Synthesis and characterization of ammonium Decavanadate (V)
Abstract
It is known that various polyoxovanadates interact specifically with enzymes, which is the main way of their biochemical activity. Therefore we have synthesized ammonium decavanadate, (NH4)(6)V(10)O(28)(.)6H(2)O. The novel compound was characterized by elemental and thermal analysis, X-ray powder and single crystal diffraction and IR and Raman spectroscopy. Its conductive properties have been studied, too. The spectroscopic analysis has shown the presence of hydrogen bonds of different strengths. In order to improve the biochemical activity of this compound and having in mind the presence of strong hydrogen bonds, we essayed the synthesis of complex of polyoxovanadate with alanine. The obtained product was characterized by the mentioned methods.
Keywords:
ammonium decavanadate / conductivity / IR and Raman spectra / polyoxometalate (POM) / thermal analysis / XRDSource:
Materials Science Forum, 2005, 494, 351-356Publisher:
- Trans Tech Publications Ltd, Zurich-Uetikon
DOI: 10.4028/www.scientific.net/MSF.494.351
ISSN: 0255-5476
WoS: 000230985800058
Scopus: 2-s2.0-33745105833
Collections
Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Todorović, Marija B. AU - Mioč, Ubavka B. AU - Holclajtner-Antunović, Ivanka AU - Šegan, Dejan M. PY - 2005 UR - https://cherry.chem.bg.ac.rs/handle/123456789/723 AB - It is known that various polyoxovanadates interact specifically with enzymes, which is the main way of their biochemical activity. Therefore we have synthesized ammonium decavanadate, (NH4)(6)V(10)O(28)(.)6H(2)O. The novel compound was characterized by elemental and thermal analysis, X-ray powder and single crystal diffraction and IR and Raman spectroscopy. Its conductive properties have been studied, too. The spectroscopic analysis has shown the presence of hydrogen bonds of different strengths. In order to improve the biochemical activity of this compound and having in mind the presence of strong hydrogen bonds, we essayed the synthesis of complex of polyoxovanadate with alanine. The obtained product was characterized by the mentioned methods. PB - Trans Tech Publications Ltd, Zurich-Uetikon T2 - Materials Science Forum T1 - Synthesis and characterization of ammonium Decavanadate (V) VL - 494 SP - 351 EP - 356 DO - 10.4028/www.scientific.net/MSF.494.351 ER -
@article{ author = "Todorović, Marija B. and Mioč, Ubavka B. and Holclajtner-Antunović, Ivanka and Šegan, Dejan M.", year = "2005", abstract = "It is known that various polyoxovanadates interact specifically with enzymes, which is the main way of their biochemical activity. Therefore we have synthesized ammonium decavanadate, (NH4)(6)V(10)O(28)(.)6H(2)O. The novel compound was characterized by elemental and thermal analysis, X-ray powder and single crystal diffraction and IR and Raman spectroscopy. Its conductive properties have been studied, too. The spectroscopic analysis has shown the presence of hydrogen bonds of different strengths. In order to improve the biochemical activity of this compound and having in mind the presence of strong hydrogen bonds, we essayed the synthesis of complex of polyoxovanadate with alanine. The obtained product was characterized by the mentioned methods.", publisher = "Trans Tech Publications Ltd, Zurich-Uetikon", journal = "Materials Science Forum", title = "Synthesis and characterization of ammonium Decavanadate (V)", volume = "494", pages = "351-356", doi = "10.4028/www.scientific.net/MSF.494.351" }
Todorović, M. B., Mioč, U. B., Holclajtner-Antunović, I.,& Šegan, D. M.. (2005). Synthesis and characterization of ammonium Decavanadate (V). in Materials Science Forum Trans Tech Publications Ltd, Zurich-Uetikon., 494, 351-356. https://doi.org/10.4028/www.scientific.net/MSF.494.351
Todorović MB, Mioč UB, Holclajtner-Antunović I, Šegan DM. Synthesis and characterization of ammonium Decavanadate (V). in Materials Science Forum. 2005;494:351-356. doi:10.4028/www.scientific.net/MSF.494.351 .
Todorović, Marija B., Mioč, Ubavka B., Holclajtner-Antunović, Ivanka, Šegan, Dejan M., "Synthesis and characterization of ammonium Decavanadate (V)" in Materials Science Forum, 494 (2005):351-356, https://doi.org/10.4028/www.scientific.net/MSF.494.351 . .