Intramolecular C-H⋯π interactions in metal-porphyrin complexes
Апстракт
Cambridge Structural Database (CSD) was screened in order to find intramolecular C-H⋯π interactions with a chelate ring of coordinated porphyrin. It was found 154 crystal structures with 244 intramolecular C-H⋯π interactions in transition metal complexes with derivatives of porphyrin. Comparison of interacting distances indicates that interactions of hydrogen atoms in positions 2 and 6 of axially coordinated pyridine are more favorable with ruffled than with planar porphyrin.
Кључне речи:
Axial ligands / C-H⋯π interactions / Chelate ring / Porphyrin / Transition metal complexesИзвор:
International Journal of Molecular Sciences, 2004, 5, SPEC ISS, 174-185Колекције
Институција/група
Hemijski fakultet / Faculty of ChemistryTY - CONF AU - Bogdanović, Goran A. AU - Medaković, Vesna AU - Milčić, Miloš K. AU - Zarić, Snežana D. PY - 2004 UR - https://cherry.chem.bg.ac.rs/handle/123456789/66 AB - Cambridge Structural Database (CSD) was screened in order to find intramolecular C-H⋯π interactions with a chelate ring of coordinated porphyrin. It was found 154 crystal structures with 244 intramolecular C-H⋯π interactions in transition metal complexes with derivatives of porphyrin. Comparison of interacting distances indicates that interactions of hydrogen atoms in positions 2 and 6 of axially coordinated pyridine are more favorable with ruffled than with planar porphyrin. C3 - International Journal of Molecular Sciences T1 - Intramolecular C-H⋯π interactions in metal-porphyrin complexes VL - 5 IS - SPEC ISS SP - 174 EP - 185 UR - https://hdl.handle.net/21.15107/rcub_cherry_66 ER -
@conference{ author = "Bogdanović, Goran A. and Medaković, Vesna and Milčić, Miloš K. and Zarić, Snežana D.", year = "2004", abstract = "Cambridge Structural Database (CSD) was screened in order to find intramolecular C-H⋯π interactions with a chelate ring of coordinated porphyrin. It was found 154 crystal structures with 244 intramolecular C-H⋯π interactions in transition metal complexes with derivatives of porphyrin. Comparison of interacting distances indicates that interactions of hydrogen atoms in positions 2 and 6 of axially coordinated pyridine are more favorable with ruffled than with planar porphyrin.", journal = "International Journal of Molecular Sciences", title = "Intramolecular C-H⋯π interactions in metal-porphyrin complexes", volume = "5", number = "SPEC ISS", pages = "174-185", url = "https://hdl.handle.net/21.15107/rcub_cherry_66" }
Bogdanović, G. A., Medaković, V., Milčić, M. K.,& Zarić, S. D.. (2004). Intramolecular C-H⋯π interactions in metal-porphyrin complexes. in International Journal of Molecular Sciences, 5(SPEC ISS), 174-185. https://hdl.handle.net/21.15107/rcub_cherry_66
Bogdanović GA, Medaković V, Milčić MK, Zarić SD. Intramolecular C-H⋯π interactions in metal-porphyrin complexes. in International Journal of Molecular Sciences. 2004;5(SPEC ISS):174-185. https://hdl.handle.net/21.15107/rcub_cherry_66 .
Bogdanović, Goran A., Medaković, Vesna, Milčić, Miloš K., Zarić, Snežana D., "Intramolecular C-H⋯π interactions in metal-porphyrin complexes" in International Journal of Molecular Sciences, 5, no. SPEC ISS (2004):174-185, https://hdl.handle.net/21.15107/rcub_cherry_66 .