, Снежана Д.; Блоомфиелд, Aарон Ј.; Станлеy, Георге; Триана, Царлос A.; Морé, Ренé; Петровић, Предраг В.; Гоберна Феррон, Сара; | |
dc.citation.volume | 1 | |
dc.citation.issue | 5 | |
dc.citation.spage | 1354 | |
dc.citation.epage | 1369 | |
dc.identifier.wos | 000519846700027 | |
dc.identifier.doi | 10.1016/j.matt.2019.06.021 | |
dc.type.version | publishedVersion | sr |
dc.identifier.scopus | 2-s2.0-85078439511 | |