1,3-Migration of phenylthio group in the rearrangement of tertiary cyclopropylmethanols possessing an α-phenylthio group

dc.creator	Saičić, Radomir
dc.creator	Badić, J.
dc.creator	Čeković, Živorad
dc.date.accessioned	2018-11-22T00:00:59Z
dc.date.available	2018-11-22T00:00:59Z
dc.date.issued	1996
dc.identifier.issn	0352-5139
dc.identifier.uri	https://cherry.chem.bg.ac.rs/handle/123456789/61
dc.description.abstract	The acid catalysed ring opening of tertiary cyclopropylmethanols 1 (R = H, vinyl, Ph), possessing a phenylthio group on the adjacent carbon atom proceeds, regioselectively and homoallylic halides 2 are obtained in 49 - 86% yields. Depending on the structure of 1 (R= Ph, SPh) and the acid used the cyclopropane ring opening follows the 1,3-migration of phenylthio group and the corresponding 1-halo-3-phenylthio-4-pentene derivatives 3 are obtained in 54-76% yields.	en
dc.rights	restrictedAccess
dc.rights.uri	https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.source	Journal of the Serbian Chemical Society
dc.subject	1,3-migration of phenylthio group	en
dc.subject	Cyclopropane ring opening	en
dc.subject	Cyclopropylcarbinyl carbocation	en
dc.title	1,3-Migration of phenylthio group in the rearrangement of tertiary cyclopropylmethanols possessing an α-phenylthio group	en
dc.type	article
dc.rights.license	BY-NC-ND
dc.citation.volume	61
dc.citation.issue	10
dc.citation.spage	841
dc.citation.epage	848
dc.citation.other	61(10): 841-848
dc.type.version	publishedVersion	en
dc.identifier.scopus	2-s2.0-0040649974
dc.identifier.rcub	https://hdl.handle.net/21.15107/rcub_cherry_61

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