Mixed-ligand complexes of cobalt(III) with dithiocarbamates and a cyclic tetradentate secondary amine
Apstrakt
4-Morpholine-, piperidine-, 4-piperazine- and N-methyl- piperazine-dithiocarbamate complexes of Cobalt (III) with 1, 4, 8, 11-tetraazacyclotetradecane, of general formula [Co(Rdtc)cyclam] (ClO4)(2), have been prepared and have been characterized. The complexes adopt cis-octahedral geometry with folded macrocyclic ligand and with the dithiocarbamate bound as a bidentate. trans-influence of the dithiocarbamate ligands was studied by NMR spectroscopy and established the order piperidine-dtc gt 4-morpholine-dtc gt N-methyl-piperazine-dtc.
Ključne reči:
cobalt(III) / macrocycles / dithiocarbamates / synthesis / complexesIzvor:
Journal of Coordination Chemistry, 1997, 41, 1-2, 19-25Izdavač:
- Gordon Breach Sci Publ Ltd, Reading
DOI: 10.1080/00958979708027954
ISSN: 0095-8972
WoS: A1997XA90900003
Scopus: 2-s2.0-0002436319
Kolekcije
Institucija/grupa
Hemijski fakultet / Faculty of ChemistryTY - JOUR AU - Sovilj, Sofija P. AU - Vuković, G AU - Babic, K AU - Sabo, Tibor AU - Macura, S. AU - Juranić, N. PY - 1997 UR - https://cherry.chem.bg.ac.rs/handle/123456789/2590 AB - 4-Morpholine-, piperidine-, 4-piperazine- and N-methyl- piperazine-dithiocarbamate complexes of Cobalt (III) with 1, 4, 8, 11-tetraazacyclotetradecane, of general formula [Co(Rdtc)cyclam] (ClO4)(2), have been prepared and have been characterized. The complexes adopt cis-octahedral geometry with folded macrocyclic ligand and with the dithiocarbamate bound as a bidentate. trans-influence of the dithiocarbamate ligands was studied by NMR spectroscopy and established the order piperidine-dtc gt 4-morpholine-dtc gt N-methyl-piperazine-dtc. PB - Gordon Breach Sci Publ Ltd, Reading T2 - Journal of Coordination Chemistry T1 - Mixed-ligand complexes of cobalt(III) with dithiocarbamates and a cyclic tetradentate secondary amine VL - 41 IS - 1-2 SP - 19 EP - 25 DO - 10.1080/00958979708027954 ER -
@article{ author = "Sovilj, Sofija P. and Vuković, G and Babic, K and Sabo, Tibor and Macura, S. and Juranić, N.", year = "1997", abstract = "4-Morpholine-, piperidine-, 4-piperazine- and N-methyl- piperazine-dithiocarbamate complexes of Cobalt (III) with 1, 4, 8, 11-tetraazacyclotetradecane, of general formula [Co(Rdtc)cyclam] (ClO4)(2), have been prepared and have been characterized. The complexes adopt cis-octahedral geometry with folded macrocyclic ligand and with the dithiocarbamate bound as a bidentate. trans-influence of the dithiocarbamate ligands was studied by NMR spectroscopy and established the order piperidine-dtc gt 4-morpholine-dtc gt N-methyl-piperazine-dtc.", publisher = "Gordon Breach Sci Publ Ltd, Reading", journal = "Journal of Coordination Chemistry", title = "Mixed-ligand complexes of cobalt(III) with dithiocarbamates and a cyclic tetradentate secondary amine", volume = "41", number = "1-2", pages = "19-25", doi = "10.1080/00958979708027954" }
Sovilj, S. P., Vuković, G., Babic, K., Sabo, T., Macura, S.,& Juranić, N.. (1997). Mixed-ligand complexes of cobalt(III) with dithiocarbamates and a cyclic tetradentate secondary amine. in Journal of Coordination Chemistry Gordon Breach Sci Publ Ltd, Reading., 41(1-2), 19-25. https://doi.org/10.1080/00958979708027954
Sovilj SP, Vuković G, Babic K, Sabo T, Macura S, Juranić N. Mixed-ligand complexes of cobalt(III) with dithiocarbamates and a cyclic tetradentate secondary amine. in Journal of Coordination Chemistry. 1997;41(1-2):19-25. doi:10.1080/00958979708027954 .
Sovilj, Sofija P., Vuković, G, Babic, K, Sabo, Tibor, Macura, S., Juranić, N., "Mixed-ligand complexes of cobalt(III) with dithiocarbamates and a cyclic tetradentate secondary amine" in Journal of Coordination Chemistry, 41, no. 1-2 (1997):19-25, https://doi.org/10.1080/00958979708027954 . .