Aristeia, Aristotle University of Thessaloniki

Link to this page

Aristeia, Aristotle University of Thessaloniki

Authors

Publications

Interaction of dinuclear cadmium(II) 5-Cl-salicylaldehyde complexes with calf-thymus DNA

Šumar-Ristović, Maja; Zianna, Ariadni; Psomas, George; Hatzidimitriou, Antonios G.; Coutouli-Argyropoulou, Evdoxia; Lalia-Kantouri, Maria

(Elsevier Science Bv, Amsterdam, 2016)

TY  - JOUR
AU  - Šumar-Ristović, Maja
AU  - Zianna, Ariadni
AU  - Psomas, George
AU  - Hatzidimitriou, Antonios G.
AU  - Coutouli-Argyropoulou, Evdoxia
AU  - Lalia-Kantouri, Maria
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/2052
AB  - Five dinuclear Cd(II) complexes with the anion of 5-Cl-salicylaldehyde (5-Cl-saloH) were synthesized in the absence or presence of the alpha-diimines: 2,2'-bipyridine (bipy), 1,10-phenanthroline (phen), 2,9-dimethyl-1,10-henanthroline (neoc) or 2,2'-dipyridylamine (dpamH) and characterized as [Cd(5-Cl-salo)(2)(CH3OH)](2) (1), [Cd(5-Cl-salo)(2)(bipy)](2) (2), [Cd(5-Cl-salo)(2)(phen)](2) (3), [Cd(5-Cl-salo)(neoc)(ONO2)](2) (4) and [Cd(5-Cl-salo)(dpamH)(ONO2)](2) (5). The complexes were characterized by spectroscopic techniques (IR, UV-vis, H-1-NMR and C-13-NMR), elemental analysis and molar conductivity measurements. The structures of four complexes (1-3 and 5) were determined by X-ray crystallography, providing all three possible coordination modes of the ligand 5-Cl-salicylaldehyde, i.e. bidentate or tridentate chelating and/or bridging mode. The complexes bind to calf-thymus (Cr) DNA mainly by intercalation, as concluded by the viscosity measurements and present relatively high DNA-binding constants. The complexes exhibit significant ability to displace ethidium bromide (EB) from the EB-DNA complex, thus indirectly proving the intercalation as the most possible binding mode to Cr DNA. (C) 2016 Elsevier B.V. All rights reserved.
PB  - Elsevier Science Bv, Amsterdam
T2  - Materials Science and Engineering. C: Materials for Biological Applications
T1  - Interaction of dinuclear cadmium(II) 5-Cl-salicylaldehyde complexes with calf-thymus DNA
VL  - 61
SP  - 579
EP  - 590
DO  - 10.1016/j.msec.2015.12.054
ER  - 
@article{
author = "Šumar-Ristović, Maja and Zianna, Ariadni and Psomas, George and Hatzidimitriou, Antonios G. and Coutouli-Argyropoulou, Evdoxia and Lalia-Kantouri, Maria",
year = "2016",
abstract = "Five dinuclear Cd(II) complexes with the anion of 5-Cl-salicylaldehyde (5-Cl-saloH) were synthesized in the absence or presence of the alpha-diimines: 2,2'-bipyridine (bipy), 1,10-phenanthroline (phen), 2,9-dimethyl-1,10-henanthroline (neoc) or 2,2'-dipyridylamine (dpamH) and characterized as [Cd(5-Cl-salo)(2)(CH3OH)](2) (1), [Cd(5-Cl-salo)(2)(bipy)](2) (2), [Cd(5-Cl-salo)(2)(phen)](2) (3), [Cd(5-Cl-salo)(neoc)(ONO2)](2) (4) and [Cd(5-Cl-salo)(dpamH)(ONO2)](2) (5). The complexes were characterized by spectroscopic techniques (IR, UV-vis, H-1-NMR and C-13-NMR), elemental analysis and molar conductivity measurements. The structures of four complexes (1-3 and 5) were determined by X-ray crystallography, providing all three possible coordination modes of the ligand 5-Cl-salicylaldehyde, i.e. bidentate or tridentate chelating and/or bridging mode. The complexes bind to calf-thymus (Cr) DNA mainly by intercalation, as concluded by the viscosity measurements and present relatively high DNA-binding constants. The complexes exhibit significant ability to displace ethidium bromide (EB) from the EB-DNA complex, thus indirectly proving the intercalation as the most possible binding mode to Cr DNA. (C) 2016 Elsevier B.V. All rights reserved.",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Materials Science and Engineering. C: Materials for Biological Applications",
title = "Interaction of dinuclear cadmium(II) 5-Cl-salicylaldehyde complexes with calf-thymus DNA",
volume = "61",
pages = "579-590",
doi = "10.1016/j.msec.2015.12.054"
}
Šumar-Ristović, M., Zianna, A., Psomas, G., Hatzidimitriou, A. G., Coutouli-Argyropoulou, E.,& Lalia-Kantouri, M.. (2016). Interaction of dinuclear cadmium(II) 5-Cl-salicylaldehyde complexes with calf-thymus DNA. in Materials Science and Engineering. C: Materials for Biological Applications
Elsevier Science Bv, Amsterdam., 61, 579-590.
https://doi.org/10.1016/j.msec.2015.12.054
Šumar-Ristović M, Zianna A, Psomas G, Hatzidimitriou AG, Coutouli-Argyropoulou E, Lalia-Kantouri M. Interaction of dinuclear cadmium(II) 5-Cl-salicylaldehyde complexes with calf-thymus DNA. in Materials Science and Engineering. C: Materials for Biological Applications. 2016;61:579-590.
doi:10.1016/j.msec.2015.12.054 .
Šumar-Ristović, Maja, Zianna, Ariadni, Psomas, George, Hatzidimitriou, Antonios G., Coutouli-Argyropoulou, Evdoxia, Lalia-Kantouri, Maria, "Interaction of dinuclear cadmium(II) 5-Cl-salicylaldehyde complexes with calf-thymus DNA" in Materials Science and Engineering. C: Materials for Biological Applications, 61 (2016):579-590,
https://doi.org/10.1016/j.msec.2015.12.054 . .
23
12
23
21

Supplementary material for the article: Ristovic, M. S.; Zianna, A.; Psomas, G.; Hatzidimitriou, A. G.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Interaction of Dinuclear Cadmium(II) 5-Cl-Salicylaldehyde Complexes with Calf-Thymus DNA. Materials Science and Engineering C 2016, 61, 579–590. https://doi.org/10.1016/j.msec.2015.12.054

Šumar-Ristović, Maja; Zianna, Ariadni; Psomas, George; Hatzidimitriou, Antonios G.; Coutouli-Argyropoulou, Evdoxia; Lalia-Kantouri, Maria

(Elsevier Science Bv, Amsterdam, 2016)

TY  - DATA
AU  - Šumar-Ristović, Maja
AU  - Zianna, Ariadni
AU  - Psomas, George
AU  - Hatzidimitriou, Antonios G.
AU  - Coutouli-Argyropoulou, Evdoxia
AU  - Lalia-Kantouri, Maria
PY  - 2016
UR  - https://cherry.chem.bg.ac.rs/handle/123456789/3544
PB  - Elsevier Science Bv, Amsterdam
T2  - Materials Science and Engineering. C: Materials for Biological Applications
T1  - Supplementary material for the article: Ristovic, M. S.; Zianna, A.; Psomas, G.; Hatzidimitriou, A. G.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Interaction of Dinuclear Cadmium(II) 5-Cl-Salicylaldehyde Complexes with Calf-Thymus DNA. Materials Science and Engineering C 2016, 61, 579–590. https://doi.org/10.1016/j.msec.2015.12.054
UR  - https://hdl.handle.net/21.15107/rcub_cherry_3544
ER  - 
@misc{
author = "Šumar-Ristović, Maja and Zianna, Ariadni and Psomas, George and Hatzidimitriou, Antonios G. and Coutouli-Argyropoulou, Evdoxia and Lalia-Kantouri, Maria",
year = "2016",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Materials Science and Engineering. C: Materials for Biological Applications",
title = "Supplementary material for the article: Ristovic, M. S.; Zianna, A.; Psomas, G.; Hatzidimitriou, A. G.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Interaction of Dinuclear Cadmium(II) 5-Cl-Salicylaldehyde Complexes with Calf-Thymus DNA. Materials Science and Engineering C 2016, 61, 579–590. https://doi.org/10.1016/j.msec.2015.12.054",
url = "https://hdl.handle.net/21.15107/rcub_cherry_3544"
}
Šumar-Ristović, M., Zianna, A., Psomas, G., Hatzidimitriou, A. G., Coutouli-Argyropoulou, E.,& Lalia-Kantouri, M.. (2016). Supplementary material for the article: Ristovic, M. S.; Zianna, A.; Psomas, G.; Hatzidimitriou, A. G.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Interaction of Dinuclear Cadmium(II) 5-Cl-Salicylaldehyde Complexes with Calf-Thymus DNA. Materials Science and Engineering C 2016, 61, 579–590. https://doi.org/10.1016/j.msec.2015.12.054. in Materials Science and Engineering. C: Materials for Biological Applications
Elsevier Science Bv, Amsterdam..
https://hdl.handle.net/21.15107/rcub_cherry_3544
Šumar-Ristović M, Zianna A, Psomas G, Hatzidimitriou AG, Coutouli-Argyropoulou E, Lalia-Kantouri M. Supplementary material for the article: Ristovic, M. S.; Zianna, A.; Psomas, G.; Hatzidimitriou, A. G.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Interaction of Dinuclear Cadmium(II) 5-Cl-Salicylaldehyde Complexes with Calf-Thymus DNA. Materials Science and Engineering C 2016, 61, 579–590. https://doi.org/10.1016/j.msec.2015.12.054. in Materials Science and Engineering. C: Materials for Biological Applications. 2016;.
https://hdl.handle.net/21.15107/rcub_cherry_3544 .
Šumar-Ristović, Maja, Zianna, Ariadni, Psomas, George, Hatzidimitriou, Antonios G., Coutouli-Argyropoulou, Evdoxia, Lalia-Kantouri, Maria, "Supplementary material for the article: Ristovic, M. S.; Zianna, A.; Psomas, G.; Hatzidimitriou, A. G.; Coutouli-Argyropoulou, E.; Lalia-Kantouri, M. Interaction of Dinuclear Cadmium(II) 5-Cl-Salicylaldehyde Complexes with Calf-Thymus DNA. Materials Science and Engineering C 2016, 61, 579–590. https://doi.org/10.1016/j.msec.2015.12.054" in Materials Science and Engineering. C: Materials for Biological Applications (2016),
https://hdl.handle.net/21.15107/rcub_cherry_3544 .