Synthesis, physicochemical properties and crystal structure of isothiocianato [2-(diphenylphosphino)benzaldehyde selenosemicarbazonato(1(-))] nickel(II)
Samo za registrovane korisnike
2004
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The syntheses of a new ligand 2-(diphenylphosphino)benzaldehyde selenosemicarbazone (HL) and the corresponding complex with Ni(II) of the formula [Ni(L)(NCS)] are reported. The complex was characterized by single crystal X-ray analysis. The compound complex is diamagnetic and has a markedly deformed square-planar structure with PNSe set of donor atoms of the ligand, the Schiff base monoanion, and the N atom of the coordinated NCS group. The phosphorus atom deviates even by 0.494(3) Angstrom from the mean plane defined by the other coordination atoms (NSeN) and the metal atom. (C) 2003 Published by Elsevier B.V.
Ključne reči:
nickel(II) complex / 2-(diphenylphosphino)benzaldehyde selenosemicarbazone / crystal structure / IR spectra / deformed coordination geometryIzvor:
Inorganic Chemistry Communications, 2004, 7, 2, 253-256Izdavač:
- Elsevier Science Bv, Amsterdam
DOI: 10.1016/j.inoche.2003.11.013
ISSN: 1387-7003
WoS: 000188859000029
Scopus: 2-s2.0-0842277653
Kolekcije
Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Brčeski, Ilija AU - Leovac, Vukadin M. AU - Bogdanović, Goran A. AU - Sovilj, Sofija P. AU - Revenco, M PY - 2004 UR - https://cherry.chem.bg.ac.rs/handle/123456789/569 AB - The syntheses of a new ligand 2-(diphenylphosphino)benzaldehyde selenosemicarbazone (HL) and the corresponding complex with Ni(II) of the formula [Ni(L)(NCS)] are reported. The complex was characterized by single crystal X-ray analysis. The compound complex is diamagnetic and has a markedly deformed square-planar structure with PNSe set of donor atoms of the ligand, the Schiff base monoanion, and the N atom of the coordinated NCS group. The phosphorus atom deviates even by 0.494(3) Angstrom from the mean plane defined by the other coordination atoms (NSeN) and the metal atom. (C) 2003 Published by Elsevier B.V. PB - Elsevier Science Bv, Amsterdam T2 - Inorganic Chemistry Communications T1 - Synthesis, physicochemical properties and crystal structure of isothiocianato [2-(diphenylphosphino)benzaldehyde selenosemicarbazonato(1(-))] nickel(II) VL - 7 IS - 2 SP - 253 EP - 256 DO - 10.1016/j.inoche.2003.11.013 ER -
@article{ author = "Brčeski, Ilija and Leovac, Vukadin M. and Bogdanović, Goran A. and Sovilj, Sofija P. and Revenco, M", year = "2004", abstract = "The syntheses of a new ligand 2-(diphenylphosphino)benzaldehyde selenosemicarbazone (HL) and the corresponding complex with Ni(II) of the formula [Ni(L)(NCS)] are reported. The complex was characterized by single crystal X-ray analysis. The compound complex is diamagnetic and has a markedly deformed square-planar structure with PNSe set of donor atoms of the ligand, the Schiff base monoanion, and the N atom of the coordinated NCS group. The phosphorus atom deviates even by 0.494(3) Angstrom from the mean plane defined by the other coordination atoms (NSeN) and the metal atom. (C) 2003 Published by Elsevier B.V.", publisher = "Elsevier Science Bv, Amsterdam", journal = "Inorganic Chemistry Communications", title = "Synthesis, physicochemical properties and crystal structure of isothiocianato [2-(diphenylphosphino)benzaldehyde selenosemicarbazonato(1(-))] nickel(II)", volume = "7", number = "2", pages = "253-256", doi = "10.1016/j.inoche.2003.11.013" }
Brčeski, I., Leovac, V. M., Bogdanović, G. A., Sovilj, S. P.,& Revenco, M.. (2004). Synthesis, physicochemical properties and crystal structure of isothiocianato [2-(diphenylphosphino)benzaldehyde selenosemicarbazonato(1(-))] nickel(II). in Inorganic Chemistry Communications Elsevier Science Bv, Amsterdam., 7(2), 253-256. https://doi.org/10.1016/j.inoche.2003.11.013
Brčeski I, Leovac VM, Bogdanović GA, Sovilj SP, Revenco M. Synthesis, physicochemical properties and crystal structure of isothiocianato [2-(diphenylphosphino)benzaldehyde selenosemicarbazonato(1(-))] nickel(II). in Inorganic Chemistry Communications. 2004;7(2):253-256. doi:10.1016/j.inoche.2003.11.013 .
Brčeski, Ilija, Leovac, Vukadin M., Bogdanović, Goran A., Sovilj, Sofija P., Revenco, M, "Synthesis, physicochemical properties and crystal structure of isothiocianato [2-(diphenylphosphino)benzaldehyde selenosemicarbazonato(1(-))] nickel(II)" in Inorganic Chemistry Communications, 7, no. 2 (2004):253-256, https://doi.org/10.1016/j.inoche.2003.11.013 . .