Evaluation of Element Mobility in River Sediment Using Different Single Extraction Procedures and Assessment of Probabilistic Ecological Risk
Authors
Sakan, Sanja M.Frančišković-Bilinski, Stanislav
Đorđević, Dragana S.
Popović, Aleksandar R.
Sakan, Nenad
Škrivanj, Sandra B.
Bilinski, Halka
Article (Published version)
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In this manuscript, samples of Kupa River sediments were examined using three different extraction agents. The aim of this study was to evaluate the applicability of single extraction procedures to investigate the bioavailability and mobility of major and trace elements (Al, As, Ba, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Ni, P, Pb, S, Si, Sr, Ti, V, and Zn) from river sediment. Two forms of studied elements were evaluated: mobile, the most toxic element form (extraction with 1 M CH3COONH4 and 0.01 M CaCl2) and potentially mobilized form (2 M HNO3 extraction). The estimation of the ecological risk, with the application of the probability distribution of RI (potential ecological risk index) values, is yielded with the help of the Monte Carlo simulation (MCS). Ammonium acetate is proved to be a better extraction agent than calcium chloride. A positive correlation between the content of all extracted elements with nitric acid and the total element content indicates that 2 M HNO3 efficientl...y extracts all studied elements. Results showed anthropogenic sources of cadmium and copper and high barium mobility. The MCS suggests that risk of Cr, Cu, Ni, Pb, and Zn was low; As and Cd posed a lower and median ecological risk in the studied areas.
Keywords:
ecological risk / element mobility / Kupa River (Croatia) / Monte Carlo simulation / probabilistic ecological riskSource:
Water, 2021, 13, 10, 1411-Funding / projects:
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-MESTD-inst-2020-200026)
Note:
- Supplementary material: https://cherry.chem.bg.ac.rs/handle/123456789/4547
Related info:
- Referenced by
https://cherry.chem.bg.ac.rs/handle/123456789/4547
DOI: 10.3390/w13101411
ISSN: 2073-4441
WoS: 000655210700001
Scopus: 2-s2.0-85107209542
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Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Sakan, Sanja M. AU - Frančišković-Bilinski, Stanislav AU - Đorđević, Dragana S. AU - Popović, Aleksandar R. AU - Sakan, Nenad AU - Škrivanj, Sandra B. AU - Bilinski, Halka PY - 2021 UR - https://www.mdpi.com/2073-4441/13/10/1411 UR - https://cherry.chem.bg.ac.rs/handle/123456789/4546 AB - In this manuscript, samples of Kupa River sediments were examined using three different extraction agents. The aim of this study was to evaluate the applicability of single extraction procedures to investigate the bioavailability and mobility of major and trace elements (Al, As, Ba, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Ni, P, Pb, S, Si, Sr, Ti, V, and Zn) from river sediment. Two forms of studied elements were evaluated: mobile, the most toxic element form (extraction with 1 M CH3COONH4 and 0.01 M CaCl2) and potentially mobilized form (2 M HNO3 extraction). The estimation of the ecological risk, with the application of the probability distribution of RI (potential ecological risk index) values, is yielded with the help of the Monte Carlo simulation (MCS). Ammonium acetate is proved to be a better extraction agent than calcium chloride. A positive correlation between the content of all extracted elements with nitric acid and the total element content indicates that 2 M HNO3 efficiently extracts all studied elements. Results showed anthropogenic sources of cadmium and copper and high barium mobility. The MCS suggests that risk of Cr, Cu, Ni, Pb, and Zn was low; As and Cd posed a lower and median ecological risk in the studied areas. T2 - Water T1 - Evaluation of Element Mobility in River Sediment Using Different Single Extraction Procedures and Assessment of Probabilistic Ecological Risk VL - 13 IS - 10 SP - 1411 DO - 10.3390/w13101411 ER -
@article{ author = "Sakan, Sanja M. and Frančišković-Bilinski, Stanislav and Đorđević, Dragana S. and Popović, Aleksandar R. and Sakan, Nenad and Škrivanj, Sandra B. and Bilinski, Halka", year = "2021", abstract = "In this manuscript, samples of Kupa River sediments were examined using three different extraction agents. The aim of this study was to evaluate the applicability of single extraction procedures to investigate the bioavailability and mobility of major and trace elements (Al, As, Ba, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Ni, P, Pb, S, Si, Sr, Ti, V, and Zn) from river sediment. Two forms of studied elements were evaluated: mobile, the most toxic element form (extraction with 1 M CH3COONH4 and 0.01 M CaCl2) and potentially mobilized form (2 M HNO3 extraction). The estimation of the ecological risk, with the application of the probability distribution of RI (potential ecological risk index) values, is yielded with the help of the Monte Carlo simulation (MCS). Ammonium acetate is proved to be a better extraction agent than calcium chloride. A positive correlation between the content of all extracted elements with nitric acid and the total element content indicates that 2 M HNO3 efficiently extracts all studied elements. Results showed anthropogenic sources of cadmium and copper and high barium mobility. The MCS suggests that risk of Cr, Cu, Ni, Pb, and Zn was low; As and Cd posed a lower and median ecological risk in the studied areas.", journal = "Water", title = "Evaluation of Element Mobility in River Sediment Using Different Single Extraction Procedures and Assessment of Probabilistic Ecological Risk", volume = "13", number = "10", pages = "1411", doi = "10.3390/w13101411" }
Sakan, S. M., Frančišković-Bilinski, S., Đorđević, D. S., Popović, A. R., Sakan, N., Škrivanj, S. B.,& Bilinski, H.. (2021). Evaluation of Element Mobility in River Sediment Using Different Single Extraction Procedures and Assessment of Probabilistic Ecological Risk. in Water, 13(10), 1411. https://doi.org/10.3390/w13101411
Sakan SM, Frančišković-Bilinski S, Đorđević DS, Popović AR, Sakan N, Škrivanj SB, Bilinski H. Evaluation of Element Mobility in River Sediment Using Different Single Extraction Procedures and Assessment of Probabilistic Ecological Risk. in Water. 2021;13(10):1411. doi:10.3390/w13101411 .
Sakan, Sanja M., Frančišković-Bilinski, Stanislav, Đorđević, Dragana S., Popović, Aleksandar R., Sakan, Nenad, Škrivanj, Sandra B., Bilinski, Halka, "Evaluation of Element Mobility in River Sediment Using Different Single Extraction Procedures and Assessment of Probabilistic Ecological Risk" in Water, 13, no. 10 (2021):1411, https://doi.org/10.3390/w13101411 . .