Synthesis and characterization of tris[butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamato]-cobalt(III) seskvitoluene
Sinteza i karakterizacija tris [butil-(1-metil-3-fenil-propil)-ditiokarbamato]-kobalt(III) seskvitoluena
Apstrakt
A new bidentate ligand butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamate (bmPhipdtc) was prepared, as the sodium salt. In the reaction of hexaaminecobalt(III) chloride with NabmPhipdtc, the corresponding tris[butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamato]cobalt(III), [Co(bmPhipdtc)(3)] complex was prepared. The complex was characterized by elemental analysis, infrared, electronic absorption, H-1 and C-13-NMR spectroscopy.
Sintetisan je novi bidentatni ligand butil-(1-metil-3-fenil-propil)-ditiokarbamat (bmΦpdtc), kao natrijumova so. Reakcijom heksaamminkobalt(III)-hlorida i navedenog liganda dobijen je odgovarajući kompleks tris[butil-(1-metil-3-fenil-propil) ditiokarbamato]kobalt(III), [Co(bmΦpdtc)3]. Kompleks je okarakterisan elementalnom analizom, infracrvenim, elektronsko-apsorpcionim, 1H i 13C-NMR spektrima.
Ključne reči:
cobal(III) complex / dithiocarbamate / dithiocarbamate / bidentate ligand / bidentate ligandIzvor:
Journal of the Serbian Chemical Society, 2002, 67, 2, 123-126Izdavač:
- Serbian Chemical Soc, Belgrade
DOI: 10.2298/JSC0202123K
ISSN: 0352-5139
WoS: 000173995100008
Scopus: 2-s2.0-0036003612
Kolekcije
Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Kaludjerovic, GN AU - Djinovic, VM AU - Trifunović, Srećko R. AU - Hodzic, IM AU - Sabo, Tibor PY - 2002 UR - https://cherry.chem.bg.ac.rs/handle/123456789/483 AB - A new bidentate ligand butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamate (bmPhipdtc) was prepared, as the sodium salt. In the reaction of hexaaminecobalt(III) chloride with NabmPhipdtc, the corresponding tris[butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamato]cobalt(III), [Co(bmPhipdtc)(3)] complex was prepared. The complex was characterized by elemental analysis, infrared, electronic absorption, H-1 and C-13-NMR spectroscopy. AB - Sintetisan je novi bidentatni ligand butil-(1-metil-3-fenil-propil)-ditiokarbamat (bmΦpdtc), kao natrijumova so. Reakcijom heksaamminkobalt(III)-hlorida i navedenog liganda dobijen je odgovarajući kompleks tris[butil-(1-metil-3-fenil-propil) ditiokarbamato]kobalt(III), [Co(bmΦpdtc)3]. Kompleks je okarakterisan elementalnom analizom, infracrvenim, elektronsko-apsorpcionim, 1H i 13C-NMR spektrima. PB - Serbian Chemical Soc, Belgrade T2 - Journal of the Serbian Chemical Society T1 - Synthesis and characterization of tris[butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamato]-cobalt(III) seskvitoluene T1 - Sinteza i karakterizacija tris [butil-(1-metil-3-fenil-propil)-ditiokarbamato]-kobalt(III) seskvitoluena VL - 67 IS - 2 SP - 123 EP - 126 DO - 10.2298/JSC0202123K ER -
@article{ author = "Kaludjerovic, GN and Djinovic, VM and Trifunović, Srećko R. and Hodzic, IM and Sabo, Tibor", year = "2002", abstract = "A new bidentate ligand butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamate (bmPhipdtc) was prepared, as the sodium salt. In the reaction of hexaaminecobalt(III) chloride with NabmPhipdtc, the corresponding tris[butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamato]cobalt(III), [Co(bmPhipdtc)(3)] complex was prepared. The complex was characterized by elemental analysis, infrared, electronic absorption, H-1 and C-13-NMR spectroscopy., Sintetisan je novi bidentatni ligand butil-(1-metil-3-fenil-propil)-ditiokarbamat (bmΦpdtc), kao natrijumova so. Reakcijom heksaamminkobalt(III)-hlorida i navedenog liganda dobijen je odgovarajući kompleks tris[butil-(1-metil-3-fenil-propil) ditiokarbamato]kobalt(III), [Co(bmΦpdtc)3]. Kompleks je okarakterisan elementalnom analizom, infracrvenim, elektronsko-apsorpcionim, 1H i 13C-NMR spektrima.", publisher = "Serbian Chemical Soc, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "Synthesis and characterization of tris[butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamato]-cobalt(III) seskvitoluene, Sinteza i karakterizacija tris [butil-(1-metil-3-fenil-propil)-ditiokarbamato]-kobalt(III) seskvitoluena", volume = "67", number = "2", pages = "123-126", doi = "10.2298/JSC0202123K" }
Kaludjerovic, G., Djinovic, V., Trifunović, S. R., Hodzic, I.,& Sabo, T.. (2002). Synthesis and characterization of tris[butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamato]-cobalt(III) seskvitoluene. in Journal of the Serbian Chemical Society Serbian Chemical Soc, Belgrade., 67(2), 123-126. https://doi.org/10.2298/JSC0202123K
Kaludjerovic G, Djinovic V, Trifunović SR, Hodzic I, Sabo T. Synthesis and characterization of tris[butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamato]-cobalt(III) seskvitoluene. in Journal of the Serbian Chemical Society. 2002;67(2):123-126. doi:10.2298/JSC0202123K .
Kaludjerovic, GN, Djinovic, VM, Trifunović, Srećko R., Hodzic, IM, Sabo, Tibor, "Synthesis and characterization of tris[butyl-(1-methyl-3-phenyl-propyl)-dithiocarbamato]-cobalt(III) seskvitoluene" in Journal of the Serbian Chemical Society, 67, no. 2 (2002):123-126, https://doi.org/10.2298/JSC0202123K . .