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A highly regioselective, protecting group controlled, synthesis of bicyclic compounds via Pd-catalysed intramolecular cyclisations
(Pergamon-Elsevier Science Ltd, Oxford, 2013)
Intramolecular Pd-catalysed cyclisation reactions for the preparation of bicyclic compounds have been studied as a model system towards the synthesis of corialstonine and corialstonidine. Significant differences in reactivity ...
Study of the intramolecular Heck reaction: synthesis of the bicyclic core of corialstonidine
(Pergamon-Elsevier Science Ltd, Oxford, 2015)
The intramolecular Heck reaction has been examined for the preparation of the core bicyclic structure of corialstonidine. Initial attempts to cyclise a vinyl iodide moiety onto a cyclic allyl alcohol were complicated by ...