Evidence based on crystal structures and calculations of a C-H-...pi interaction between an organic moiety and a chelate ring in transition metal complexes
Само за регистроване кориснике
2002
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Structural and computational evidence is given for a special type of C-H(...)pi interaction where the C-H group interacts with the pi-system of a six-membered chelate ring. An investigation of crystal structures shows that these interactions take place in quite a number of metal complexes, including organometallic compounds; in the CSD we found over 1200 structures with these interactions, These interactions exist in complexes of different metals and various chelate rings, DFT calculations on three model systems show that the energy of these interactions is about 1 kcal/mol. ((C) Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002).
Кључне речи:
C-H center dot center dot center dot pi interactions / chelates / noncovalent interactions / density functional calculations / weak hydrogen bondsИзвор:
European Journal of Inorganic Chemistry, 2002, 7, 1599-1602Издавач:
- Wiley-V C H Verlag Gmbh, Weinheim
Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Bogdanović, Goran A. AU - Bire, ASD AU - Zarić, Snežana D. PY - 2002 UR - https://cherry.chem.bg.ac.rs/handle/123456789/497 AB - Structural and computational evidence is given for a special type of C-H(...)pi interaction where the C-H group interacts with the pi-system of a six-membered chelate ring. An investigation of crystal structures shows that these interactions take place in quite a number of metal complexes, including organometallic compounds; in the CSD we found over 1200 structures with these interactions, These interactions exist in complexes of different metals and various chelate rings, DFT calculations on three model systems show that the energy of these interactions is about 1 kcal/mol. ((C) Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002). PB - Wiley-V C H Verlag Gmbh, Weinheim T2 - European Journal of Inorganic Chemistry T1 - Evidence based on crystal structures and calculations of a C-H-...pi interaction between an organic moiety and a chelate ring in transition metal complexes IS - 7 SP - 1599 EP - 1602 UR - https://hdl.handle.net/21.15107/rcub_cherry_497 ER -
@article{ author = "Bogdanović, Goran A. and Bire, ASD and Zarić, Snežana D.", year = "2002", abstract = "Structural and computational evidence is given for a special type of C-H(...)pi interaction where the C-H group interacts with the pi-system of a six-membered chelate ring. An investigation of crystal structures shows that these interactions take place in quite a number of metal complexes, including organometallic compounds; in the CSD we found over 1200 structures with these interactions, These interactions exist in complexes of different metals and various chelate rings, DFT calculations on three model systems show that the energy of these interactions is about 1 kcal/mol. ((C) Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002).", publisher = "Wiley-V C H Verlag Gmbh, Weinheim", journal = "European Journal of Inorganic Chemistry", title = "Evidence based on crystal structures and calculations of a C-H-...pi interaction between an organic moiety and a chelate ring in transition metal complexes", number = "7", pages = "1599-1602", url = "https://hdl.handle.net/21.15107/rcub_cherry_497" }
Bogdanović, G. A., Bire, A.,& Zarić, S. D.. (2002). Evidence based on crystal structures and calculations of a C-H-...pi interaction between an organic moiety and a chelate ring in transition metal complexes. in European Journal of Inorganic Chemistry Wiley-V C H Verlag Gmbh, Weinheim.(7), 1599-1602. https://hdl.handle.net/21.15107/rcub_cherry_497
Bogdanović GA, Bire A, Zarić SD. Evidence based on crystal structures and calculations of a C-H-...pi interaction between an organic moiety and a chelate ring in transition metal complexes. in European Journal of Inorganic Chemistry. 2002;(7):1599-1602. https://hdl.handle.net/21.15107/rcub_cherry_497 .
Bogdanović, Goran A., Bire, ASD, Zarić, Snežana D., "Evidence based on crystal structures and calculations of a C-H-...pi interaction between an organic moiety and a chelate ring in transition metal complexes" in European Journal of Inorganic Chemistry, no. 7 (2002):1599-1602, https://hdl.handle.net/21.15107/rcub_cherry_497 .