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Free radical domino reactions in the synthesis of small ring compounds: multiple annulation of cyclopropane-containing polycycles

dc.creatorFerjančić, Zorana
dc.creatorČeković, Živorad
dc.creatorSaičić, Radomir
dc.date.accessioned2018-11-22T00:04:03Z
dc.date.available2018-11-22T00:04:03Z
dc.date.issued2001
dc.identifier.issn1387-1609
dc.identifier.urihttps://cherry.chem.bg.ac.rs/handle/123456789/470
dc.description.abstractFree radical approach to fused vinylcyclopropane derivatives is described. Homolytic decomposition of Barton esters 4a-f in the presence of activated alkynes affords bicyclo[3.1.0]hex-2-ene derivatives 5a-g in moderate yields (18-52 %). The propagation sequence comprises: intermolecular addition/5-exo-cyclization/3-exo-cyclization/beta -elimination, and allows for a one-pot synthesis of bicyclic cyclopropane derivatives starting from two acyclic, unsaturated compounds. (C) 2001 Academie des sciences / Editions scientifiques et medicales Elsevier SAS.en
dc.publisherEditions Scientifiques Medicales Elsevier, Paris Cedex 15
dc.rightsrestrictedAccess
dc.sourceComptes Rendus de L'academie des Sciences: Series IIc: Chemistry
dc.subjectradicalsen
dc.subjectcyclizationen
dc.subjectcyclopropaneen
dc.subjectpolycyclesen
dc.subjectdomino reactionsen
dc.titleFree radical domino reactions in the synthesis of small ring compounds: multiple annulation of cyclopropane-containing polycyclesen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractЦековиц, З; Ферјанчић, Зорана; Саичић, Радомир;
dc.citation.volume4
dc.citation.issue7
dc.citation.spage599
dc.citation.epage610
dc.identifier.wos000170832300012
dc.identifier.doi10.1016/S1387-1609(01)01276-2
dc.citation.other4(7): 599-610
dc.citation.rankM23
dc.type.versionpublishedVersionen
dc.identifier.scopus2-s2.0-18044403837


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