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Total Synthesis of CrocaginA
dc.creator | Bihelović, Filip | |
dc.creator | Stichnoth, Desiree | |
dc.creator | Surup, Frank | |
dc.creator | Mueller, Rolf | |
dc.creator | Trauner, Dirk | |
dc.date.accessioned | 2018-11-22T00:41:15Z | |
dc.date.available | 2018-11-22T00:41:15Z | |
dc.date.issued | 2017 | |
dc.identifier.issn | 1433-7851 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/2532 | |
dc.description.abstract | CrocaginA (1) combines an attractive molecular structure with an unusual biosynthesis and bioactivity. An efficient synthesis of crocaginA is presented that hinges on an early formation of the heterotricyclic core, an electrophilic amination, and the stereoselective hydrogenation of a tetrasubstituted double bond. This synthesis confirms the absolute configuration of crocaginA and provides access to the natural product and derivatives thereof for further biological testing. | en |
dc.publisher | Wiley-V C H Verlag Gmbh, Weinheim | |
dc.relation | Deutsche Forschungsgemeinschaft (CIPSM) | |
dc.relation | Deutsche Forschungsgemeinschaft [SFB 749] | |
dc.rights | restrictedAccess | |
dc.source | Angewandte Chemie (International Edition) | |
dc.subject | electrophilic amination | en |
dc.subject | hydrogenation | en |
dc.subject | natural products | en |
dc.subject | RiPPs | en |
dc.subject | total synthesis | en |
dc.title | Total Synthesis of CrocaginA | en |
dc.type | article | |
dc.rights.license | ARR | |
dcterms.abstract | Суруп, Франк; Бихеловић, Филип; Траунер, Дирк; Муеллер, Ролф; Стицхнотх, Десирее; | |
dc.citation.volume | 56 | |
dc.citation.issue | 42 | |
dc.citation.spage | 12848 | |
dc.citation.epage | 12851 | |
dc.identifier.wos | 000412189700006 | |
dc.identifier.doi | 10.1002/anie.201612641 | |
dc.citation.other | 56(42): 12848-12851 | |
dc.citation.rank | M21 | |
dc.identifier.pmid | 28812331 | |
dc.description.other | Supplementary material: [http://cherry.chem.bg.ac.rs/handle/123456789/3261] | |
dc.type.version | publishedVersion | en |
dc.identifier.scopus | 2-s2.0-85030637829 |