Stereoselective synthesis of (-)-cytoxazone and (+)-epi-cytoxazone

dc.creator	Milicevic, S
dc.creator	Matović, Radomir
dc.creator	Saičić, Radomir
dc.date.accessioned	2018-11-22T00:06:39Z
dc.date.available	2018-11-22T00:06:39Z
dc.date.issued	2004
dc.identifier.issn	0040-4039
dc.identifier.uri	https://cherry.chem.bg.ac.rs/handle/123456789/564
dc.description.abstract	Optically pure (-)-cytoxazone was synthesized, starting from methyl p-methoxycinnamate, in six steps and in 31%, overall yield. The required anti-aminoalcohol configuration was established by combining Sharpless asymmetric aminohydroxylation with the configurational inversion of the intermediate amidoalcohol via ail oxazoline. The synthesis of (+)-epi-cytoxazone is also described. (C) 2003 Elsevier Ltd. All rights reserved.	en
dc.publisher	Pergamon-Elsevier Science Ltd, Oxford
dc.rights	restrictedAccess
dc.source	Tetrahedron Letters
dc.subject	cytoxazone	en
dc.subject	asymmetric synthesis	en
dc.subject	natural products	en
dc.subject	immunosuppressive compounds	en
dc.subject	amino alcohols	en
dc.title	Stereoselective synthesis of (-)-cytoxazone and (+)-epi-cytoxazone	en
dc.type	article
dc.rights.license	ARR
dcterms.abstract	Матовиц, Р; Милицевиц, С; Саичић, Радомир;
dc.citation.volume	45
dc.citation.issue	5
dc.citation.spage	955
dc.citation.epage	957
dc.identifier.wos	000188380400015
dc.identifier.doi	10.1016/j.tetlet.2003.11.096
dc.citation.other	45(5): 955-957
dc.citation.rank	M21
dc.type.version	publishedVersion	en
dc.identifier.scopus	2-s2.0-0346392218