Приказ основних података о документу
Cobalt(II) and cadmium(II) compounds with adamantane-1-sulfonic acid
Nova jedinjenja kobalta(II) i kadmijuma(II) sa adamantan-1-sulfonskom kiselinom
dc.creator | Đorđević, Milena M. | |
dc.creator | Jeremić, Dejan | |
dc.creator | Anđelković, Katarina K. | |
dc.creator | Gruden-Pavlović, Maja | |
dc.creator | Divjaković, Vladimir | |
dc.creator | Šumar-Ristović, Maja | |
dc.creator | Brčeski, Ilija | |
dc.date.accessioned | 2018-11-22T00:22:19Z | |
dc.date.available | 2018-11-22T00:22:19Z | |
dc.date.issued | 2012 | |
dc.identifier.issn | 0352-5139 | |
dc.identifier.uri | https://cherry.chem.bg.ac.rs/handle/123456789/1553 | |
dc.description.abstract | In this work, the syntheses and characterization of two novel compounds of adamantane-1-sulfonic acid (1-AdSO(3)H) with cobalt(II) and cadmium(II) are reported. The results of single crystal X-ray analysis of the compounds revealed that adamantane-1-sulfonate (1-AdSO(3)(-)) in the monoanionic form plays different roles in the investigated compounds. Namely, while in compound [Co(H2O)(6)](1-AdSO(3))(2), six water molecules are coordinated to the cobalt(II) ion and 1-AdSO(3)(-) serves as a counter ion, in compound [Cd(H2O)(4)(1-AdSO(3))(2)], two molecules of 1-AdSO(3)(-) are trans-coordinated to the cadmium(II) ion as a monodentate (O)-ligand and the other coordination sites are occupied by water molecules. The obtained compounds showed moderate activity against Artemia salina. | en |
dc.description.abstract | U ovom radu prikazana je sinteza i karakterizacija dva nova jedinjenja adamantan-1-sulfonske kiseline (1-AdSO3H) sa kobaltom(II) i kadmijumom(II). Rezultati rend- genske strukturne analize datih jedinjenja ukazuju da monoanjon adamantan-1-sulfonata (1-AdSO3 pokazuje različit afinitet prema Co(II) i Cd(II) jonima). U kompleksu [Co(H2O)6](1-AdSO3)2, šest molekula vode se koordinuje za Co(II) jon, dok 1-AdSO3 ima ulogu kontrajona. U kompleksu [Cd(H2O)4(1-AdSO3)2] dva jona 1-AdSO3 su koordinovana za Cd(II) jon kao monodentati u trans položaju preko kiseonikovih atoma, dok su ostala koordinaciona mesta zauzeta molekulima vode. Dobijena jedinjenja su pokazala umerenu aktivnost na Artemia salina. | sr |
dc.publisher | Serbian Chemical Soc, Belgrade | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172017/RS// | |
dc.rights | openAccess | |
dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.source | Journal of the Serbian Chemical Society | |
dc.subject | X-ray structure determination | en |
dc.subject | transition metal compounds | en |
dc.subject | transition metal compounds | en |
dc.subject | metal complexes | en |
dc.subject | metal complexes | en |
dc.subject | adamantane-1-sulfonate derivatives | en |
dc.subject | adamantane-1-sulfonate derivatives | en |
dc.title | Cobalt(II) and cadmium(II) compounds with adamantane-1-sulfonic acid | en |
dc.title | Nova jedinjenja kobalta(II) i kadmijuma(II) sa adamantan-1-sulfonskom kiselinom | sr |
dc.type | article | |
dc.rights.license | BY-NC-ND | |
dcterms.abstract | Шумар-Ристовић, Маја; Aнђелковић, Катарина; Груден-Павловић, Маја; Јеремиц, Дејан; Брчески, Илија; Дордевиц, Милена; Дивјаковиц, Владимир; Нова једињења кобалта(ИИ) и кадмијума(ИИ) са адамантан-1-сулфонском киселином; Нова једињења кобалта(ИИ) и кадмијума(ИИ) са адамантан-1-сулфонском киселином; | |
dc.citation.volume | 77 | |
dc.citation.issue | 10 | |
dc.citation.spage | 1391 | |
dc.citation.epage | 1399 | |
dc.identifier.wos | 000311594100007 | |
dc.identifier.doi | 10.2298/JSC120419051D | |
dc.citation.other | 77(10): 1391-1399 | |
dc.citation.rank | M23 | |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-84870201150 | |
dc.identifier.fulltext | https://cherry.chem.bg.ac.rs/bitstream/id/8657/1551.pdf |