Use of different salt solutions in salting-out TLC of Co(III) complexes on silica gel
Abstract
Saturated aqueous solutions of 28 different salts have been studied as a potential mobile phases for salting-out thin-layer chromatography, on silica gel, of a series of four mixed bis-aminocarboxylato cobalt(III) complexes. In addition, by linear regression analysis of chromatographic data obtained for fifteen mixed aminocarboxylato Co(III) complexes (four series) with solutions of ammonium chloride, three alkali metal chlorides, and four alkaline earth metal chlorides, four linear dependences previously established on different adsorbents with (NH4)(2)SO4 solutions were confirmed. The qualities of the separations achieved with the salts were compared and Li+, Mg2+, and Ca2+ chlorides are proposed as the most suitable.
Keywords:
salting-out thin-layer chromatography / application of different salts / salting-out ability / silica gel / mixed aminocarboxylato Co(III) complexesSource:
Chromatographia, 2008, 67, 3-4, 259-267Publisher:
- Vieweg, Wiesbaden
Funding / projects:
- Sinteze, fizičke, strukturne i biološke karakteristike novih kompleksnih jedenjenja (RS-MESTD-MPN2006-2010-142028)
DOI: 10.1365/s10337-007-0489-y
ISSN: 0009-5893
WoS: 000252806200009
Scopus: 2-s2.0-38849096555
Collections
Institution/Community
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Živković-Radovanović, Vukosava AU - Vuckovic, Gordana PY - 2008 UR - https://cherry.chem.bg.ac.rs/handle/123456789/911 AB - Saturated aqueous solutions of 28 different salts have been studied as a potential mobile phases for salting-out thin-layer chromatography, on silica gel, of a series of four mixed bis-aminocarboxylato cobalt(III) complexes. In addition, by linear regression analysis of chromatographic data obtained for fifteen mixed aminocarboxylato Co(III) complexes (four series) with solutions of ammonium chloride, three alkali metal chlorides, and four alkaline earth metal chlorides, four linear dependences previously established on different adsorbents with (NH4)(2)SO4 solutions were confirmed. The qualities of the separations achieved with the salts were compared and Li+, Mg2+, and Ca2+ chlorides are proposed as the most suitable. PB - Vieweg, Wiesbaden T2 - Chromatographia T1 - Use of different salt solutions in salting-out TLC of Co(III) complexes on silica gel VL - 67 IS - 3-4 SP - 259 EP - 267 DO - 10.1365/s10337-007-0489-y ER -
@article{ author = "Živković-Radovanović, Vukosava and Vuckovic, Gordana", year = "2008", abstract = "Saturated aqueous solutions of 28 different salts have been studied as a potential mobile phases for salting-out thin-layer chromatography, on silica gel, of a series of four mixed bis-aminocarboxylato cobalt(III) complexes. In addition, by linear regression analysis of chromatographic data obtained for fifteen mixed aminocarboxylato Co(III) complexes (four series) with solutions of ammonium chloride, three alkali metal chlorides, and four alkaline earth metal chlorides, four linear dependences previously established on different adsorbents with (NH4)(2)SO4 solutions were confirmed. The qualities of the separations achieved with the salts were compared and Li+, Mg2+, and Ca2+ chlorides are proposed as the most suitable.", publisher = "Vieweg, Wiesbaden", journal = "Chromatographia", title = "Use of different salt solutions in salting-out TLC of Co(III) complexes on silica gel", volume = "67", number = "3-4", pages = "259-267", doi = "10.1365/s10337-007-0489-y" }
Živković-Radovanović, V.,& Vuckovic, G.. (2008). Use of different salt solutions in salting-out TLC of Co(III) complexes on silica gel. in Chromatographia Vieweg, Wiesbaden., 67(3-4), 259-267. https://doi.org/10.1365/s10337-007-0489-y
Živković-Radovanović V, Vuckovic G. Use of different salt solutions in salting-out TLC of Co(III) complexes on silica gel. in Chromatographia. 2008;67(3-4):259-267. doi:10.1365/s10337-007-0489-y .
Živković-Radovanović, Vukosava, Vuckovic, Gordana, "Use of different salt solutions in salting-out TLC of Co(III) complexes on silica gel" in Chromatographia, 67, no. 3-4 (2008):259-267, https://doi.org/10.1365/s10337-007-0489-y . .