@conference{
author = "Berbić, Damir and Araškov, Jovana and Filipović, Nenad and Todorović, Tamara",
year = "2019",
abstract = "New nickel(II) complex with (E)-4-(4-tolylphenyl)-2-(2-(2-pyridylmethyilidene)hydrazinyl)thiazole (HL) was synthesized and characterized. The complex was synthesized by the reaction of the ligand with nickel(II) perchlorate hexahydrate and obtained in a single crystal form. The structure of the complex, with general formula [NiL2](ClO4)2, was solved by a single crystal X-ray diffraction analysis (Fig. 1). HL is tridentately coordinated to nickel(II) via pyridine, imine and thiazole nitrogen atoms with two perchlorate anions in the outer sphere. Besides electrostatic interactions, hydrogen interactions are also present in the crystal packing of the complex. Magnetic moment and conductivity measurements showed that the complex is paramagnetic and 2 : 1 type of electrolyte.
Antiproliferative activity of the complex was evaluated against several human tumour cell lines. The complex showed better activity than positive control
5-fluorouracil. The complex was shown to highly efficiently catalyze photodegradation of reactive Orange 16 dye.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Seventh Conference of Young Chemists of Serbia, Belgrade, 2nd November 2019",
title = "Nickel(II) complex with hydrazinyl-thiazole: structural charactacterization, antiproliferative and photocatalytic activity",
url = "https://hdl.handle.net/21.15107/rcub_cherry_6000"
}